PNDI(2HD)2T (high-mobility n-type polymer)


Order Code: M2082A1
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PNDI(2HD)2T is now available featuring:

  • Higher molecular weights and high purityPNDI(2HD)2T is purified via Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere - higher molecular weights and higher purity normally gives better device performance
  • Larger-quantity orders (so you can plan your experiments with polymers from the same batch)

Pricing

Batch Quantity Price
M2082A1/A2 100 mg £300.00
M2082A1/A2 250 mg £599.00
M2082A2 500 mg £1080.00
M2082A2 1 g £1960.00

Batch details

Batch Mw PDI Stock Info
M2082A1 ≥50,000 ≤3 Low stock
M2082A2 ≥100,000 ≤3 In stock

General Information

Full name Poly{[N,N'-bis(2-hexyldecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}
Synonyms
  • P(NDI2HD-T2)
  • Polynaphthalene diimide-bithiophene
Chemical formula (C54H72N2O4S2)n
CAS number 1459168-70-7
HOMO / LUMO HOMO = -5.80 eV, LUMO = -3.82 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, Organic photovoltaics, All-polymer solar cells (All-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Chlorobenzene, dichlorobenzene
P(NDI2HD-2T), pndi2hd2t, PNDI(2HD)2T, 1459168-70-7
Chemical structure and product image of PNDI(2HD)2T; Chemical formula: (C54H72N2O4S2)n.

 

Applications

PNDI(2HD)2T, also known as P(NDI2HD-T2), copolymer of naphtalene and bithiophene, is used as a polymer acceptor in high performance all-PSCs.

Compared to PNDI(2OD)2T, PNDI(2HD)2T exhibits a higher degree of crystalline behaviours. This facilitates superior 3D charge-transport between polymer donor and acceptor materials, resulting in enhanced device performance for all-PSCs. 

When PNDI-bithiophene copolymers with different side-chain length were compared, the maximum µe,FET value was identified as 0.39, 1.22 and 1.90 cm2 V−1 s−1 for PNDI(2DT)2T, PNDI(2OD)2T, and PNDI(2HD)2T respectively [2].

 

Literature and Reviews

  1. Rationally Designed Donor–Acceptor Random Copolymers with Optimized Complementary Light Absorption for Highly Efficient All-Polymer Solar Cells, S. Kim et al., Adv. Funct. Mater., 27, 1703070 (2017); DOI: 10.1002/adfm.201703070.
  2. Side Chain Optimization of Naphthalenediimide–Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells, W. Lee et al., Adv. Funct. Mater., 26, 1543–1553 (2016); DOI:10.1002/adfm.201504191.
  3. Controlling Molecular Orientation of Naphthalenediimide-​Based Polymer Acceptors for High Performance All-​Polymer Solar Cells, J. Jung et al., Adv. Energy Mater., 6 (15), 1600504 (2016), DOI:10.1002/aenm.201600504.