PFN-FP is one of the family members of conjugated poly-electrolyte materials (such as PFN) which is used as an electron-interface layer material in OPV devices (including perovskite solar cells) to improve extraction efficiencies. PFN-FP is also used as an active-layer material for blue OLED devices.
PFN-FP is soluble in polar solvents (such as water and methanol) in the presence of small amounts of acetic acid.
|Absorption (in film)||λmax 398 nm|
|HOMO/LUMO||HOMO = -5.70 eV, LUMO = -2.12 eV |
|Classification/Family||Conjugated polymers, Polymer electrolyte, Polyfluorenes, Electron interface-layer materials, OLED, OPV, Perovskite materials|
Literature and References
- Novel Electroluminescent Conjugated Polyelectrolytes Based on Polyfluorene, F. Huang et al., Chem. Mater.,16, 708-716 (2004); DOI: 10.1021/cm034650o.
- Approaches Toward Efficient and Stable Electron Extraction Contact in Organic Photovoltaic Cells: Inspiration from Organic Light-Emitting Diodes, T-W. Lee et al., Elec Mater. Lett., 6 (1), 41-50 (2010); DOI: 10.3365/eml.2010.03.041.
- Combination of Titanium Oxide and a Conjugated Polyelectrolyte for High-Performance Inverted-Type Organic Optoelectronic Devices, H. Choi et al., Adv. Mater., 23, 2759–2763 (2011); DOI: 10.1002/adma.201100266.
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