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Product Code M2313A1-250mg
Price $413 ex. VAT

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3-(4,6-Diphenyl-1,3,5-triazin-2-yl)-9-phenyl-9H-carbazole (DPTPCz) is an isomer to  Cab-Ph-TRZ with triazine as electron-deficient and carbazole as electron-rich moieties. The difference between them is that for DPTPCz, triazine is directly attached to the carbazole unit while there is a phenyl spacer between the trazine and carbazole units for Cab-Ph-TRZ.

DPTPCz is used as a phosphorescent host material for blue, green and red light-emitting diodes. The bipolar host can achieve balanced charge injection/transport in phosphorescent organic light emitting diodes (PhOLEDs). Nearly 100% triplet harvesting in conventional fluorophor-based organic light-emitting devices is realized through energy transfer from TAPC:DPTPCz exciplex with C545T-doped device. The device showed a maximum current efficiency of 44.0 cd A-1, a maximum power efficiency of 46.1 lm W-1, and a maximum external quantum efficiency of 14.5% [3]

General Information

CAS number 1313391-57-9
Full name 3-(4,6-Diphenyl-1,3,5-triazin-2-yl)-9-phenyl-9H-carbazole
Chemical formula C33H22N4
Molecular weight 474.55 g/mol
Absorption λmax 305, 353 nm in Ethyl acetate
Fluorescence λmax 416 nm in Ethyl acetate
HOMO/LUMO HOMO 5.69 eV, LUMO 2.76 eV, ET = 2.78 eV[1]
Synonyms DPTPCz
Classification / Family Triazine derivatives, Bipolar host materials, PHOLEDs host materials, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point Tg = 86 ℃
Appearance White powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

DPTPCz chemical structure, CAS# 1313391-57-9

Chemical structure of 3-(4,6-Diphenyl-1,3,5-triazin-2-yl)-9-phenyl-9H-carbazole (DPTPCz), CAS 1313391-57-9

Device Structure(s)

Device structure ITO/NPB (30 nm)/TCTA (10 nm)/DPTPCz:Ir(ppy)2acac (7 wt%, 30 nm)/TPBi (30 nm)/LiF (1 nm)/Al [1]
Colour Green green
Max. EQE 21.2%
Max. Current Efficiency 65.7 cd/A

 

Device structure ITO/NPB (30 nm)/TCTA (10 nm)/DPTPCz:FIrPic (12 wt%, 30 nm)/TAZ (30 nm)/LiF (1 nm)/Al [1]
Colour Blue blue
Max. EQE 14.4%
Max. Current Efficiency 27.4 cd/A

 

Device structure ITO/NPB (30 nm)/TCTA (10 nm)/DPTPCz:Ir(2-phq)3(6%; 30 nm)/TPBi (30 nm)/LiF (1 nm)/Al (100 nm) [2]
Colour Red red
Max. Luminance 22,480 cd/m2
Max. Current Efficiency 31.66 cd/A

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2313A1 250 mg £330
Sublimed (>99.0% purity) M2313A1 500 mg £520
Sublimed (>99.0% purity) M2313A1 1 g £850

MSDS Documentation

DPTPCz MSDSDPTPCz MSDS sheet

Literature and Reviews

  1. Novel bipolar host materials based on 1,3,5-triazine derivatives for highly efficient phosphorescent OLEDs with extremely low efficiency roll-off, X. Liu et al., Phys. Chem. Chem. Phys., 14, 14255-14261 (2012); DOI: 10.1039/C2CP41542A.
  2. Highly efficient green and red phosphorescent OLEDs using novel bipolar blue fluorescent materials as hosts, J. Xiao et al., Synth. Met., 193, 89-93 (2014); DOI: 10.1016/j.synthmet.2014.04.001.
  3. Nearly 100% Triplet Harvesting in Conventional Fluorescent Dopant-Based Organic Light-Emitting Devices Through Energy Transfer from Exciplex, X. Liu et al., Adv. Mater., 27 (12); 2025-2030 (2015); DOI: 10.1002/adma.201500013.
  4. Prediction and Design of Efficient Exciplex Emitters for High-Efficiency, Thermally Activated Delayed-Fluorescence Organic Light-Emitting Diodes, X. Liu et al., Adv. Mater., 27 (14); 2378-2383 (2014); DOI: 10.1002/adma.201405062..

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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