DPPDPy2Br

CAS Number 1455028-34-8

Chemistry Building Blocks, Dibromo Monomers, Heterocyclic Building Blocks, Monomers

Overview
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3,6-Bis(5-bromopyridin-2-yl)-2,5-bis(2-octyldodecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (DPPDPy2Br), CAS number 1455028-34-8, is a pyridine-flanked diketopyrrolopyrrole building block for the synthesis of n-type polymer semiconductors, in the application of OFETs and OPVs. As both diketopyrrolopyrrole and pyridyl units are electron-deficient, they lower the HOMO energy level of the polymer semiconductors - making the polymer suitable as an electron acceptor with good electron mobilities.

This material (DPPDPy2Br) has been used in our own lab for the synthesis of DPPDPyBT (n-type).

General Information

CAS Number	1455028-34-8
Chemical Formula	C₅₆H₈₈Br₂N₄O₂
Molecular Weight	1009.13 g/mol
Synonyms	PyDPP 3,6-Bis(5-bromopyridin-2-yl)-2,5-bis(2-octyldodecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione 3,6- Bis(5-bromopyridin-2-yl)-2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]- pyrrole-1,4(2H,5H)-dione
Classification / Family	Pyrrolo[3,4-c]pyrrole, Organic semiconducting materials, Semiconductor synthesis, Low band-gap polymers, OFETs, OLED, Organic photovoltaics, Polymer solar cells

Chemical Structure

Product Details

Purity	>98%
Melting Point	N/A
Appearance	Red/pink powder

MSDS Documentation

DPPDPy2Br MSDS Sheet

Literature and Reviews

Record High Electron Mobility of 6.3 cm²V^-1s^-1 Achieved for Polymer Semiconductors Using a New Building Block, B. Sun et al., Adv. Mater., 26, 2636-2642 (2014).
A pyridine-flanked diketopyrrolopyrrole (DPP)-based donor–acceptor polymer showing high mobility in ambipolar and n-channel organic thin film transistors, B. Sun, Polym. Chem., 6, 938-945 (2015)

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