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[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid

CAS Number 1542274-12-3

Chemistry Building Blocks, Materials, MOF Ligands, Porous Organic Frameworks

[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid CAS 1542274-12-3
Product Code B3081-500mg
Price £110 ex. VAT
£ GBP

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Metal Organic Frameworks (MOFs) Terphenyl Ligand

A linear ligand linker for MOFs in applications of removing methane blue and highly efficient ion conductivity batteries

[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid (H6TPHC), CAS number 1542274-12-3, has a linear terphenyl core with two carboxylic acid groups on each of the benzene rings, 2,5-positions of the central one and 3,5-positions on each of the end ones.

Porous metal–organic framework ZJU-24 with H4TPHC/H6TPHC as ligand linkers, shows strong interactions with methylene blue and thus the complete removal of methylene blue from aqueous solution can be realized.

Highly electronegative carboxyl-decorated anionic metal–organic framework (MOF), InOF based on indium ion cluster nodes and H6TPHC as the ligand linkers, possesses 12 negative sites that originate from the negatively charged secondary building unit and exposed carboxyl groups on the ligand in one unit cell. The abundant electronegative sites can facilitate the hopping of ions in channels and thus result in highly efficient ion conductivities for various metal ions.

General Information

CAS Number 1542274-12-3
Chemical Formula C24H14O12
Full Name [1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid
Molecular Weight 494.36 g/mol
Synonyms H6TPHC, 4-(3,5-dicarboxyphenyl)-[1,1'-biphenyl]-2,3',5,5'-tetracarboxylic acid
Classification / Family Terphenyl, MOF ligands, 

Chemical Structure

1542274-12-3 - [1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid chemical structure
[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid (H6TPHC) Chemical Structure, 1542274-12-3

Product Details

Purity >98%
Melting Point n.a.
Appearance Off white powder/crystal

MSDS Documentation

1542274-12-3 - [1,1':4',1''-terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid MSDS Sheet

Literature and Reviews

  1. A porous metal–organic framework with –COOH groups for highly efficient pollutant removal, Q. Zhang et al., Chem. Commun., 2014, 14455-14458 (2014); DOI: 10.1039/C4CC06648K.
  2. Metal-organic frameworks bearing free carboxylic acids: Preparation, modification, and applications, B. Bhadra et al., 450, 214237 (2022); DOI: 10.1016/j.ccr.2021.214237.
  3. Structural variability, unusual thermochromic luminescence and nitrobenzene sensing properties of five Zn(ii) coordination polymers assembled from a terphenyl-hexacarboxylate ligand, X. Wan et al., CrystEngComm, 17, 3829-3837 (2015); DOI: 10.1039/C5CE00420A.
  4. Two Carboxyl-Decorated Anionic Metal–Organic Frameworks as Solid-State Electrolytes Exhibiting High Li+ and Zn2+ Conductivity, X. Duan et al., Inorg. Chem., 60, 15, 11032–11037 (2021); DOI: 10.1021/acs.inorgchem.1c00744.
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