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DMAC-TRZ

DMAC-TRZ
Product Code M2343A1
Price £183.00 ex. VAT
£ GBP

DMAC-TRZ, 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine, has a bipolar structure containing both 2,4,6-triphenyl-1,3,5-triazine (TRZ) as the electron-accepting and 9,9-dimethyl-9,10-dihydroacridine (DMAC) as the electron-donating moieties. 

DMAC-TRZ is a well-known sky blue TADF emitter for both highly efficient doped and non-doped OLED devices, with high maximum external quantum efficiencies (EQE) over 20%. It shows not only high photoluminescence quantum yield (PLQY, ≥90%) in doped films but also high PLQY (83%) in neat films with low concentration quenching.

General Information

CAS number 1628752-98-6
Full name 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine
Chemical formula C36H28N4
Molecular weight 516.63 g/mol
Absorption λmax 390 nm in Toluene
PL λem 425 nm in Toluene
HOMO/LUMO HOMO = 5.92 eV, LUMO = 2.92 eV; T1=2.91 eV[1]
Synonyms
Classification / Family Acridine derivatives, Sky-blue TADF emitter, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point mp = 234 °C (DSC), Tg = 91 °C
Appearance Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

chemical structure of dmac-trz, cas 1628752-98-6
Chemical structure of DMAC-TRZ, 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine, CAS 1628752-98-6.

Device Structure(s)

Device structure ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/mCPCN:DMAC-TRZ 8 wt.% (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour Blue - greenish blue-greenish
Max Current Efficiency 66.8 cd/A 
Max. Power Efficiency 65.6 Im/W
Max. EQE 26.5%
Device structure ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/DMAC-TRZ (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour Blue - greenish blue-greenish
Max Current Efficiency 61.6 cd/A 
Max. Power Efficiency 45.7 Im/W
Max. EQE 20.0%

 

Device structure ITO/PEDOT:PSS/X-OTPD* (20 nm)]/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour Blue - greenish blue-greenish
Max Current Efficiency 30.4 cd/A 
Max. Power Efficiency 24.5 Im/W
Max. EQE 8.8%

 

Device structure ITO/PEDOT:PSS/X-QUPD (10 nm)/X-DCDPA* (10 nm)/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour Blue - greenish blue-greenish
Max Current Efficiency 79.6 cd/A 
Max. Power Efficiency 48.6 Im/W
Max. EQE 25.9%

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2343A1 100 mg £183.00
Sublimed (>99.0% purity) M2343A1 250 mg £366.00
Sublimed (>99.0% purity) M2343A1 500 mg £586.00
Sublimed (>99.0% purity) M2343A1 1 g £938.00

MSDS Documentation

DMAC-TRZ MSDSDMAC-TRZ MSDS sheet

Literature and Reviews

  1. Versatile Thermally Activated Delayed Fluorescence Emitter for Both Highly Efficient Doped and Non‐Doped Organic Light Emitting Devices, W. Tsai et al., Chem. Commun., 51, 13662-13665 (2015); DOI: 10.1039/C5CC05022G.
  2. Solution-Processed Thermally Activated Delayed Fluorescent OLED with High EQE as 31% Using High Triplet Energy Crosslinkable Hole Transport Materials, K. Tsai et al., Adv. Funct. Mater., 29 (15), 1901025 (2019); DOI: 10.1002/adfm.201901025.
  3. Highly Efficient Organic Light Emitting Diode with 37% External Quantum Efficiency Using Thermally Activated Delayed Fluorescence from Spiroacridine-Triazine Hybrid Emitter Simultaneously Having Unitary Photoluminescence and Strongly Horizontal Emitting Dipoles, T. Lin et al., Adv. Mater., 28 (32), 6976-6983 (2016); DOI: 10.1002/adma.201601675.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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