2,6-Di(pyridin-4-yl)naphthalene
CAS Number 950520-39-5
Chemistry Building Blocks, Materials, MOF Ligands, Porous Organic Frameworks
Metal Organic Frameworks (MOFs) Dipyridylnaphthalene Ligand
A rigid linear ligand linker for MOFs in applications of catalysts and pure white LEDs.
Specifications | MSDS | Literature and Reviews
2,6-Di(pyridin-4-yl)naphthalene (DPyN) has a naphthalene with two 4-pyridyl groups at 2,6-positions.
2,6-Di(pyridin-4-yl)naphthalene is synthesised by reacting 2,6-dibromonaphthalene with 4-pyridylboronic acid via Suzuki coupling reaction using tetrakis(triphenylphosphine)palladium as the catalyst.
White-light-emitting systems in water at the single-molecule scale utilizing 2,6-di(pyridin-4-yl)naphthalene core and coumarin pedant groups with natural self-folded conformation can be realized. This particular folding behaviour could enhance the ICT efficiency and lead to pure white-light emission.
General Information
CAS Number | 950520-39-5 |
Chemical Formula | C20H14N2 |
Full Name | 2,6-Di(pyridin-4-yl)naphthalene |
Molecular Weight | 282.34 g/mol |
Synonyms | DPyN, 2,6-bis(pyridin-4-yl)naphthalene |
Classification / Family | Dipyridylnaphthalene, MOF ligands, |
Chemical Structure
Product Details
Purity | >98% |
Melting Point | N/A |
Appearance | Off white powder/crystal |
MSDS Documentation
2,6-Di(pyridin-4-yl)naphthalene MSDS Sheet
Literature and Reviews
-
Liquid-Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site-Isolation of Catalytic Centers, M. Beyzavi et al., ChemPlusChem, 81 (8), 708-713 (2016); DOI: 10.1002/cplu.201600046.
-
Rational Design and Construction of Hierarchical Superstructures Using Shape-Persistent Organic Cages: Porphyrin Box-Based Metallosupramolecular Assemblies, Y. Kim et al., J. Am. Chem. Soc., 140 (44), 14547–14551 (2018); DOI: 10.1021/jacs.8b08030.
-
Opening Metal–Organic Frameworks Vol. 2: Inserting Longer Pillars into Pillared-Paddlewheel Structures through Solvent-Assisted Linker Exchange, O. Karagiaridi et al., Chem. Mater., 25 (17), 3499–3503 (2013); DOI: 10.1021/cm401724v.