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Product Code B1171-25g
Price £170 ex. VAT

A convenient intermediate for construction of more complex structures

Used in application of organic photovoltaic and OLED devices.

Specifications | MSDS | Literature and Reviews

2-Bromo-9H-carbazole (CAS number 3652-90-2) is a mono-brominated derivative of 9H-carbazole at 2-position bearing both bromo and amine functional groups. It has been used for further synthesis of semiconducting small molecules and polymers in application of OLEDs, dye sensitized solar cells, polymer and perovskite solar cells.

PyEtCz, a deep blue fluorescent material derived from 2-Bromo-9H-carbazole, shows good thermal stability exhibits strong deep-blue emission with high fluorescent quantum yield of 75%. Device performance with maximum luminance of 6573 cd m-2 and maximum luminance efficiency of 3.24 cd A-1 (3.35%) was achieved with CIE coordinate of (0.15, 0.10). The molar ratio of the 2-bromo-9H-carbazole phosphor to acrylamide can strongly influences the room-temperature phosphorescent (RTP) emission intensities and quantum yields of the blue–purple phosphorescence emitting amorphous copolymer of 2-bromocarbazole phosphor and acrylamide [1, 2].

Carbazole building block

Carbazole building block

for the synthesis of OLED and organic photovoltaic materials

3652-90-2 Worldwide shipping

Worldwide shipping

Quick and reliable shipping

Substituted with a bromide group

Substituted with a bromide group

for facile reactions

High purity

High purity

>98% Purity

General Information

CAS Number 3652-90-2
Chemical Formula C12H8BrN
Full Name 2-Bromo-9H-carbazole
Molecular Weight 246.1 g/mol
Synonyms 2-Bromocarbazole
Classification / Family Carbazoles, semiconductor synthesis intermediates, Electron donor unit, OLED, OFETs, organic photovoltaics

Chemical Structure

2-Bromo-9H-carbazole chemical structure, CAS 3652-90-2
2-Bromo-9H-carbazole chemical structure, CAS 3652-90-2

Product Details

Purity >98% (1H NMR)
Melting Point 255 °C
Appearance Off-white to beige powder

MSDS Documentation

2-Bromo-9H-carbazole2-Bromo-9H-carbazole MSDS Sheet

Literature and Reviews

  1. Efficient deep blue emitter based on carbazole-pyrene hybrid for non-doped electroluminescent device, T. Zhang et al., Opt. Mater., 100, 109632 (2020); DOI: 10.1016/j.optmat.2019.109632.
  2. Amorphous 2-Bromocarbazole Copolymers with Efficient Room-Temperature Phosphorescent Emission and Applications as Encryption Ink, T. Zhang et al.,Ind. Eng. Chem. Res., 56, 11, 3123–3128 (2017); 10.1021/acs.iecr.7b00149.
  3. Hole-transporting side-chain polystyrenes based on TCTA with tuned glass transition and optimized electronic properties, F. Limberg et al., RSC Adv., 5, 83122-83128 (2015); DOI: 10.1039/C5RA12963J.
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