PDINO
PDINO, allows high work function metals to act as efficient cathodes
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PDINO, bearing amino N-oxide group on perylenediimide (PDI) with π-delocalized planar structures and high electron affinities, is widely used as cathode interlayer materials. While working great with Al as the cathode, PDINO also allow high work function metals (such as Au and Ag) to act as efficient cathodes.
With a measured conductivity of 7.6 × 10-5 S/cm, PDINO has four orders of magnitude higher than that of the well-known cathode interlayer PFN (6.9 × 10-9 S/cm). Organic photovoltaic cell with 17% efficiency was achieved with PDINO as the cathode interlayer material by employing PBDB-TF (PM6):BTP-4Cl-12 (Y7-BO) as the active layer.
Device structure: ITO/PEDOT:PSS/PBDB-TF (PM6):BTP-4Cl-12 (Y7-BO)/PDINO/Al [3]
| Thickness (nm) | VOC (V) | JSC (mA cm-2) | FF (%) | PCE (%) |
| 100 | 0.858 | 25.6 | 77.6 | 17.0 |
General Information
| Full name | N,N'-Bis(N,N-dimethylpropan-1-amine oxide)perylene-3,4,9,10-tetracarboxylic diimide |
| Purity | 98% (1H NMR) |
| Synonyms | 3,3'-(1,3,8,10-Tetraoxoanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-2,9(1H,3H,8H,10H)-diyl)bis(N,N-dimethylpropan-1-amine oxide) |
| Chemical formula | C34H32N4O6 |
| Molecular weight | 592.64 g/mol |
| CAS number | 1558023-86-1 |
| HOMO / LUMO | HOMO = -6.21 eV LUMO = -3.63 eV [1] |
| Melting point | 103.4 °C (TGA, 5% weight loss) |
| Form | Reddish brown powder/crystals |
| Absorption | λmax 468 nm (film) |
| Solubility/processing solvents | Methanol, ethanol, trifluoroethanol |
| Classification / Family | Perylene diimide (PDI), Organic semiconducting materials, Organic Photovoltaics, OLED, Small molecule electrolyte |
Chemical Structure
MSDS Documentation
PDINO MSDS sheetPricing
| Batch | Quantity | Price |
| M2236A1 | 250 mg | £360 |
| M2236A1 | 500 mg | £600 |
| M2236A1 | 1 g | £1000 |
| M2236A1 | 5 g | £4400 |
Literature and Reviews
- Cathode engineering with perylene-diimide interlayer enabling over 17% efficiency single-junction organic solar cells, J. Yao et al., Nat. Commun., 11:2726 (2020); DOI: 10.1038/s41467-020-16509-w.
- Perylene diimides: a thickness-insensitive cathode interlayer for high performance polymer solar cells, Z. Zhang et al., Environ. Sci., 7, 1966 (2014); DOI: 10.1039/c4ee00022f.
- Organic photovoltaic cell with 17% efficiency and superior processability, Y. Cui et al., Natl Sci Rev, 7(7), 1239–1246 (2020); DOI: 10.1093/nsr/nwz200.
- A non-fullerene small molecule processed with green solvent as an electron transporting material for high efficiency p-i-n perovskite solar cells, J. Miao et al., Org. Electonics, 52, 200-205 (2018); DOI: 10.1016/j.orgel.2017.10.028.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.