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Product Code M2335A1-100mg
Price £250 ex. VAT

mCPPO1, bipolar phosphorescent host material for blue, green and red OLEDs

High purity (>99.0%) material used to improve device performance


mCPPO1, 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole, has a bipolar character with an electron rich 1,3-di(9H-carbazol-9-yl)benzene core unit and an electron deficient diphenylphosphine oxide attachment.

mCPPO1 is an extended family member of mCP with a higher glass transition temperature (Tg = 114.7 °C), and can be used as a phosphorescent host material for blue, green and red organic light emitting diodes. The bipolar charge transport properties of mCPPO1 can effectively balance holes and electrons in the emitting layer, improving device performance.

General Information


CAS number 1296229-26-9
Full name 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole
Chemical formula C42H29N2OP
Molecular weight 608.67 g/mol
Absorption λmax 324 nm, 338 nm (in DCM)
Phosphorescene λmax 361 nm (in DCM)
HOMO/LUMO HOMO 6.13 eV, LUMO 2.64 eV [1]
Synonyms [9-[3-(9H-Carbazol-9-yl)phenyl]-9H-carbazol-3-yl]diphenylphosphine oxide
Classification / Family Carbazole derivatives, TADF Light-emitting diodes, Organic electronics, PHOLEDs host materials, Sublimed materials.

Product Details


Purity >99.0% (HPLC)
Melting point Tg = 114.7 °C
Appearance White powder/crystals

Chemical Structure


mCPPO1, 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole, 1296229-26-9
Chemical structure of 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole (mCPPO1), CAS# 1296229-26-9.

Device Structure(s)


Device structure ITO (70 nm)/4wt% ReO3:mCP (30 nm)/mCP (10 nm)/10wt% (HFP)2Ir(mpic):mCPPO1 (30 nm)/TSPO1 (10 nm)/8wt%Rb2CO3:mCP (30 nm)/Al (100 nm) [3]
Colour blue light emitting device Blue
Max Current Efficiency 27.2 cd/A
Max. Power Efficiency 25.9 lm W-1
Max. EQE 21.4%
Device structure ITO (50 nm)/PEDOT(CH8000, 60 nm)/TAPC(20 nm)/mCP(10 nm)/mCPPO1:3wt% Ir(dfpypy)dpm  (25 nm)/TSPO1(35 nm)/LiF(1 nm)/Al (200 nm) [4]
Colour blue light emitting device Blue
Max Current Efficiency 20.4 cd/A
Max. Power Efficiency 24.7 lm W-1
Device structure ITO/PEDOT:PSS (45 nm)/TFB (40 nm)/R-QDs:G-QDs* (18 nm, 1:9)/ZnMgO (40 nm)/Al (2 nm)/IZO (60 nm)/HATCN (20 nm)/TAPC (40 nm)/mCP (5 nm)/Firpic:mCPPO1 (30 nm)/TmPyPB (30 nm)/LiF (1 nm)/Al (100 nm) [5]
Colour white light emitting device White
Max. Power Efficiency 20.31 lm W-1
Max. EQE 26.02%

*For chemical structure information, please refer to the cited references.

Pricing


Grade Order Code Quantity Price
Sublimed >99.0% purity M2335A1 100 mg £250
Sublimed >99.0% purity M2335A1 250 mg £500
Sublimed >99.0% purity M2335A1 500 mg £850
Sublimed >99.0% purity M2335A1 1 g £1450

MSDS Documentation


mCPPO1 MSDSmCPPO1 MSDS Sheet

Literature and Reviews


  1. External Quantum Efficiency Above 20% in Deep Blue Phosphorescent Organic Light-Emitting Diodes, S. Jeon et al., Adv. Mater., 23 (12), 1436-1441 (2011); DOI: 10.1002/adma.201004372.
  2. Solution processed deep blue phosphorescent organic light-emitting diodes with over 20% external quantum efficiency, K. Yook et al., Org. Electronics, 12 (10); 1711-1715 (2011); DOI: 10.1016/j.orgel.2011.07.004.
  3. Highly efficient deep-blue phosphorescence from heptafluoropropyl-substituted iridium complexes, J. Kim et al., Chem. Commun., 51, 58-61 (2015); DOI: 10.1039/C4CC07768G.
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