Phen-TRZ
Phen-TRZ, 2-(10H-Phenoxazine-10-yl)-4,6-diphenyl-1,3,5-triazine, has a structure of phenoxazine directly attached to diphenyltrazine with spacer in between. Comparing with PXZ-TRZ, Phen-TRZ is relatively sterically hindered without the rotational degree of freedom.
Phen-TRZ is light blue TADF emitter and can replace PXZ-TRZ for a blue shade of green emission.
General Information
| CAS number | 1357066-21-7 |
| Chemical formula | C27H18N4O |
| Molecular weight | 414.46 g/mol |
| Absorption | λmax 307 nm (in DCM) |
| Fluorescene | λem 497 nm (in DCM) |
| HOMO/LUMO | n.a. |
| Full chemical name | 2-(10H-Phenoxazine-10-yl)-4,6-diphenyl-1,3,5-triazine |
| Synonyms | DPhPXZT |
| Classification / Family | Triazine derivatives, TADF blue emitters, Sublimed materials |
Product Details
| Purity | Sublimed >99.0% (HPLC) |
| Melting point | TGA: >300 °C(0.5% weight loss) |
| Appearance | Bluish green powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Chemical Structure
Pricing
| Grade | Order Code | Quantity | Price |
| Sublimed(>99.0% purity) | M2264A1 | 100 mg | £150.00 |
| Sublimed(>99.0% purity) | M2264A1 | 250 mg | £300.00 |
| Sublimed(>99.0% purity) | M2264A1 | 500 mg | £500.00 |
| Sublimed(>99.0% purity) | M2264A1 | 1 g | £850.00 |
MSDS Documentation
Phen-TRZ MSDS sheetLiterature and Reviews
- Fluorescence, Phosphorescence, or Delayed Fluorescence?-A Theoretical Exploration on the Reason Why a Series of Similar Organic Molecules Exhibit Different Luminescence Types, Y. Duan et al., J. Phys. Chem. C, 122, 40, 23091–23101 (2018); DOI:10.1021/acs.jpcc.8b06533.
- Intersystem-Crossing and Phosphorescence Rates in fac-IrIII(ppy)3: A Theoretical Study Involving Multi-Reference Configuration Interaction Wavefunctions, M. Kleinschmidt et al., J. Chem. Phys. 142, 094301 (2015); DOI: 10.1063/1.4913513.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.