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BCBP

bcbp chemical structure, cas# 858131-70-1
Order Code: M2194A1
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MSDS sheet
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2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl (BCBP) has a bridged biphenyl structure with two electron rich carbazolyl pendant moieties. The bridged structure is believed to enhance the conjugation and raise the HOMO energy level, facilitating hole-injection and leading to low turn-on voltages in organic photoelectroluminescent devices.

Comparing with 4,4′-(bis(9-carbazolyl))biphenyl (CBP), a well known host material, BCBP is thermally more stable with a high glass transition temperature (Tg) of 173 °C, while CBP has a relatively low Tg of 69 °C.

Carbazolyl groups are largely embedded in both fluorescent and phosphorescent host materials because of their higher triplet energy levels and higher hole mobility. Like the rest of the family members such as CDBP and mCBP, BCBP is commonly used as host material for blue, green, red phosphorescent dopants for highly efficient OLED devices.

General Information

CAS number 858131-70-1
Full name 2,2'-bis(4-(carbazol-9-yl)phenyl)-biphenyl
Chemical formula C48H32N2
Molecular weight 636.78 g/mol
Absorption λmax 325 nm in DCM
Fluorescence λem 373 nm in DCM
HOMO/LUMO HOMO = 6.1 eV, LUMO = 2.6 (Eg = 3.5 eV; ET = 2.8 eV)
Synonyms 2,2'-bis(4-carbazolylphenyl)-1,1'-biphenyl
Classification / Family Organic electronics, Hole transport layer materials (HTL), Fluorescent and phosphorescent host materials, TADF-OLEDs, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point

Tg = 173 °C (lit.)

TGA: >330 °C (0.5% weight loss)
Colour White powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

bcbp, 858131-70-1
Chemical structure of BCBP

Device Structure(s)

Device structure ITO/TPDPES:TBPAH (20 nm)/BTPD (20 nm)/BCBP:15%FIrpic (30 nm)/DPPS (30 nm)/LiF (0.5 nm)/Al (100 nm) [1]
Colour Blue  blue
Max. Luminance 10,578 cd/m2
Max. Current Efficiency 50.5 cd/A 
Max. EQE 22.0%
Max. Power Efficiency 47.0 lm W-1
Device structure ITO/MoO3/TAPC/Ir(dpm)(piq)2(4%):BSB/Eu(TTA)3Phen*(0.3%):Ir(dpm)(piq)2(4%):BCBP/TPBi/LiF/Al
Colour Red  red
Max. Luminance 63,110 cd/m2
Max. Current Efficiency 61.71 cd/A 
Max. Power Efficiency 64.59 lm W-1
Device structure ITO/MoO3/TAPC/mer-Ir(Pmb)3(9%):BSB/Tm(acac)3Phen*(0.3%):mer-Ir(Pmb)3(9%):BCBP/TPBi/LiF/Al
Colour Blue  blue
Max. Luminance 20,095 cd/m2
Max. Current Efficiency 30.08 cd/A 
Max. Power Efficiency 37.56 lm W-1
Device structure ITO/MoO3/TAPC/Ir(ppy)2(m-bppy)(9%):Ir(piq)2(acac)(3%):BSB/Tm(acac)3Phen(0.3%):mer-Ir(pmb)3(25%):BCBP/TPBi/LiF/Al 
Colour White    white
Max. Luminance 43,122 cd/m2
Max. Current Efficiency 60.55 cd/A 
Max. Power Efficiency 63.18 lm W-1

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2194A1 100 mg £180.00
Sublimed (>99.0% purity) M2194A1 250 mg £360.00
Sublimed (>99.0% purity) M2194A1 500 mg £612.00
Sublimed (>99.0% purity) M2194A1 1 g £1040.00

MSDS Documentation

BCBP MSDSBCBP MSDS sheet

Literature and Reviews

  1. Nearly 100% Internal Quantum Efficiency in an Organic Blue-Light Electrophosphorescent Device Using a Weak Electron Transporting Material with a Wide Energy Gap, L Xiao et al., Adv. Mater., 21, 1271–1274 (2009); DOI: 10.1002/adma.200802034.
  2. Diarylmethylene-bridged 4,4′-(bis(9-carbazolyl))biphenyl: morphological stable host material for highly efficient electrophosphorescence, Z. Jiang et al., J. Mater. Chem., 19, 7661-7665 (2009); DOI: 10.1039/B910247G.
  3. Towards Highly Efficient Blue-Phosphorescent Organic Light-EmittingDiodes with Low Operating Voltage and Excellent Efficiency Stability, C. Han et al., Chem. Eur. J., 17, 445 – 449 (2011); DOI: 10.1002/chem.201001981.
  4. Organic host materials for phosphorescent organic light-emitting diodes, Y. Tao et al., Chem. Soc. Rev., 40, 2943-2970 (2011); DOI: 10.1039/C0CS00160K.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.

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