PDPP3T
CAS Number 1198291-01-8
Interface Polymers, Luminosyn™ Polymers, OPV Polymers, Semiconducting Polymers
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PDPP3T is used as active layer material for OPV devices with 6.71% PCE reported when a solvent mixture of DCB/Chloroform/DIO was used.
Being electron rich, PDPP3T is also used as an effective spiro-OMeTAD replacement hole-transport layer material for perovskite solar cells [1], as well as in organic field-effect transistors [2, 3] and printed electronics.
Luminosyn™ PDPP3T
Luminosyn™ PDPP3T is now available.
High purity and good solubility
PDPP3T is purified by soxhlet extraction with methanol, hexane and chlorobenzene under argon atmosphere
Batch-specific GPC data
Have confidence in what you are ordering; batch-specific GPC data for your thesis or publications
Large quantity orders
Plan your experiments with confidence with polymers from the same batch
General Information
Full name | Poly{2,2′-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6- tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]- 5,5′-diyl-alt-thiophen-2,5-diyl} |
Synonyms | PDPP3T, DPP3T |
Chemical formula | (C50H72N2O2S3)n |
CAS number | 1198291-01-8 |
HOMO / LUMO | HOMO = -5.17 eV, LUMO = -3.61 eV [1] |
Solubility | Toluene, chloroform, chlorobenzene, dichlorobenzene |
Classification / Family | Pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells, OFETs |
Chemical Structure

MSDS Documentation
Pricing
Batch | Quantity | Price |
M0991A | 100 mg | £260 |
M0991A | 250 mg | £500 |
M0991A | 500 mg | £950 |
M0991A | 1 g | £1650 |
M0991A | 5 g / 10 g* | Please enquire |
*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.
Batch details
Batch | Mw | Mn | PDI | Stock Info |
M991 | 66,759 | 31,505 | 2.12 | Discontinued |
M0911A1 | 63,931 | 34,736 | 1.84 |
In stock |
M0911A2 | 57,572 | 31,072 | 1.85 | In stock |
Literature and Reviews
- Solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation, A. Dubey et al., Sol. Energ. Mat. Sol. Cells 145, 193–199 (2016);DOI: 10.1016/j.solmat.2015.10.008.
- Optimization of charge carrier transport balance for performance improvement of PDPP3T-based polymer solar cells prepared using a hot solution, J. Wang et al., Phys. Chem. Chem. Phys. 17, 9835--9840 (2015); DOI: 10.1039/c5cp00963d.
- Effects of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane doping on diketopyrrolopyrrole-based, low crystalline, high mobility polymeric semiconductor, S. Yoon et al., Appl. Phys. Lett. 107, 133302 (2015); doi: 10.1063/1.4932530.
To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.