Pricing
Grade Order Code Quantity Price
Sublimed (99.5% purity) M2175A1 250 mg
£266.3
Sublimed (99.5% purity) M2175A1 500 mg £426.2
Sublimed (99.5% purity) M2175A1 1 g
£681.9
General Information
CAS number 1030380-51-8
Full name
4,6-Bis(3,5-di(pyridin-4-yl)phenyl)-2-methylpyrimidine, 4,6-Bis(3,5-di-4-pyridinylphenyl)-2-methylpyrimidine
Chemical formula C37 H 26 N 6
Molecular weight 554.64 g/mol
Absorption λmax 250 nm in DCM
Fluorescence
λ max 410 nm in Film
HOMO/LUMO 4,6-Bis(3,5-di-4-pyridinylphenyl)-2-methylpyrimidine
Synonyms
Classification / Family
Pyrimidine derivatives, Highly efficient light-emitting diodes, Organic electronics, Electron-transport layer (ETL) materials, Hole-blocking layer (HBL) materials, Sublimed materials.
Product Details
Purity Sublimed 99.5% (HPLC)
Melting point 374 °C
Appearance White crystals/powder
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED Devices page.
Chemical structure of B4PymPm; CAS No. 1030380-51-8.
Applications
B4PymPm is an isomer to B2PymPm and B3PymPm. It has a 2-methylpyrimidine core structure with four pyridine pendants. It is electron-deficient and can be used in OLEDs and photovoltaics (e.g. perovskite solar cells) as an electron-transporting or hole-blocking layer material.
Due to its intermolecular hydrogen bonding, B4PyMPM molecules self-assemble in a horizontal orientation - parallel to the substrate, with a significantly large anisotropy. This self-assembly gives high molecular stacking in films with high π-orbital overlaps, which can significantly enhance charge-carrier mobility and transport.
Device structure ITO (110 nm)/HAT-CN (10 nm)/TAPC (40 nm)/TCTA (10 nm)/mCP (10 nm)/mCP:B4PyMPM :15 wt% FIrpic (20 nm)/B4PyMPM (50 nm)/Liq (0.8 nm)/Al (120 nm) [2]
Colour Blue
Max. Power Efficiency
79.8 lm W − 1
Max. Current Efficiency 41.3 cd/A
Max. EQE 17.3%
Device structure
ITO (110 nm)/TAPC (40 nm)/TCTA (10 nm)/mCP (10 nm)/mCP:50 wt% B4PyMPM :15 wt% FIrpic:0.2 wt% PO-01* (20 nm)/B4PyMPM (50 nm)/Liq (0.8 nm)/Al (120 nm) [2]
Colour
White
Max. Power Efficiency
105.0 lm W − 1
Max. Current Efficiency 83.6 cd/A
Max. EQE 28.1%
Device structure ITO (70 nm)/TAPC (75 nm)/TCTA (10 nm)/ TCTA:B4PYMPM :8 wt% Ir(ppy)2 tmd (30 nm)/B4PYMPM (50 nm)/LiF (0.7 nm)/Al (100 nm) [3]
Colour Yellow
Max. Power Efficiency 152.5 lm W− 1
Max. EQE 30.4%
Device structure ITO/HAT-CN (5 nm)/TAPC (30 nm)/TCTA (8 nm)/26DCzPPy:PO-01 (4 wt%, 2 nm)/26DCzPPy:B4PyMPM:FIrpic (1:1, 15 wt%, 20 nm)/
Colour White
Max. Power Efficiency 95.5 lm W− 1
Max. Current Efficiency 82.0 cd/A
Max. EQE 28.5%
*For chemical structure information, please refer to the cited references
Literature and Reviews
Influence of Substituted Pyridine Rings on Physical Properties and Electron Mobilities of 2-Methylpyrimidine Skeleton-Based Electron Transporters, H, Sasabe et al., Adv. Funct. Mater., 21, 336–342 (2011); DOI: 10.1002/adfm.201001252.
White Organic LED with a Luminous Efficacy Exceeding 100 lm W−1 without Light Out-Coupling Enhancement Techniques, S. Wu et al., Adv. Funct. Mater., 27, 1701314 (2017); DOI: 10.1002/adfm.201701314.
Highly Efficient, Conventional, Fluorescent Organic Light-Emitting Diodes with Extended Lifetime, H. Kim et al., Adv. Mater., 29, 1702159 (2017); DOI: 10.1002/adma.201702159.
High-Performance White Organic Light-Emitting Diodes with Simplified Structure Incorporating Novel Exciplex-Forming Host, Q. Tian et al., ACS Appl. Mater. Interfaces, 10, 39116−39123 (2018); DOI: 10.1021/acsami.8b17737.
Development of high performance OLEDs for general lighting, H. Sasabe et al., J. Mater. Chem. C, 1, 1699 (2013); DOI: 10.1039/c2tc00584k.
