PDPP4T-2F, semiconducting polymer with deep HOMO level
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Specifications | MSDS | Literature and Reviews
PDPP4T-2F is the fluorinated version of PDPP4T with a device performance PCE of 7.59% [1].
In comparison to PDPP4T, PDPP4T-2F has a deeper highest-occupied molecular orbital (HOMO) level, due to the electron-withdrawing nature of the fluorine atoms on the thiophene units. It has also been reported that apart from being more favorable for realizing higher Voc due to its deeper HOMO energy level, PDPP4T-2F shows great potential in achieving a higher Jsc than PDPP4T in devices for its improved extinction coefficient.
General Information
| Full name | Poly[2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione -3,6-diyl)-alt-(3'',4'-difluoro[2,2’;5’,2’’;5’’,2’’’-quaterthiophen]-5,5’’’-diyl)] |
| Synonyms | PFDPP4T, PDQT-2F |
| CAS number | 1926166-46-2 |
| Chemical formula | (C62H88F2N2O2S4)n |
| Molecular weight | See Batch Details table |
| HOMO / LUMO | HOMO = ~ 5.22 eV, LUMO = ~ 3.66 eV [3] |
| Soluble in | Chloroform, chlorobenzene, dichlorobenzene |
| Recommended Processing Solvents at 10mg/ml | Chloroform (2mg/ml) |
| Classification / Family | Quaterthiophene, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, Polymer solar cells, OFETs |
Batch Details
| Batch | Mw | Mn | PDI | Stock Info |
| M2051A1 | 173,151 | 63,296 | 2.74 | Out of stock |
| M2051A2 | 70.758 | 33,458 | 2.11 | In Stock |
Chemical Structure
MSDS Documentation
PDPP4T-2F MSDS sheetLiterature and Reviews
- Sequential Deposition: Optimization of Solvent Swelling for High-Performance Polymer Solar Cells, Y. Liu et al., ACS Appl. Mater. Interfaces, 7, 653-661 (2015); DOI: 10.1021/am506868g.
- Effect of Fluorination on Molecular Orientation of Conjugated Polymers in High Performance Field-Effect Transistors, A. Zhang et al., Macromolecules, 49 (17), 6431–6438 (2016); DOI: 10.1021/acs.macromol.6b01446.
- Over 11% Efficiency in Tandem Polymer Solar Cells Featured by a Low-Band-Gap Polymer with Fine-Tuned Properties, Z. Zheng et al., Adv. Mater., 28, 5133–5138 (2016); DOI: 10.1002/adma.201600373.