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Product Code M2122A1-250mg
Price $438 ex. VAT

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PXZ-DPS, ideal green emitter for TADF-OLED devices

High photo-luminescence quantum yields and purity (>99.0%)


10,10′-(sulfonylbis(4,1-phenylene))bis(10H-phenoxazine) (PXZ-DPS), possess a structure of a weak electron-accepting diphenylsulfone and strong electron-donating acridine moieties. It is used as a TADF green emitter or dopant, and has a small ΔEST of less than 0.1 eV, a short lifetime of less than 3.1 µs.

Like DMAC-DPS, PXZ-DPS has high photo-luminescence quantum yields (PLQY) in devices even with the change of host materials. It is an ideal candidate for applications in green TADF-OLED devices with biploar charge-transporting capability.

General Information

CAS number 1477511-57-1
Full name 10-(4-(4-(10H-Phenoxazin-10-yl)phenylsulfonyl)phenyl)-10H-phenoxazine
Chemical formula C36H24N2O4S
Molecular weight 580.65 g/mol
Absorption n/a
PL λem 507 nm in toluene
HOMO/LUMO HOMO = 5.59 eV, LUMO = 2.79 eV; T1=2.74 eV, ΔEST = 0.08 eV [1]
Synonyms DPS-PXZ
Classification / Family Acridine derivatives, TADF green emitter, TADF green host materials, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point TGA > 220 °C (0.5% weight loss)
Appearance Off-white powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

PXZ-DPS chemical structure
Chemical structure of PXZ-DPS

Device Structure(s)

Device structure ITO/a-NPD (30 nm)/TCTA (20 nm)/CzSi (10 nm)/PXZ–DPS:DPEPO (20 nm)/DPEPO (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al [2]
Colour Green green light emitting device
Max EQE 17.6%
Device structure ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Green green light emitting device
Max EQE 19.3%
Max. Power Efficiency 48.5 lm W-1
Device structure ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:PhCzTRz:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Green green light emitting device
Max EQE 24%
Max. Power Efficiency 71.4 lm W-1

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2122A1 250 mg £350
Sublimed (>99.0% purity) M2122A1 500 mg £620
Sublimed (>99.0% purity) M2122A1 1 g £1000

MSDS Documentation

PXZ-DPS MSDSPXZ-DPS MSDS sheet

Literature and Reviews

  1. Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence, Q. Zhang et al., Nat. Photonics, 8, 326–332 (2014); DOI: 10.1038/nphoton.2014.12.
  2. Blocking Energy-Loss Pathways for Ideal Fluorescent Organic Light-Emitting Diodes with Thermally Activated Delayed Fluorescent Sensitizers, D. Zhang et al., Adv. Mater., 30, 1705250(2018); DOI: 10.1002/adma.201705250.
  3. Recent progress of green thermally activated delayed fluorescent emitters, Y. Im et al., J. Info. Display, 18:3, 101-117 (2017); DOI: 10.1080/15980316.2017.1333046.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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