Boron-doped Graphene Powder
CAS Number 7782-42-5
2D Materials, Anode Materials, Graphene, Low Dimensional Materials, Materials
Multi-Layer Graphene Doped with Boron
For applications in sensors, fuel cells, supercapacitors, energy storage and batteries.
Overview | Product Information | Related Products
Boron-doped graphene powder (CAS number 7782-42-5) is a multi-layered graphene doped with boron atoms. Boron, one of the important doping elements, can induce electron deficiency in graphene with a p-doping effect, while retaining its original sp2 hybridization and conjugated planar structure. As the electronegativity of boron is smaller than that of carbon, the doping of boron to graphene can lead to a clear differentiation of electron densities on the carbon ring structure.
With a much improved electrocatalytic activity, boron-doped graphene exhibits superior oxygen reduction reaction (ORR) catalytic performance. The electron deficient boron atoms can introduce positive charges to the graphene thus enhancing the adsorption of oxygen and promoting O–O cleavage during ORR. Being relatively positively charged, boron-doped graphene can also improve the adsorption of nitrogen to the surface to form B-N bonds for the reduction of nitrogen to ammonia. With a doping level of 6.2%, boron-doped graphene gained an ammonia production rate of 9.8 μg·hr-1·cm-2 and an excellent faradic efficiency of 10.8% at -0.5 V versus reversible hydrogen electrode.
Multi-Layered
Doped with boron atoms
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Boron-doped graphene is also a promising anode materials for potassium-ion batteries (KIBs) with large capacity, high rate, and good cycling stability performances. Maximum specific capacity of metallic B4C28 anode with a doping concentration of 12.5 at. % can reach 564 mAh/g, larger than that of most anodes for KIBs.
General Information
| CAS Number | 7782-42-5 |
|---|---|
| Chemical Formula | C/B |
| Full Name | Boron-doped Graphene Powder |
| Composite |
Boron content: >11% Carbon content: 88.9% |
| Form | Powder |
| Synonyms | Boron-doped Graphene Powder |
| Classification or Family | Graphene, Doped Graphene, 2D Materials, Carbon Nanomaterials |
Boron-doped Graphene Powder
| Form | Powder |
|---|---|
| Layers | <10 layers |
| Thickness | 5 nm |
| Size | 5 – 10 μm |
Pricing
| Batch | Quantity | Price |
|---|---|---|
| M2372A1 | 100 mg |
£190 |
| M2372A1 | 250 mg |
£380 |
| M2372A1 | 500 mg | £600 |
| M2372A1 | 1 g | £1000 |
MSDS Documentation
Boron-doped Graphene Powder MSDS Sheet
More on Boron-doped Graphene
Strong B-C bond energy preserves the mechanical properties of graphene, although the thermal conductivity of boron-doped graphene is dramatically reduced compared to pristine graphene. The incorporation of boron in graphene finds many potential applications in:
- Sensors
- Electrodes for batteries and supercapacitors
- Energy storage
- Fuel cells
- Electrocatalytic nitrogen/oxygen reduction
References
- Boron-doped graphene synthesis by pulsed laser co-deposition of carbon and boron, Y. Bleu et al., Appl. Surf. Sci., 513, 145843 (2020); DOI: 10.1016/j.apsusc.2020.145843.
- Boron-Doped Graphene for Electrocatalytic N2 Reduction, X. Yu et al., Joule 2, 1610–1622 (2018); DOI: 10.1016/j.joule.2018.06.007.
- Growth and Electronic Structure of Boron-Doped Graphene, J. Gebhardt et al., Phys. Rev. B, 87(15), 155437 2012); DOI:10.1103/PhysRevB.87.155437.
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