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CAS Number 107063-53-6

Chemistry Building Blocks, MOF Ligands, Porous Organic Frameworks

Product Code B3031-500mg
Price $188 ex. VAT

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Metal Organic Frameworks (MOFs) Triphenylpyridyl Ligand

A triangular ligand linker for MOFs in applications of iron detection, carbon dioxide fixation and catalytic reactions

2,4,6-Tris-(p-carboxyphenyl)pyrdin (H3PTB) ias a pyridine-based tritopic linker with three 4-carboxyphenyl groups at 2,4,6-positions of the central pyridine ring.

Luminescent MOF PCN‐604, based on 2,4,6-tris-(p-carboxyphenyl)pyrdin as the ligand linkers and aluminum ion cluster nodes, shows excellent thermal and chemical stability. As a luminescent senor, PCN‐604 shows intense luminescence in water and promising sensitivity and selectivity towards trace amount of Fe3+ ions with quenching constant of 2.85 x 104 M‐1 and low detection limit of 6.2 μM.

Crystalline framework, [Cu3(H3PTB)2(H2O)3]n, is mesoporous in nature and it is showing dual functionality in the removal of organic dyes. Microporous Zn-H3PTB based anionic MOF shows open channels capturing the cationic dye methylene blue. The Zn-MOF also demonstrates excellent catalytic activity for CO2 fixation by cycloaddition reaction with epoxides for the generation of cyclic carbonates.

General Information

CAS Number 107063-53-6
Chemical Formula C26H17NO6
Full Name 2,4,6-Tris-(p-carboxyphenyl)pyrdin
Molecular Weight 439.42 g/mol
Synonyms H3PTB, 4,4',4''-(Pyridine-2,4,6-triyl)tribenzoic acid
Classification / Family 2,4,6-triphenylpyridine, MOF ligands, 

Chemical Structure

107063-53-6 - 2,4,6-Tris-(p-carboxyphenyl)pyrdin chemical structure
2,4,6-Tris-(p-carboxyphenyl)pyrdin (H3PTB) Chemical Structure, 107063-53-6

Product Details

Purity >98%
Melting Point 368-373 °C 
Appearance Off white powder/crystal

MSDS Documentation

107063-53-6 - 2,4,6-tris-(p-carboxyphenyl)pyrdin2,4,6-Tris-(p-carboxyphenyl)pyrdin MSDS Sheet

Literature and Reviews

  1. Direct synthesis of functionalized PCN-333 via linker design for Fe3+ detection in aqueous media, Y. Zhang et al., Dalton Trans., 47, 11806-11811 (2018); DOI: 10.1039/C8DT01508B.
  2. Dual-Functional Mesoporous Copper(II) Metal-Organic Frameworks for the Remediation of Organic Dyes, V. Au et al., Chem. Eur. J. 27 (35), 9174-9179 (2021); DOI: 10.1002/chem.202100289.
  3. Isoreticular chemistry of scandium analogues of the multicomponent metal–organic framework MIL-142, R. Prasad et al., CrystEngComm, 23, 804-812 (2021); DOI: 10.1039/D0CE01593H.
  4. Anionic Metal–Organic Framework for Selective Dye Removal and CO2 Fixation, S. Kumar et al., Eur. J. Inorg. Chem., 2016 (27), 4373-4377 (2016); DOI: 10.1002/ejic.201600218.
  5. Direct Catalytic Conversion of CO2 to Cyclic Organic Carbonates under Mild Reaction Conditions by Metal—Organic Frameworks, S. Huh, Catalyst, 9 (34), 2019; DOI: 10.3390/catal9010034

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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