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Product Code M2343A1-100mg
Price $300 ex. VAT

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DMAC-TRZ, sky blue TADF emitter for highly efficient doped and non-doped OLED devices

High purity (>99.0%) and high PLQY in doped and neat films


DMAC-TRZ, 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine, has a bipolar structure containing both 2,4,6-triphenyl-1,3,5-triazine (TRZ) as the electron-accepting and 9,9-dimethyl-9,10-dihydroacridine (DMAC) as the electron-donating moieties. 

DMAC-TRZ is a well-known sky blue TADF emitter for both highly efficient doped and non-doped OLED devices, with high maximum external quantum efficiencies (EQE) over 20%. It shows not only high photoluminescence quantum yield (PLQY, ≥90%) in doped films but also high PLQY (83%) in neat films with low concentration quenching.

General Information

CAS number 1628752-98-6
Full name 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine
Chemical formula C36H28N4
Molecular weight 516.63 g/mol
Absorption λmax 390 nm in Toluene
PL λem 425 nm in Toluene
HOMO/LUMO HOMO = 5.92 eV, LUMO = 2.92 eV; T1=2.91 eV[1]
Synonyms
Classification / Family Acridine derivatives, Sky-blue TADF emitter, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point mp = 234 °C (DSC), Tg = 91 °C
Appearance Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

chemical structure of dmac-trz, cas 1628752-98-6
Chemical structure of DMAC-TRZ, 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine, CAS 1628752-98-6.

Device Structure(s)

Device structure ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/mCPCN:DMAC-TRZ 8 wt.% (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour greenish-blue light emitting device Greenish-Blue
Max Current Efficiency 66.8 cd/A 
Max. Power Efficiency 65.6 Im/W
Max. EQE 26.5%
Device structure ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/DMAC-TRZ (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour greenish-blue light emitting device Greenish-Blue
Max Current Efficiency 61.6 cd/A 
Max. Power Efficiency 45.7 Im/W
Max. EQE 20.0%
Device structure ITO/PEDOT:PSS/X-OTPD* (20 nm)]/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour greenish-blue light emitting device Greenish-Blue
Max Current Efficiency 30.4 cd/A 
Max. Power Efficiency 24.5 Im/W
Max. EQE 8.8%
Device structure ITO/PEDOT:PSS/X-QUPD (10 nm)/X-DCDPA* (10 nm)/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour greenish-blue light emitting device Greenish-Blue
Max Current Efficiency 79.6 cd/A 
Max. Power Efficiency 48.6 Im/W
Max. EQE 25.9%

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2343A1 100 mg £240
Sublimed (>99.0% purity) M2343A1 250 mg £480
Sublimed (>99.0% purity) M2343A1 500 mg £760
Sublimed (>99.0% purity) M2343A1 1 g £1250

MSDS Documentation

DMAC-TRZ MSDSDMAC-TRZ MSDS sheet

Literature and Reviews

  1. Versatile Thermally Activated Delayed Fluorescence Emitter for Both Highly Efficient Doped and Non‐Doped Organic Light Emitting Devices, W. Tsai et al., Chem. Commun., 51, 13662-13665 (2015); DOI: 10.1039/C5CC05022G.
  2. Solution-Processed Thermally Activated Delayed Fluorescent OLED with High EQE as 31% Using High Triplet Energy Crosslinkable Hole Transport Materials, K. Tsai et al., Adv. Funct. Mater., 29 (15), 1901025 (2019); DOI: 10.1002/adfm.201901025.
  3. Highly Efficient Organic Light Emitting Diode with 37% External Quantum Efficiency Using Thermally Activated Delayed Fluorescence from Spiroacridine-Triazine Hybrid Emitter Simultaneously Having Unitary Photoluminescence and Strongly Horizontal Emitting Dipoles, T. Lin et al., Adv. Mater., 28 (32), 6976-6983 (2016); DOI: 10.1002/adma.201601675.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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