TBPe

2,5,8,11-Tetra-tert-butylperylene (TBPe), a family member of perylene, has been widely used as a blue fluorescence emitter in OLED devices.

With the introduction of four steric tert-butyl groups to the perylene, electroluminescent devices using TBPe as a dopant have the benefit of electroluminescent color stability; this is  due to a lower degree of molecular aggregation tendency in the non-planar perylene structure.

The steric hindrance of the side groups also prevents the formation of exciplex and charge trapping, leading to higher efficiency of the electroluminescent devices.

General Information

* Measurable with an optical spectrometer, see our spectrometer application notes.

Product Details

* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.

Chemical Structure

Device Structure(s)

Device structure	ITO (120 nm)/PEDOT:PSS (60 nm)/mCP (30 nm)/CzAcSF:TBPe (25 nm)/TSPO1* (5 nm)/TPBi (30 nm)/LiF (1 nm)/Al (200 nm) [2]
Colour	Blue
Max Current Efficiency	23.7 cd/A
Max EQE	15.4%
Max. Power Efficiency	23.4 lm W-1

Device structure	ITO (120 nm)/PEDOT:PSS (60 nm)/mCP (30 nm)/CzAcSF:TBPe:TBRb (25 nm)/TSPO1* (5 nm)/TPBi (30 nm)/LiF (1 nm)/Al (200 nm) [2]
Colour	White
Max Current Efficiency	35.1 cd/A
Max EQE	14.0%
Max. Power Efficiency	36.2 lm W-1

Device structure	ITO/a-NPB (35 nm)/mCP (10 nm)/1 wt%-TBPe:15wt%-ACRSA:DPEPO (15 nm)/DPEPO (8 nm)/TPBi (57 nm)/LiF (0.8 nm)/Al (100 nm) [3]
Colour	Blue
Max Current Efficiency	27 cd/A
Max EQE	13.4%
Max. Power Efficiency	18 lm W-1

Device structure	ITO (120 nm)/PEDOT:PSS (60 nm)/TAPC (10 nm)/TCTA (10 nm)/mCP (10 nm)/DPEPO:50% CzAcSF:0.1% TBPe (25 nm)/TSPO1* (5 nm)/TPBI (30 nm)/LiF (1 nm)/Al (200 nm) [4]
Colour	Blue
Max Current Efficiency	29.8 cd/A
Max EQE	18.1
Max. Power Efficiency	31.2 lm W-1

Pricing

MSDS Documentation

TBPe MSDS sheet

Literature and Reviews

1. Electroluminescent Properties of Fully Substituted Ethylene Moieties, S. Kim et al., Mol. Cryst. Liq. Cryst., 458:1, 209-216 (2006); DOI: 10.1080/15421400600932371.
2. Host Engineering for High Quantum Effi ciency Blue and White Fluorescent Organic Light-Emitting Diode, W. Song et al., Adv. Mater., 27, 4358–4363 (2015); DOI: 10.1002/adma.201501019.
3. High-efficiency organic light-emitting diodes with fluorescent emitters, H. Nakanotani et al., Nat. Commun., 5:4016 (2014); DOI: 10.1038/ncomms5016.
4. High efficiency blue fluorescent organic light-emitting diodes using a conventional blue fluorescent emitter, I-H. Lee et al., J. Mater. Chem. C, 3, 8834 (2015); DOI: 10.1039/c5tc01626f.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.