Pricing
Batch Quantity Price
M2148A1 100 mg
£320.00
M2148A1 250 mg
£664.00
M2148A1 500 mg
£1190.00
M2148A1 1 g
£2150.00
General Information
Purity ≥99.0% (1 H NMR)
Full name 3,9-bis(2-methylene-((3-(1,1-dicyanomethylene)-6,7-dimethyl)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2’,3’-d’]-s-indaceno[1,2-b:5,6-b’]dithiophene
Synonyms IT-2M, IT-DM
Chemical formula C98 H90 N4 O2 S4
CAS number 2047352-92-9
Molecular weight 1484.05
HOMO / LUMO HOMO = -5.56 eV, LUMO = -3.93 eV [1]
Classification / Family Non-fullerene acceptors (NFAs), Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptors (SMAs), Organic photovoltaics, Polymer solar cells, NF-PSCs.
Chemical structure of ITIC-DM; CAS No. 2047352-92-9 .
Applications
ITIC-DM, another family member of ITIC , is used as an acceptor material to replace fullerene for high-performing organic solar cells (NFA-OSC).
Due to the electron-donating nature of the methyl groups at the end benzene rings, ITIC-DM has higher HOMO/LUMO energy levels compared those of ITIC or ITIC-M . Extra methyl groups also have the potential to help enhance solubility and film morphology for material processing and device fabrication.
Characterisation (1 H NMR)
1 H NMR spectrum of ITIC-DM in CDCl3 .Literature and Reviews
Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells, S. Li et al., Adv. Mater., 28, 9423–9429 (2016); DOI: 10.1002/adma.201602776.
Recent Progress in Fused-Ring Based Nonfullerene Acceptors for Polymer Solar Cells, C. Cui et al., Front. Chem., 6:404 (2018); doi: 10.3389/fchem.2018.00404.
New developments in non-fullerene small molecule acceptors for polymer solar cells, N. Liang et al., Mater. Chem. Front., 1, 1291 (2017); DOI: 10.1039/c6qm00247a.
A nonvolatile morphology regulator for enhancing the molecular order in the active layer and power conversion efficiency of polymer solar cells, H-J. Jhuo et al., J. Mater. Chem. A, 6, 8874 (2018); DOI: 10.1039/c8ta01739e.
