PXZ-DPS


Order Code: M2122A1
Not in stock

Pricing

 Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2122A1 250 mg £270.00
Sublimed (>99.0% purity) M2122A1 500 mg £464.00
Sublimed (>99.0% purity) M2122A1 1 g £742.00

General Information

CAS number 1477511-57-1
Full name 10-(4-(4-(10H-Phenoxazin-10-yl)phenylsulfonyl)phenyl)-10H-phenoxazine
Chemical formula C36H24N2O4S
Molecular weight 580.65 g/mol
Absorption n/a
PL λem 507 nm in toluene
HOMO/LUMO HOMO = 5.59 eV, LUMO = 2.79 eV; T1=2.74 eV, 
ΔEST = 0.08 eV [1]
Synonyms DPS-PXZ
Classification / Family Acridine derivatives, TADF green emitter, TADF green host materials, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point TGA > 220 °C (0.5% weight loss)
Appearance Off-white powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

 

pxz-dps chemical structure
Chemical structure of PXZ-DPS; CAS No. 1477511-57-1.

 

Applications

10,10′-(sulfonylbis(4,1-phenylene))bis(10H-phenoxazine) (PXZ-DPS), posses a structure of a weak electron-accepting diphenylsulfone and strong electron-donating acridine moieties. It is used as a TADF green emitter or dopant, and has a small ΔEST of less than 0.1 eV, a short lifetime of less than 3.1 µs.

Like DMAC-DPS, PXZ-DPS has high photo-luminescence quantum yields (PLQY) in devices even with the change of host materials. It is an ideal candidate for applications in green TADF-OLED devices with biploar charge-transporting capability.

Device structure ITO/a-NPD (30 nm)/TCTA (20 nm)/CzSi (10 nm)/PXZ–DPS:DPEPO (20 nm)/DPEPO (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al [2]
Colour Green  green
Max EQE 17.6%
Device structure >ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Green  green
Max EQE 19.3%
Max. Power Efficiency 48.5 lm W-1
Device structure ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:PhCzTRz:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2]
Colour Green green
Max EQE 24%
Max. Power Efficiency 71.4 lm W-1

*For chemical structure information, please refer to the cited references.

 

Literature and Reviews

  1. Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence, Q. Zhang et al., Nat. Photonics, 8, 326–332 (2014); DOI: 10.1038/nphoton.2014.12.
  2. Blocking Energy-Loss Pathways for Ideal Fluorescent Organic Light-Emitting Diodes with Thermally Activated Delayed Fluorescent Sensitizers, D. Zhang et al., Adv. Mater., 30, 1705250(2018); DOI: 10.1002/adma.201705250.
  3. Recent progress of green thermally activated delayed fluorescent emitters, Y. Im et al., J. Info. Display, 18:3, 101-117 (2017); DOI: 10.1080/15980316.2017.1333046.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.