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Product Code M441-500mg
Price $163 ex. VAT

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Rubrene, molecular semiconductor with high charge mobility

Applications in organic electronics (OLEDs and OFETs)


Rubrene, a molecule with a tetracene backbone and four appended phenyl rings, is one of the most studied molecular semiconductors due to its high charge mobility. Notably, room-temperature hole mobilities of the order of 20-40 cm2V-1s-1 have been measured for rubrene in single-crystal organic field-effect transistors (SC-OFET) [1]. It is widely used in organic electronics, especially organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs).

General Information

CAS number 517-51-1
Chemical formula C42H28
Molecular weight 532.67 g/mol
Absorption λmax 299 nm (in THF)
Fluorescence λem 553 nm (in THF)
HOMO/LUMO HOMO = -5.4 eV, LUMO = -3.2 eV
Synonyms 5,6,11,12-Tetraphenylnaphthacene
Classification / Family Hydrocarbons, OLEDs, Organic field-effect transistors (OFETs), Organic electronics

Product Details

Purity  >99.0%
Melting point 330-335 °C (lit.)
Colour Red powder/crystals

Chemical Structure

Rubrene, tetraphenylnaphthacene
Chemical Structure of 5,6,11,12-tetraphenylnaphthacene (Rubrene)

Device Structure(s)

Device structure ITO/NPB (70 nm)/ADN: 0.5% rubrene (30 nm)/Alq3 (50 nm)/MgAg [6]
Colour White white light emitting device
Max. Luminance 11,700 cd/m2
Max. Current Efficiency 3.7 cd/A
Max. Power Efficiency 1.72 lm W-1
Device structure ITO/TPD (50 nm)/BePP2 (5 nm)/TPD (4 nm)/BePP2:rubrene (5 nm)/TPD (4 nm)/Alq (10 nm)/Al [7]
Colour White white light emitting device
Max. Luminance 20,000 cd/m2
Max. Power Efficiency 1.11 lm W−1
Device structure ITO/NPB/CBP:3 wt%TBPe:1 wt% rubrene/Zn(BTZ)2:5 wt% Ir(piq)2(acac)/Zn(BTZ)2/Mg:Ag [8]
Colour White white light emitting device
Max. EQE 2.4%
Max. Luminance 23,000 cd/m2
Device structure ITO/NPB/rubrene in p-DMDPVBi:NPB/TPBi/LiF/Al [9]
Colour White white light emitting device
Max. Luminance 18,100  cd/m2
Max. Current Efficiency 10.6 cd/A
Device structure ITO/PVK:TPD (30 nm)/Zn(BTZ)2:0.05 wt.% rubrene (50 nm)/Al (100 nm) [10]
Colour White white light emitting device
Max. EQE 0.63%
Max. Luminance 4,048 cd/m2
Max. Current Efficiency 4.05 cd/A

Characterisation

HPLC of rubrene
HPLC trace of 5,6,11,12-tetraphenylnaphthacene (rubrene)

MSDS Documentation

Rubrene MSDSRubrene MSDS sheet

Literature and Reviews

  1. Organic field-effect transistors using single crystals, T. Hasegawa et al., Sci. Technol. Adv. Mater. 10, 024314 (2009), doi:10.1088/1468-6996/10/2/024314.
  2. Rubrene: The Interplay between Intramolecular and Intermolecular Interactions Determines the Planarization of Its Tetracene Core in the Solid State, C. Sutton et al., J. Am. Chem. Soc., 137, 8775-8782 (2015)
  3. Luminescence of Rubrene and DCJTB molecules in organic light-emitting devices, C-B. Moon et al., J. Luminescence, 146, 314-320, 2014.
  4. The effect of rubrene as a dopant on the efficiency and stability of organic thin film electroluminescent devices, Z. Zhang et al., J. Phys. D: Appl. Phys. 31, 32–35 (1998).
  5. Performance improvement of rubrene-based organic light emitting devices with a mixed single layer, Z. Wang et al., Appl Phys A 100: 1103–1108 (2010), DOI 10.1007/s00339-010-5710-4.
  6. Efficient and stable single-dopant white OLEDs based on 9,10-bis (2-naphthyl) anthracene, S. Tao et al., J. Luminance, 121(2), 568-572 (2006); doi:10.1016/j.jlumin.2005.12.053.
  7. Organic white light electroluminescent devices, S. Liu et al., Thin Solid Films, 363, 294-297 (2000); doi:10.1016/S0040-6090(99)01017-2. 
  8. Influence of Dopant Concentration on Electroluminescent Performance of Organic White-Light-Emitting Device with Double-Emissive-Layered Structure, M. Wu et al., Chin. Phys. Lett., 25, 294-297 (2008).
  9. Co-Host Comprising Hole-Transporting and Blue-Emitting Components for Efficient Fluorescent White OLEDs, Y-C. Chen et al., J. Electrochem. Soc., 159 (4) J127-J131 (2012); doi: 10.1149/2.092204jes.
  10. White organic light-emitting devices using Zn(BTZ)2 doped with Rubrene as emitting layer,
    J. Zheng et al., Chin. Sci. Bull., 50, 509-513 (2005); DOI: 10.1360/04wb0050.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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