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Product Code M2286A1-100mg
Price $313 ex. VAT

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DDCzTRZ, high quality and high purity bipolar material

Paired with the donor DMAC-DPS for green TADF-OLED devices with high PLQY and quantum efficiency


DDCzTRZ, has a bipolar structure with four electron donating carbazole moieties attached to two of the phenyl rings of an electron deficient 1,3,5-triphenyltriazine unit at meta-positions.

DDCzTRZ can also form exciplex with electron donor, i.e. DMAC-DPS for green TADF-OLED devices with high photoluminescence quantum yield and high quantum efficiency. Exciplex TADF device with DMAC-DPS:DDCzTrz as active layer materials achieved high quantum efficiency of 13.4%.

Comparing to DCzTRZ, DDCzTrz has greater stability and shows an LT80 of 52 h, while DCzTrz has an LT80 of only 5 h.

General Information

CAS number 1685282-47-6
Full name 9,9',9'',9'''-((6-Phenyl-1,3,5-triazine-2,4-diyl)bis(benzene-5,3,1-triyl))tetrakis(9H -carbazole)
Chemical formula C69H43N7
Molecular weight 970.13 g/mol
Absorption λmax 337 nm (in toluene)
Phosphorescene λmax 461 nm (in toluene)
HOMO/LUMO HOMO = 6.01 eV, LUMO = 2.90 eV [1]
Synonyms 9-(3-(4-(3,5-Di(9H-carbazol-9-yl)phenyl)-6-phenyl-1,3,5-triazin-2-yl)-5-(9H-carbazol-9-yl)phenyl)-9H-carbazole
Classification / Family Triazine derivatives, Light-emitting diodes, Organic electronics, TADF blue emitter, Exciplex green emitter, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point Tg = 218 ℃, Td (Temperature at 5% weight loss) = 493 ℃.
Appearance Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

DDCzTrz chemical structure
Chemical structure of DDCzTRZ, CAS 1685282-47-6

Device Structure(s)

Device structure ITO/PEDOT:PSS/TAPC/mCP/25 wt% DDCzTRZ:DPEPO/TSPO1/TPBI/LiF/Al [1]
Colour blue light emitting device Blue
Max. Current Efficiency 31.3 cd/A
Max. Power Efficiency 26.21 lm W-1
Max. EQE 18.9%
Device structure ITO/MoO3/TAPC/DDCzTRZ/TmPyPb/LiF/Al [2]
Colour white light emitting device White
Max. Luminance 18,796 cd/m2
Max. Current Efficiency 65.4 cd/A
Max. Power Efficiency 68.5 lm W-1
Max. EQE 28.4%
Device structure ITO/HAT-CN (100 nm)/TAPC (20 nm)/mCP: DDCzTrz (10 nm, 20%)/26DCzPPy (3 nm)/Bepp2: Ir(dmppy)2(dpp) (15 nm, 1: 2%)/Bepp2 (35 nm)/LiF (1 nm)/Al (160 nm) [2]
Colour white light emitting device White
Max. Luminance 103,756 cd/m2
Max. Power Efficiency 70.92 lm W-1
Max. EQE 23.5%

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2286A1 100 mg £250
Sublimed (>99.0% purity) M2286A1 250 mg £500
Sublimed (>99.0% purity) M2286A1 500 mg £850
Sublimed (>99.0% purity) M2286A1 1 g £1450

MSDS Documentation

DDCzTRZ MSDSDDCzTRZ MSDS Sheet

Literature and Reviews

  1. Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes, M. Kim et al., Adv. Mater., 27 (15), 2515-2520 (2015); DOI: 10.1002/adma.201500267.
  2. Extremely Simplified, High-Performance, and Doping-Free White Organic Light-Emitting Diodes Based on a Single Thermally Activated Delayed Fluorescent Emitter, D. Lou et al., ACS Energy Lett., 3, 7, 1531–1538 (2018); DOI: 10.1021/acsenergylett.8b00711.
  3. High-performance hybrid white organic light-emitting diodes exploiting blue thermally activated delayed fluorescent dyes, D. Luo et al., Dyes Pigm., 147, 83-89 (2017); DOI: 10.1016/j.dyepig.2017.07.072.
  4. Highly efficient exciplex organic light-emitting diodes using thermally activated delayed fluorescent emitters as donor and acceptor materials, Nanotechnology, 27 (22), 224001 (2016); S. Jeon et al., DOI: 10.1088/0957-4484/27/22/224001.
  5. Recent Progress in High-Efficiency Blue-Light-Emitting Materials for Organic Light-Emitting Diodes, Y. Im et al., Adv. Funct. Mater., 27, 1603007 (2017); DOI: 10.1002/adfm.201603007.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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