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[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid

CAS Number 143613-17-6

Chemistry Building Blocks, Materials, MOF Ligands, Porous Organic Frameworks

Product Code B3001-1g
Price £110 ex. VAT

Metal Organic Frameworks (MOFs) Quaterphenyl Ligand

A linear ligand linker for MOFs in applications of artificial photosynthesis dyes, gas adsorption and separation, and catalysis

Specifications | MSDS | Literature and Reviews

[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid, also known as H2QPDC (CAS number 143613-17-6), is consisted of four phenyl rings joined linearly at 1,4-postions of each phenyl ring and two carboxyl groups (-COOH) at each end of the structure. With a hydrophobic body and hydrophilic heads, H2QPDC tends to form vertically self-assembled monolayers and Langmuir-Blodgett (LB) films.

The carboxyl group (-COOH) at both ends makes [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid an ideal intermediate for the synthesis of metal organic framework (MOF) clusters as linkers. MOFs have shown great potential in various applications, such as heterogeneous catalysis, gas adsorption and separation, sensing, drug delivery, and artificial photosynthesis dyes etc. The unique physical and chemical properties of H2QPBC make it also a potential candidate for application in optoelectronic devices, such as bioelectronics and organic field-effect transistors (OFETs).

General Information

CAS Number 143613-17-6
Chemical Formula C26H18O4
Full Name [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid
Molecular Weight 394.42 g/mol
Synonyms H2QPDC, 4-[4-[4-(4-Carboxyphenyl)phenyl]phenyl]benzoic acid
Classification / Family Quaterphenyls, MOF ligands, 

Chemical Structure

H2QPDC-143613-17-6 chemical structure, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid
[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid (H2QPDC) Chemical Structure, 143613-17-6 

Product Details

Purity >98%
Melting Point Tm = 235 °C – 240 °C
Appearance Off white powder/crystal

MSDS Documentation

143613-17-6, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid MSDS Sheet

Literature and Reviews

  1. A novel series of isoreticular metal organic frameworks: realizing metastable structures by liquid phase epitaxy, J. Liu et al., Sci Rep 2, 921 (2012); DOI: 10.1038/srep00921
  2. Synergistic Steric and Electronic Effects on the Photoredox Catalysis by a Multivariate Library of Titania Metal–Organic Frameworks, J. Bryant et al., J. Am. Chem. Soc., 145 (8), 4589–4600 (2023); DOI: 10.1021/jacs.2c12147.
  3. Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”, A. Ejegbavwo et al., J. Am. Chem. Soc., 141 (29), 11628–11640 (2019); DOI: 10.1021/jacs.9b04737.
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