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[60]PCBH

CAS Number 850807-50-0

Fullerene Acceptors


Product Code M821-250mg
Price $313 ex. VAT

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[60]PCBH, fullerene acceptor used to enhance the performance of OPV devices

High purity (>99%), low price, and available to buy online for priority dispatch 


[60]PCBH, Phenyl-C61-butyric acid hexyl ester is a fullerene derivative of C60 that is used as an electron acceptor material in organic photovoltaic (OPV) solar cells. It is more soluble than PCBM, which makes it more desirable when higher concentrations of the acceptor unit are required. The higher solubility and longer carbon chain also makes [60]PCBH more compatible with polymers so that phase separations can be better controlled, resulting in improved film morphology and higher performing OPV devices.

[60]PCB-Cn (n = 4, 6, 8) have been also a popular candidate for perovskite solar cells applications.

Soluble fullerene acceptor

Soluble fullerene acceptor

For high efficient OPV applications

compatible with polymers

Improves film morphology and OPVs performance

More compatible with polymers

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High purity

High purity

>99% High purity

Device Structure ITO/PEDOT:PSS (80 nm)/p-TPD (20 nm)/CH3NH3PbI3 (320 nm)/PCBM (50 nm)/Ba:Ag [1] ITO/PEDOT:PSS (80 nm)/p-TPD (20 nm)/CH3NH3PbI3(320 nm)/PCBH (50 nm)/Ba:Ag [1]
JSC (mA cm-2) 15.68 15.92
VOC (V) 1.087 1.097
FF (%) 80 79
PCE 13.58 13.75
Device Structure TCO/PEDOT:PSS/P3HT:PCBH/Al [2]
JSC (mA cm-2) 10.4
VOC (V) 0.59
FF (%) 61.4
PCE  3.8

Note: We also have [60]PCBB (Phenyl-C61-butyric acid butyl ester) available, please enquire for information if interested.

General Information

CAS Number 850807-50-0
Chemical Formula C77H24O2
Molecular Weight 981.01 g/mol
HOMO/LUMO No data available; comparable to PCBM (HOMO 6.1 = eV, LUMO = 3.7 eV)
Synonyms

PCBH
[60]PCBH
[60]PCB-C6, Phenyl-C61-butyric acid hexyl ester
[6,6]-Phenyl-C61 butyric acid hexyl ester

Classification / Family Fullerene derivatives, Electron transport materials (ETM), Acceptor materials, Organic photovoltaics (OPV), Organic electronics

Chemical Structure

[60]PCBH chemical structure, CAS 850807-50-0
[60]PCBH chemical structure, CAS 850807-50-0

Product Details

Purity >99%
Melting Point / Thermal Analysis Differential Scanning Calorimetry (DSC): Tg = 60.9 °C
Colour Dark brown powder

MSDS Documentation

[60]PCBH MSDS[60]PCBH MSDS Sheet

Pricing

Product Code Purity Quantity Price
M821 >99% 250 mg £250

Literature and Reviews

  1. Fullerene imposed high open-circuit voltage in efficient perovskite based solar cells, L. Gil-Escrig et al., J. Mater. Chem. A, 4, 3667 (2016); DOI: 10.1039/c5ta10574a.
  2. IMPROVEMENT OF EFFICIENCY OF POLYMER SOLAR CELLS WITH SOLUBLE FULLERENE DERIVATIVES, H-J. Lee et al., IEEE, 233-235 (2006).

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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