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MADN

madn chemical structure, 804560-00-7
Product Code M2092A1
Price $325.00 ex. VAT
$ USD

MADN, highly-efficient blue host material and HTL material for organic electronic devices

High-purity (>99.0%) and available online for priority dispatch

MADN, 2-methyl-9,10-bis(naphthalen-2-yl)anthracene is commonly known as a blue emitter. It is widely used as a highly-efficient blue host material and hole-transporting material (HTM) for organic electronic devices. Exhibiting an ambipolar transporting ability, MADN offers stable thin-film morphology and a wide energy band-gap.

As a hole-transporting material, MADN can reduce the amount of hole carriers injected into the device - leading to a well-balanced carrier recombination [2].

General Information

CAS number 804560-00-7
Chemical formula C35H24
Molecular weight 444.57 g/mol
Absorption λmax 379 nm, 399 nm in DCM
Fluorescence λem  439 nm in DCM
HOMO/LUMO HOMO = -5.5 eV, LUMO = -2.5 eV [1]
Synonyms 2-Methyl-9,10-bis(naphthalen-2-yl)anthracene, 2-Methyl-9,10-di(2-naphthyl)anthracene
Classification / Family Hole-transport layer (HTL) materials, Solution-processed OLED maetrials, Blue emitter, PHOLEDs, OPV, Sublimed materials

Product Details

Purity >99.0% (sublimed)
Melting Point 253 - 258 °C (lit.); TGA: Td ≥ 310 oC (5% weight loss)
Colour White powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

madn chemical structure, 804560-00-7
Chemical structure of 2-Methyl-9,10-bis(naphthalen-2-yl)anthracene (MADN)

Device Structure(s)

Device structure ITO/CFx/MADN (60 nm)/Alq3:1%C545T (37.5 nm)/Alq3 (37.5 nm)/LiF (1 nm)/Al (150 nm) [2]
Colour Green green light emitting device
Luminance@6.6V 4366 cd/m2
Current Efficiency@20mA/cm2 21.8 cd/A
Power Efficiency@20mA/cm2 10.4 lm W−1
EQE@20mA/cm2 5.8%
Device structure ITO/CFx/c-HTL (40nm)/NPB (10nm)/MADN:5%BD1 (40nm)/Alq3 (10nm)/Al-LiF [3]
Colour Deep Blue deep blue light emitting device
Luminance@6.8V 1080 cd/m2
Current Efficiency@20mA/cm2 5.4 cd/A
Power Efficiency@20mA/cm2 2.5 lm W−1
EQE@20mA/cm2 5.1%
Device structure ITO/NPD (40 nm)/MADN:1wt% C545T (20 nm)/B3PyPB (40 nm)/LiF/Al [4]
Colour Green green light emitting device
Max. EQE 6.0%
Device structure ITO/TAPC (35 nm)/MADN + 6 wt%DPAVBi (20 nm)/B3PyPB (40 nm)/LiF (1 nm)/Al (80 nm) [4]
Colour Blue blue light emitting device
EQE@100 cd/m2 8.2%

*For chemical structure information, please refer to the cited references

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0%) M2092A1 1 g £260
Sublimed (>99.0%) M2092A1 5 g £1100

MSDS Documentation

MADN MSDSMADN MSDS sheet

Literature and Reviews

  1. Highly efficient and stable sky blue organic light-emitting devices, M-F. Lin et al., Appl. Phys. Lett. 89, 121913 (2006); doi: 10.1063/1.2356903.
  2. Study of efficient and stable organic light-emitting diodes with 2-methyl-9,10-di(2-naphthyl)anthracene as hole-transport material by admittance spectroscopy, M-H. Ho et al., Appl. Phys. Lett. 94, 023306 (2009); doi: 10.1063/1.3072616.
  3. Highly Efficient, Deep-Blue Doped Organic Light-Emitting Devices, M-T. Lee et al., Adv. Mater.,17, 2493–2497 (2005); DOI: 10.1002/adma.200501169.
  4. Optimizing the Charge Balance of Fluorescent OrganicLight-Emitting Devices to Achieve High External QuantumEffi ciency Beyond the Conventional Upper Limit, Y-J. Pu et al., Adv. Mater., 24, 1765–1770 (2012); DOI: 10.1002/adma.201104403.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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