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mSiTrz


Product Code M2309A1
Price £177.00 ex. VAT

mSiTrz - 2-Phenyl-4,6-bis(3-(triphenylsilyl)phenyl)-1,3,5-triazine is wide bandgap (4.11 eV) triphenylsilyl high triplet energy exciplex phosphorescent host with antriazine core. The electron deficient nature of the triazine give the rise of the electron transport property of mSiTrz which could also be used with some other electron donating hosts, i.e. oCBP to form exciplex hosts.

Mixed host oCBP:mSiTrz has achieved high external quantum efficiency over 20% with a color coordinate of (0.14, 0.16) deep blue and device lifetime of longer than 1000 h at 100 cd m-2 [1].

General Information

CAS number 2252416-90-1
Chemical formula C57H43N3Si2
Molecular weight 826.14 g/mol
Absorption λmax 274 nm
Photoluminescence λem 393 nm
HOMO/LUMO HOMO = 6.9 eV, LUMO = 2.79 eV; ET = 3.08 eV [1]
Chemical name 2-Phenyl-4,6-bis(3-(triphenylsilyl)phenyl)-1,3,5-triazine
Synonyms mSiTrz
Classification / Family Triazine derivatives, Phosphorescent host materials, Sublimed materials, Semiconducting small molecules

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point Tg = 108.21 °C (lit.)
Appearance White powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials for OLED devices page.

Chemical Structure

mSiTrz chemical structure, CAS No. 2252416-90-1

Chemical structure of 2-Phenyl-4,6-bis(3-(triphenylsilyl)phenyl)-1,3,5-triazine (mSiTrz), CAS 2252416-90-1.

Device Structure(s)

Device structure ITO (50 nm)/BPBPA:HATCN (40 nm:30%)/BPBPA (10 nm)/ PCZAC (10 nm)/Ir(cb)3:oCBP:mSiTrz (30 nm)/DBFTrz (5 nm)/ZADN (20 nm)/LiF (1.5 nm)/Al (200 nm) [1]
Colour Blue blue
Max. EQE 21.6%
Max. Power Efficiency 29.3 Im/W


Device structure ITO (50 nm)/BPBPA:HATCN (40 nm:30%)/BPBPA (10 nm)/ PCZAC (10 nm)/Ir(cb)3:26CzDBF:mSiTrz (30 nm)/DBFTrz (5 nm)/ZADN (20 nm)/LiF (1.5 nm)/Al (200 nm) [2]
Colour Blue blue
Max. EQE 23%
Max. Power Efficiency 27.9 Im/W

 

Device structure ITO (50 nm)/BPBPA:HATCN (40 nm:30%)/BPBPA (10 nm)/ PCZAC (10 nm)/Ir(cb)3:46CzDBF:mSiTrz (30 nm)/DBFTrz (5 nm)/ZADN (20 nm)/LiF (1.5 nm)/Al (200 nm) [2]
Colour Blue blue
Max. EQE 20.3%
Max. Power Efficiency 28.3 Im/W

 

Device structure ITO (50 nm)/BPBPA:HATCN (40 nm:30%)/BPBPA (10 nm)/ PCZAC (10 nm)/Ir(cb)3:28CzDBF:mSiTrz (30 nm)/DBFTrz (5 nm)/ZADN (20 nm)/LiF (1.5 nm)/Al (200 nm) [2]
Colour Blue blue
Max. EQE 22.4%
Max. Power Efficiency 26.3 Im

 

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2309A1 100 mg £177.00
Sublimed (>99.0% purity) M2309A1 250 mg £353.00
Sublimed (>99.0% purity) M2309A1 500 mg £566.00
Sublimed (>99.0% purity) M2309A1 1 g £980.00

MSDS Documentation

mSiTrz MSDS sheet

 

Literature and Reviews

  1. Simultaneous Achievement of High Efficiency and Long Lifetime in Deep Blue Phosphorescent Organic Light-Emitting Diodes, K. Choi et al., Adv. Optical Mater., 7 (23); 1901374 (2019). DOI: 10.1002/adom.201901374.
  2. Effects of Substitution Position of Carbazole-Dibenzofuran Based High Triplet Energy Hosts to Device Stability of Blue Phosphorescent Organic Light-Emitting Diodes, K. Choi et al., Molecules 26, 2804 (2021); DOI: 10.3390/molecules26092804.
  3. Extremely Superb Efficiency and Lifetime of Deep Blue Phosphorescent OLEDs by Introducing Hypsochromic-shift Intermolecular Complex with Negligibly Small ΔEST and Fast Reverse Intersystem Crossing Rate, K. Kim et al., J. Mater. Chem. C, 9, 4029-4038 (2021); DOI: 10.1039/D0TC06107G..

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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