Titanium Diselenide Crystal


Small

Order Code: M2151A10
Not in stock

Pricing

Size Product code Size description* Quantity (EA) Price
Small M2151A10 >10 mm2 1 £395.00

*typical representative size, areas/dimensions may vary

General Information

CAS number ‎12067-45-7
Chemical formula TiSe2
Molecular weight 205.79 g/mol
Bandgap n/a
Synonyms Titanium selenide (TiSe2), Bis(selanylidene)titanium
Classification / Family Transition metal dichalcogenides (TMDCs), Charge density wave (CDW), Superconductivity, Nano-electronics, Nano-photonics, Photovoltaic, Materials science

Product Details

Form Single Crystal
Preparation Synthetic - Chemical Vapour Transport (CVT)
Purity ≥ 99.999%
Structure ‎Octahedral (1T)
Electronic properties Semimetal, Charge density waves (CDW)
Melting point n/a
Colour Dark brown

General Description

Titanium diselenide (TiSe2) is a family member of Group IV transition metal dichalcogenides (TMDCs), and is of great interest as one of the typical charge density wave (CDW) materials. It is known that the CDW characteristics of TiSe2 can be changed; they are typically suppressed. In some cases, this leads to superconductivity or magnetic order by applying high pressure or intercalation. 

TiSe2 has an octahedral crystal structure (1T, space group D3d) with van der Waals stacked layers. Monolayer TiSe2 consists of stacked Se–Ti–Se atomic layers, in which Ti and Se atoms are strongly bound within the layer. 1T-TiSe2 undergoes a phase transition from a semimetal (1 × 1 × 1 normal phase) to a commensurate CDW (2 × 2 × 2 CDW) at around 200 K.


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Applications

Titanium diselenide has potential applications in optoelectronics, advanced low‐power electronics, superconductors, voltage-controlled oscillators, and ultra-fast electronics.

Synthesis

Titanium diselenide is manufactured using chemical vapour transport (CVT) crystallisation, with crystals having a purity in excess of 99.999%.

Usage

Titanium diselenide single crystals can be used to prepare monolayer and few-layer TiSe2 by mechanical or liquid exfoliation.

Literature and Reviews

  1. Enhancing charge-density-wave order in 1T-TiSe2 nanosheet by encapsulation with hexagonal boron nitride, L. Li et al., Appl. Phys. Lett. 109, 141902 (2016); doi: 10.1063/1.4963885.
  2. Unveiling the charge density wave inhomogeneity and pseudogap state in 1T-TiSe2, K. Zhang et al., Sci. Bull., 63, 426–432 (2018); doi: 10.1016/j.scib.2018.02.018.
  3. Unconventional Charge-Density-Wave Transition in Monolayer 1T‑TiSe2, K. Sugawara et al., ACS Nano, 10, 1341−1345 (2016); DOI: 10.1021/acsnano.5b06727.
  4. Raman Characterization of the Charge Density Wave Phase of 1T-TiSe2: From Bulk to Atomically Thin Layers, D. Duong et al., ACS Nano, 11, 1034−1040 (2017); DOI: 10.1021/acsnano.6b07737.
  5. Hydrogenation-driven phase transition in single-layer TiSe2, F. Iyikanat et al, Nanotechnology 28, 495709 (2017); doi: 10.1088/1361-6528/aa94ab.



To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.