Perovskite Frequently Asked Questions (FAQ)
Our technical support team receive enquiries about perovskite photovoltaic fabrication on a regular basis and as such, we've collated some of the most common questions here which you may find of use when using I101 or I201 perovskite precursor inks.
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Which dehumidifier do you use in your lab to reduce the humidity to 30-40% rh?
We are currently using a 10L Igenix Portable dehumidifier and find this works very well for a small room with a recirculating fume hood rather than extracting fume hood. The volume of our perovskite lab is about 45 cubic meters (about 18 square meters with ceiling height of 2.5 meters).
How long will the Perovskite solutions be stable for?
The solutions are dissolved, stored, decanted and sealed in a nitrogen filled glovebox. The individual lots of packaged in a 2 ml amber vial with a PTFE cap, as can be seen below. They are securely fastened and an additional protective layer of parafilm is used around the lid. This should therefore allow the solutions to be stable in ambient conditions. Should you wish to store the solutions for very long times (many months) then we would still advise storing the solutions in a nitrogen filled glovebox if possible.
How do I clean my equipment after spinning the Perovskite ink?
For spinning outside in air (i.e. I101), our technique is to clean the spin coater using a 10% NaOH solution. This cleanly and effectively removes any residue material. Please remember to clean the NaOH off with DI water afterwards.
Using I201 inside the glovebox, we want to restrict the presence of moisture within the glovebox. Therefore, using small quantities of neat DMF will efficiently remove the residue.
How do I remove the Perovskite film from certain areas on the substrate (i.e. for the deposition of the cathode)?
Our technique has been to wipe the substrate using a dry cleaning swab after spinning (for I101 based devices), or using a cleaning swab dipped in DMF (for I201 devices - note that devices should be on the hotplate during this particular process to prevent the DMF solution from seeping into the entire Perovskite film).
What is used to similarly remove the PC70BM layer?
A cleaning swab dipped in chlorobenzene (CB) is sufficient to remove the PC70BM film. This does not require the device to be on a hotplate as there is little risk of the CB solvent seeping into the rest of the PC70BM film.
Where should the Perovskite films be kept while preparing the PC70BM solution (which requires a few hours heating)?
The best routine we have employed is to prepare the PC70BM solution either at the start of the experiment (i.e. before cleaning substrates) or the night before. This will provide the solution ample time on the hotplate to dissolve prior to its use. It will also prevent the Perovskite films from having to experience any "storage" time and allow a fluent fabrication procedure to be performed.
What is the difference between the various substrate systems (i.e. pixelated anode substrate, pixelated cathode substrate and the Edgeless 8-pixel substrate systems)?
- The pixelated anode substrate system (S101) was our first substrate design enabling 6 pixels per device and originating from the world of OLEDs which are higher voltage and lower current meaning that series resistance is less important. Here the pixels act as the anodes while a cathode strip is thermally evaporated through a shadow mask to connect with the upper ITO strip for extracting electrons.
- The pixelated cathode substrate system (S171), on the other hand, has a single large area anode with multiple thermally evaporated cathodes. This re-design of the substrate system affords a greater degree of flexibility for the multitude of device architectures. It also provides a reduction in the sheet resistance of the substrate which is more important for PV than OLED as there is a much higher current density. However, we then improved this design further and it evolved into the 8 pixel edgeless photovoltaic substrate system.
- The edgeless 8 pixel photovoltaic substrate system (S211) (our newest design) capitalises on the flexibility and reduced sheet resistance from the pixelated cathode substrate system all the while enabling an additional 2 pixels per substrate. Furthermore, the design enables all pixels to exist in the centre of the substrate thereby removing the typical lower performing edge pixels. An additional benefit from removing the edge pixels is a reduction of potential edge ingress thus increasing device stability. As such, we currently recommend the edgeless 8 pixel substrates for PV devices.
Why should I101 be spun in air, rather than in a nitrogen/argon filled glovebox?
We have found that humidity plays a crucial role during the spinning and annealing stages of the Perovskite device fabrication. Substrate coverage and wettability, as well as crystal formation are just a few considerations required for Perovskite films. In our humidity video we explored the differences from spinning in low or high humidity environments. Our Perovskite ink I101 has been specifically designed to perform best when processed and annealed in air (with a humidity of 30-40% rh).
Note that I201 is optimised for use in a glovebox and performance is reduced by the presence of air.