1,2,3,4-Butanetetracarboxylic dianhydride (BDA)

CAS Number 4534-73-0

Chemistry Building Blocks, COF Ligands, Diamines and Dianhydrides, Heterocyclic Building Blocks, Monomers, Porous Organic Frameworks

MSDS

1,2,3,4-Butanetetracarboxylic dianhydride (BDA) CAS 4534-73-0

A dianhydride building block

An intermediate for polyester and polyimides synthesis in application of super absorbances, water treatments and wrinkle-free fabrics

Overview
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1,2,3,4-Butanetetracarboxylic dianhydride (BDA, CAS number 4534-73-0) has two succinic anhydrides bridged by a carbon-carbon single bond. 1,2,3,4-Butanetetracarboxylic dianhydride readily reacts with amines and hydroxyls forming imides and esters. BDA is a well-known anti-wrinkle reagent to treat cotton fabrics, as its ability to crosslink the cellulose (through esterification). The breaking and tearing strengths of the fabrics are improved via crosslinking modification. Super absorbance hydrogels can be synthesized from polysaccharide and 1,2,3,4-butanetetracarboxylic dianhydride. The products are applied in water purification and agricultural water retention.

High ionic conductive ionomer can be prepared from BDA and diol. The ionomer is promising to use as solid polymer electrolytes.

General Information

CAS Number	4534-73-0
Chemical Formula	C₈H₆O₆
Full Name	1,2,3,4-Butanetetracarboxylic dianhydride
Molecular Weight	198.13 g/mol
Synonyms	Tetrahydro(3,3'-bifuran)-2,2',5,5'-tetrone, 3-(2,5-Dioxooxolan-3-yl)oxolane-2,5-dione
Classification / Family	Dianhydride building block, Polyesters, Polyimides, Hydrogels, Absorbances

Chemical Structure

Product Details

Purity	>99%
Melting Point	T_m = 242 °C – 243 °C
Appearance	White to pale yellow to slight brown powder/crystal

MSDS Documentation

1,2,3,4-butanetetracarboxylic dianhydride (BDA) MSDS Sheet

Literature and Reviews

Adsorption of Pb(II) ions from contaminated water by 1, 2, 3, 4-butanetetracarboxylic acid-modified microcrystalline cellulose: isotherms, kinetics, and thermodynamic studies, A. Hashem et al., Int. J. Biol. Macromol., 164, 3193-3203(2020); DOI: 10.1016/j.ijbiomac.2020.08.159.
Bio-synthesis of itaconic acid as an anti-crease finish for cellulosic fiber fabric, A. Boondaeng et al., RSC Adv., 11, 25943(2021); DOI: 10.1039/d1ra05037k.
Green routes for the development of chitin/chitosan sustainable hydrogels, M. Maddaloni et al., Sus. Chem., 1, 325–344(2020); DOI: 10.3390/suschem1030022.
Ionomers from step-growth polymerization: highly ordered ionic aggregates and ion conduction, L. Yan et al., Macromolecules, 53, 1777−1784(2020); DOI: 10.1021/acs.macromol.9b02220.
Polysaccharide based superabsorbent hydrogels and their methods of synthesis: A review, M. Qureshi et al., Carbohydrate Polymer Technologies and Applications, 1, 100014(2020); DOI: 10.1016/j.carpta.2020.100014.
Role of crosslinkers for synthesizing biocompatible, biodegradable and mechanically strong hydrogels with desired release profile, S. Zafar et al., Polym. Bull., 79, 9199–9219 (2022); DOI: 10.1007/s00289-021-03956-8.
Superabsorbent polymers used for agricultural water retention, L. Chang et al., Polym. Test., 94, 107021(2021); DOI: 10.1016/j.polymertesting.2020.107021.

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