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Product Code M2082A3-100mg
Price $500 ex. VAT

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PNDI(2HD)2T, polymer acceptor in high performance all-PSCs

High purity polymer available for fast, secure dispatch


PNDI(2HD)2T, also known as P(NDI2HD-T2), copolymer of naphthalene and bithiophene, is used as a polymer acceptor in high performance all-PSCs.

Compared to PNDI(2OD)2T, PNDI(2HD)2T exhibits a higher degree of crystalline behaviours. This facilitates superior 3D charge-transport between polymer donor and acceptor materials, resulting in enhanced device performance for all-PSCs. When PNDI-bithiophene copolymers with different side-chain length were compared, the maximum µe,FET value was identified as 0.39, 1.22 and 1.90 cm2 V−1 s−1 for PNDI(2DT)2T, PNDI(2OD)2T, and PNDI(2HD)2T respectively [2].

Luminosyn™ PNDI(2HD)2T

Luminosyn™ PNDI(2HD)2T is now available.

High molecular weight and high purity
PNDI(2HD)2T is purified via Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Large quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly{[N,N'-bis(2-hexyldecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}
Synonyms
  • P(NDI2HD-T2)
  • Polynaphthalene diimide-bithiophene
Chemical formula (C54H72N2O4S2)n
CAS number 1459168-70-7
HOMO / LUMO HOMO = -5.80 eV, LUMO = -3.82 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, Organic photovoltaics, All-polymer solar cells (All-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility (10mg/mL) Chlorobenzene / dichlorobenzene (1:1)

Chemical Structure

P(NDI2HD-2T)
Chemical structure of PNDI(2HD)2T

MSDS Documentation

PNDI(2HD)2T MSDSPNDI(2HD)2T MSDS sheet

Pricing

Batch Quantity Price
M2082A1/A2 100 mg £400
M2082A1/A2 250 mg £800
M2082A1/A2 500 mg £1450
M2082A2 1 g £2600

Batch details

Batch Mw PDI Stock Info
M2082A1 ≥50,000 ≤3 Discontinued
M2082A2 147,102 2.47 Discontinued
M2082A3 143,634 1.93 In stock

Literature and Reviews

  1. Rationally Designed Donor–Acceptor Random Copolymers with Optimized Complementary Light Absorption for Highly Efficient All-Polymer Solar Cells, S. Kim et al., Adv. Funct. Mater., 27, 1703070 (2017); DOI: 10.1002/adfm.201703070.
  2. Side Chain Optimization of Naphthalenediimide–Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells, W. Lee et al., Adv. Funct. Mater., 26, 1543–1553 (2016); DOI:10.1002/adfm.201504191.
  3. Controlling Molecular Orientation of Naphthalenediimide-​Based Polymer Acceptors for High Performance All-​Polymer Solar Cells, J. Jung et al., Adv. Energy Mater., 6 (15), 1600504 (2016), DOI:10.1002/aenm.201600504.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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