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L8-BO-F


Product Code M2306A1
Price $260.00 ex. VAT

L8-BO-F, highly efficient non-fullerene acceptor

Higher solubility and morphoplogy than L8-BO, giving impressive device performances


Structurally, L8-BO-F has the same thienothienopyrrolo-thienothienoindole (TTP-TTI) core units as L8-BO (L8-BO-2F) with mono-fluorinated peripheral 2-(5 or 6-fluoro-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile end-groups.

L8-BO-F is another highly efficient non-fullerene acceptor that belongs to Y6 family. Similar to L8-BO, it has a branched 2-butyloctyl side chain which not only promotes solubility but also improves the morphology to achieve better packed film with higher intermolecular stackings, balanced charge transport and to reduce charge combination. L8-BO-F is also believed to suppresses the non-radiative recombination leading to a reduce the voltage loss.

Outstanding device performance with PCE of 18.66% has achieved while a binary BTP-eC9 and L8-BO-F non-fullerene acceptors were used with polymer donor PM6. The polymer donor and mixed NFAs give complementary absorptions in the visible and NIR region with well matched energy alignment.

Device structure: ITO/PEDOT:PSS/PM6:BTP-eC9:L8-BO-F (1:1.2)/PNDIT-F3N/Ag

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
100 0.853 27.35 80.00 18.66

General Information

Purity >99% (1H NMR)
Full name 2,2'-((2Z,2'Z)-((12,13-bis(2-ethylhexyl)-3,9-(2-butyloctyl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2",3’':4’,5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(5 or 6-fluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile
Synonyms L8-BO-F
Chemical formula C84H92F2N8O2S5
Molecular weight 1444.00 g/mol
CAS number n.a.
HOMO / LUMO HOMO = -5.59 eV, LUMO = -3.85 eV [1]
Solubility Chloroform, chlorobenzene and dichlorobenzene
Form Dark blue powder/crystal
Classification / Family BTP series NFAs, n-type non-fullerene electron acceptors, Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptor, Organic photovoltaics, Polymer solar cells, NF-PSCs.

Chemical Structure

L8-BO-F chemical structure, NFAs
Chemical structure of L8-BO-F, highly efficient non-fullerene acceptor.

MSDS Documentation

L8-BO-F MSDS sheetL8-BO-F MSDS sheet

Pricing

Batch Quantity Price
M2306A1 50 mg £200.00
M2306A1 100 mg £300.00
M2306A1 250 mg £600.00
M2306A1 500 mg £1080.00
M2306A1 1 g £1950.00
M2306A1 5 g / 10 g* Please contact us for details

*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Literature and Reviews

  1. A Well-Mixed Phase Formed by Two Compatible Non-Fullerene Acceptors Enables Ternary Organic Solar Cells with Efficiency over 18.6%, Y. Cai et al., Adv. Mater., 33 (33); 2101733 (2021); DOI: 10.1002/adma.202101733.
  2. A facile strategy for third-component selection in non-fullerene acceptor-based ternary organic solar cells, Y. Li et al., Energy Environ. Sci., 14, 5009-5016 (2021); DOI: 10.1039/D1EE01864G.
  3. Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells, C. Li et al., Nat. Energy, 6, 605–613 (2021); DOI: 10.1038/s41560-021-00820-x.
  4. High-efficiency organic solar cells with low voltage loss induced by solvent additive strategy, J. Song et al., Matter, 4 (7), 2542-2552 (2021); DOI: 10.1016/j.matt.2021.06.010.
  5. 18.77 % Efficiency Organic Solar Cells Promoted by Aqueous Solution Processed Cobalt(II) Acetate Hole Transporting Layer, H. Meng et al., Angew. Chem, 133 (41); 22728-22735 (2021); DOI: 10.1002/ange.202110550.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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