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ITIC-DM (n-type acceptor)

itic-dm, it-2m
Order Code: M2148A1
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MSDS sheet
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ITIC-DM, another family member of ITIC, is used as an acceptor material to replace fullerene for high-performing organic solar cells (NFA-OSC).

Due to the electron-donating nature of the methyl groups at the end benzene rings, ITIC-DM has higher HOMO/LUMO energy levels compared those of ITIC or ITIC-M. Extra methyl groups also have the potential to help enhance solubility and film morphology for material processing and device fabrication.

Characterisation (1H NMR)

1H NMR of ITIC-DM
1H NMR spectrum of ITIC-DM in CDCl3.

General Information

Purity ≥99.0% (1H NMR)
Full name 3,9-bis(2-methylene-((3-(1,1-dicyanomethylene)-6,7-dimethyl)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2’,3’-d’]-s-indaceno[1,2-b:5,6-b’]dithiophene
Synonyms IT-2M, IT-DM
Chemical formula C98H90N4O2S4
CAS number 2047352-92-9
Molecular weight 1484.05
HOMO / LUMO HOMO = -5.56 eV, LUMO = -3.93 eV [1]
Classification / Family Non-fullerene acceptors (NFAs), Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptors (SMAs), Organic photovoltaics, Polymer solar cells, NF-PSCs.

Chemical Structure

itic-dm, 2047352-92-9
Chemical structure of ITIC-DM; CAS No. 2047352-92-9.

MSDS Documentation

ITIC-DM MSDSITIC-DM MSDS Sheet

Pricing

Batch Quantity Price
M2148A1 100 mg £320.00
M2148A1 250 mg £664.00
M2148A1 500 mg £1190.00
M2148A1 1 g £2150.00

Literature and Reviews

  1. Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells, S. Li et al., Adv. Mater., 28, 9423–9429 (2016); DOI: 10.1002/adma.201602776.
  2. Recent Progress in Fused-Ring Based Nonfullerene Acceptors for Polymer Solar Cells, C. Cui et al., Front. Chem., 6:404 (2018); doi: 10.3389/fchem.2018.00404.
  3. New developments in non-fullerene small molecule acceptors for polymer solar cells, N. Liang et al., Mater. Chem. Front., 1, 1291 (2017); DOI: 10.1039/c6qm00247a.
  4. A nonvolatile morphology regulator for enhancing the molecular order in the active layer and power conversion efficiency of polymer solar cells, H-J. Jhuo et al., J. Mater. Chem. A, 6, 8874 (2018); DOI: 10.1039/c8ta01739e.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.

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