Phen-TRZ
Phen-TRZ, 2-(10H-Phenoxazine-10-yl)-4,6-diphenyl-1,3,5-triazine, has a structure of phenoxazine directly attached to diphenyltrazine with spacer in between. Comparing with PXZ-TRZ, Phen-TRZ is relatively sterically hindered without the rotational degree of freedom.
Phen-TRZ is light blue TADF emitter and can replace PXZ-TRZ for a blue shade of green emission.
General Information
CAS number | 1357066-21-7 |
Chemical formula | C27H18N4O |
Molecular weight | 414.46 g/mol |
Absorption | λmax 307 nm (in DCM) |
Fluorescene | λem 497 nm (in DCM) |
HOMO/LUMO | n.a. |
Full chemical name | 2-(10H-Phenoxazine-10-yl)-4,6-diphenyl-1,3,5-triazine |
Synonyms | DPhPXZT |
Classification / Family | Triazine derivatives, TADF blue emitters, Sublimed materials |
Product Details
Purity | Sublimed >99.0% (HPLC) |
Melting point | TGA: >300 °C(0.5% weight loss) |
Appearance | Bluish green powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Chemical Structure
Pricing
Grade | Order Code | Quantity | Price |
Sublimed(>99.0% purity) | M2264A1 | 100 mg | £150.00 |
Sublimed(>99.0% purity) | M2264A1 | 250 mg | £300.00 |
Sublimed(>99.0% purity) | M2264A1 | 500 mg | £500.00 |
Sublimed(>99.0% purity) | M2264A1 | 1 g | £850.00 |
MSDS Documentation
Literature and Reviews
- Fluorescence, Phosphorescence, or Delayed Fluorescence?-A Theoretical Exploration on the Reason Why a Series of Similar Organic Molecules Exhibit Different Luminescence Types, Y. Duan et al., J. Phys. Chem. C, 122, 40, 23091–23101 (2018); DOI:10.1021/acs.jpcc.8b06533.
- Intersystem-Crossing and Phosphorescence Rates in fac-IrIII(ppy)3: A Theoretical Study Involving Multi-Reference Configuration Interaction Wavefunctions, M. Kleinschmidt et al., J. Chem. Phys. 142, 094301 (2015); DOI: 10.1063/1.4913513.
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