Photovoltaic Substrate (8 Pixel) Overview and Schematic

The photovoltaic substrates have been developed to maximise performance and fabrication efficiency for a range of modern photovoltaic device types where ITO series resistance becomes critical.

Developed and evolved over a number of years these substrates have become the mainstay of our own research on organic photovoltaics and perovskite PV but are also used by customers around the world for a wide for a huge array of device types including:

  • Perovskite solar cells
  • Bulk heterojunction (solution processed) organic photovoltaics (OPV)
  • Planar heterojunction (vacuum processed) organic photovoltaics (OPV)
  • Copper Indium Gallium Selenide (CIGS) solar cells
  • Copper Zinc Tin Sulfide (CZTS) solar cells
  • Quantum dot solar cells

System Overview

The below diagrams show schematically how devices are built on the photovoltaic substrate. For more detailed instructions please see our perovskite video guide, OPV video guide, or written photovoltaic fabrication guide. There are also many variations of these architectures that can be built using the same substrate but below we have outlined the most common.

 

Step 1: Clean

Clean the ITO coated substrate using an electronic grade cleaning agent (such as Hellmanex) and organic wash routine to remove any surface particulates. Then ensure the surface is chemically clean and hydrophobic by using either sonication in a strong base such as NaOH or by using a UV Ozone cleaner.

Photovoltaic substrate ITO schematic
Photovoltaic substrate schematic showing the ITO layout with eight contact pads for the pixel electrodes and the counter-electrode bus bar to the four corner contacts.

 

Step 2: Deposit Interlayer

Deposit the hole transport layer (or electron transport layer if building inverted devices). If using solution processed layers such as PEDOT:PSS or ZnO solgels then this is typically done by spin coating, blade coating or spray coating followed by wiping the edges clean but a clean-room swab. If using vacuum deposition interlayers such as MoOx or BCP then this can be done by using our active area deposition mask.

Photovoltaic substrate coated with PEDOT:PSS
Schematic showing where the interlayer should be deposited (examples include PEDOT:PSS, MoOx, TiOx or ZnO). This can be done by vacuum processing using the active area deposition shadow mask or by solution processing by wiping the edges with a clean-room swab

 

Step 3: Deposit Active Layer

This can be done in the same way as step 2 above. However, if both layers are solution processed then care needs to be taken to ensure that orthogonal solvents are used so that the bottom layer isn't washed away when depositing the top layer. For help choosing orthogonal solvents use our solvents table which lists most of the common solvents used in organic and innovative electronics or alternatively contact our technical team.

Photovoltaic substrate coated with active layer eg. perovskite or OPV
Active layers such as perovskites, bulk heterojunctions, CIGS or quantum dots should be deposited in the same location as the interlayers. Additional interlayers can also be deposited on top.

 

Step 4: Deposit the top cathode (and any additional interlayers)

For non-inverted devices the top electrode (sometimes called the back contact) is often a combination of an electron interface such as calcium, LiF, C60 or BCP with a highly conductive overlayer (aluminum or silver). For inverted devices this is an hole interface such as MoOx with again a conductive back contact such as aluminium, silver or gold.

The same substrate can also be used with two different pixel arrangements just by changing the shadow mask (see cathode deposition masks). This can result in either eight small pixels for maximum statistical data or one large pixel for maximum area.

Photovoltaic substrate with eight small pixelsPhotovoltaic substrate with one large pixel
Schematic showing the photovoltaic substrates configured with either eight small pixels (left) or one large pixel (right). These are typically deposited by vacuum processing but solution processing is also possible.

 

As an alternative to vacuum processing, solution processed top cathodes can also be used such as the HTL Solar formulation of PEDOT:PSS.

 

Step 5: Encapsulate

The Ossila encapsulation epoxy can be used safely with a wide range of delicate or reactive materials from polymers to calcium and in conjunction with a glass coverslip provides hermetic encapsulation from the top and thereby can provide high lifetimes (up to 14,000 OPV lifetime in our labs).

Photovoltaic substrate after encapsulation
Schematic of the photovoltaic substrates after encapsulation using a glass coverslip and E131 encapsulation epoxy.

 

Step 6: Measure

For any lab based devices the active area of the substrates is one of the primary sources of uncertainty. However, by using an electrochemically etched aperture mask which has dimensional aperture tolerance of less than 10 microns this uncertainty can be significantly reduced.

Photovoltaic substrate measured with aperture mask and illumination
Schematic showing the finished photovoltaic device being measured in conjunction with an aperture mask to accurately define the active area.

 

It's possible to connect to the substrates in a variety of ways such as using electrical connection legs (or even crocodile clips). However, to make life easy we also provide push-fit test boards which can be mounted to an optical bench underneath the solar simulator to allow quick and simple measurements.

If using a large number of devices or performing lifetime measurements we also provide a single substrate multiplexing unit or multi-substrate multiplexing unit.

 

Optional Steps

Option 1: Add a bus bar

For any photovoltaic device the resistive loss scales with the current squared. As such, with modern thin films materials pushing current densities of over 20 mA/cm2 this can lead to nearly four times the resistive losses of older generation materials which could be up to a 5% of relative performance (up to 1% absolute power conversion efficiency for a 20% efficient device). To see details of these calculations see our photovoltaic resistive-losses white paper.

While the loss of a few percent may not make a huge difference when testing new materials on a day-to-day basis, when trying to get the best data you can for publication every little helps. Simply by adding a bus bar to the device it's possible to eliminate any unnecessary losses and can be deposited after cleaning with an additional evaporation of typically gold or silver using our photovoltaic substrate bus-bar mask (email info@ossila.com for a quotation for this mask).

Photovoltaic substrate with bus bar (optional)
Schematic of the optional bus-bar overlay (typically gold or silver) used to eliminate any unnecessary series resistance from the ITO.