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T2T

chemical structure of t2t, 2,4,6-tris(biphenyl-3-yl)-1,3, 5-triazine
Order Code: M2103A1
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MSDS sheet
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2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine (T2T) is a family member of triazine.  It has one electron-withdrawing triazine core and three electron-rich biphenyl groups. It has been widely used as a host material for phosphorescent OLEDs and electron transport layer material (ETL) for TADF-OLEDs.

Due to its electron-deficient nature, T2T and its derivatives are also used as acceptor materials to form exciplexes in blue-emission TADF devices.

General Information

CAS number 1201800-83-0
Chemical formula C39H27N3
Molecular weight 537.65 g/mol
Absorption λmax 270 nm in DCM
Fluorescene λem 380 nm in DCM
HOMO/LUMO HOMO = 6.5 eV, LUMO = 3.0 eV; T1 = 2.80 eV [1]
Synonyms 2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine
Classification / Family Triazine, TADF blue emitter materials, TADF host materials, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity  Sublimed >99.0% (HPLC)
Melting point TGA: >300 °C (0.5% weight loss)
Appearance Off-white powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

Chemical structure T2t
Chemical structure of 2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine (T2T)

Device Structure(s)

Device structure  ITO/PEDOT:PSS/a-NPD (20 nm)/TCTA (5 nm)/(PPy)2Ir(acac):T2T (25 nm)/TPBi (50 nm)/LiF (0.5 nm)/Al (100 nm) [2]
Colour Green green
Max. EQE 17.5%
Max. Power Efficiency 65.2 Im/W
Device structure  ITO/MoO3 (3 nm)/TAPC (25 nm)/TAPC:T2T (15 nm)/T2T (5 nm)/Bphen (30 nm)/LiF (1 nm)/Al (100 nm) [3]
Colour Green green
Max. Current Efficiency 40.4 cd/A
Max. EQE 11.6%
Max. Power Efficiency 42.2 Im/W
Device structure  ITO/TAPC (35 nm)/1 wt%-TBRb:25 wt%-PXZ-TRX:mCBP (30 nm)/T2T (10 nm)/Alq3 (55 nm)/LiF (0.8 nm)/Al (100 nm) [4]
Colour Yellow  yellow
Max. Current Efficiency 60 cd/A
Max. EQE 18.0%
Max. Power Efficiency 58 Im/W
Device structure  ITO (100 nm)/HAT-CN (10 nm)/TAPC (30 nm)/0.65mol%-TBRb:6.3mol%-4CzIPN-Me:mCBP (30 nm)/T2T (10 nm)/Alq3 (55 nm)/LiF (0.8 nm)/Al (100 nm) [5]
Colour Green green
Max. Current Efficiency 73 cd/A
Max. EQE 21%

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2103A1 250 mg £249.00
Sublimed (>99.0% purity) M2103A1 500 mg £423.00
Sublimed (>99.0% purity) M2103A1 1 g £738.00

MSDS Documentation

T2T MSDST2T MSDS sheet

Literature and Reviews

  1. Operational stability enhancement in organic light-emitting diodes with ultrathin Liq interlayers, D. Tsang et al., Sci. Rep., 6:22463 (2016); DOI: 10.1038/srep22463.
  2. 1,3,5-Triazine derivatives as new electron transport–type host materials forhighly efficient green phosphorescent OLEDs, H-F. Chen et al., J. Mater. Chem., 19, 8112–8118 (2009); DOI: 10.1039/b913423a.
  3. Thermally activated delayed-fluorescence organic light-emitting diodes based on exciplex emitter with high efficiency and low roll-off, T. Lin et al., Org. Electronics, 38, 69-73 (2016); DIO: 10.1016/j.orgel.2016.08.001.
  4. High-efficiency organic light-emitting diodes with fluorescent emitters, H. Nakanotani et al., Nat. Commun., 5:4016 (2014); DOI: 10.1038/ncomms5016.
  5. Dual enhancement of electroluminescence efficiency and operational stability by rapid upconversion of triplet excitons in OLEDs, T. Furukawa1 et al., Sci. Rep., 5:8429 (2015) DOI: 10.1038/srep08429.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.

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