{"product_id":"pndit-f3n","title":"PNDIT-F3N","description":"\u003ch2 id=\"product-oneliner\"\u003en-Type Semiconducting Polymer for Electron Transport Layer\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eAlcohol soluble cathode interlayer material for polymer organic solar cells and perovskite solar cells\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e | \u003ca href=\"#related-products\"\u003eRelated Products\u003c\/a\u003e | \u003ca href=\"#technical-support\"\u003eTechnical Support\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003ePNDIT-F3N is an alternating n-type conjugated copolymer of electron deficient naphthalene diimide and electron rich fluorene backbone units. As a semiconducting polymer, it is used in high performance polymer organic solar cells as an electron transport layer (ETL) interface between the active layer and the cathode.\u003c\/p\u003e\n\u003cp\u003eThe presence of amine groups on the side chains of the polymer can \u003cem\u003en-\u003c\/em\u003edope the acceptor in contact (i.e. to improve the electron extraction properties) and also induce self-doping to generate highly conductive ETLs with reduced ohmic loss for electron transport and extraction. Power conversion efficiency of 19.32% was achieved for a ternary active layer \u003ca href=\"https:\/\/www.ossila.com\/products\/d18\" target=\"_blank\"\u003eD18\u003c\/a\u003e:BTP-3FBr:\u003ca href=\"https:\/\/www.ossila.com\/products\/idic\" target=\"_blank\"\u003eIDIC\u003c\/a\u003e based device using PNDIT-F3N as the electron transport and PEDOT:PSS as the hole transport.\u003c\/p\u003e\n\u003cp\u003eBy mixing two electron transport materials, PNDIT-F3N and \u003ca rel=\"noopener\" title=\"pdinn\" href=\"https:\/\/www.ossila.com\/products\/pdinn\" target=\"_blank\"\u003ePDINN\u003c\/a\u003e (4:1 wt%), the mixed electron transport layer shows better energy level alignment with the active layer and an improved film morphology, leading to better charge selectivity, enhanced charge extraction, suppressed exciton recombination, and finally a boosted PCE in the \u003ca rel=\"noopener\" title=\"pm6, pbdb-t-2f\" href=\"https:\/\/www.ossila.com\/products\/pbdb-t-2f\" target=\"_blank\"\u003ePM6\u003c\/a\u003e:\u003ca rel=\"noopener\" title=\"y6, btp-4f\" href=\"https:\/\/www.ossila.com\/products\/y6\" target=\"_blank\"\u003eY6\u003c\/a\u003e-based solar cells. Additionaly, a polymer organic solar device based on \u003ca rel=\"noopener\" title=\"pm6, pbdb-t-2f\" href=\"https:\/\/www.ossila.com\/products\/pbdb-t-2f\" target=\"_blank\"\u003ePM6\u003c\/a\u003e:\u003ca rel=\"noopener\" title=\"y6, btp-4f\" href=\"https:\/\/www.ossila.com\/products\/y6\" target=\"_blank\"\u003eY6\u003c\/a\u003e as the active layer and PNDIT-F3N and \u003ca rel=\"noopener\" title=\"pdin\" href=\"https:\/\/www.ossila.com\/products\/pdin\" target=\"_blank\"\u003ePDIN\u003c\/a\u003e (3:2 wt%) as the hybrid cathode interlayer yielded higher FF of 74.45% and \u003cem\u003eJ\u003csub\u003eSC\u003c\/sub\u003e\u003c\/em\u003e of 27.12 mA cm\u003csup\u003e2\u003c\/sup\u003e, resulting in a high PCE of 17.4%.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg width=\"50\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Fewer_variables_better_films.svg?v=1697616421\" loading=\"lazy\" height=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eElectron Transport Layer\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eFor polymer \u0026amp; perovskite solar cells\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 margin-top text-center\"\u003e\n\u003cimg width=\"50\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg?v=1698159365\" loading=\"lazy\" height=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003e\u003cspan\u003eSimple Worldwide Shipping\u003c\/span\u003e\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eReliable delivery via tracked courier\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg width=\"50\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg?v=1698833718\" loading=\"lazy\" height=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003en-Type Conjugated Polymer\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eWith better energy alignment\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg width=\"50\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Optical_bandgap.svg?v=1699346628\" loading=\"lazy\" height=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003e1.64 eV Bandgap\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eHOMO = −5.55 eV, LUMO = −3.91 eV\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"panel panel-default\"\u003e\n\u003cdiv class=\"panel-body\"\u003e\n\u003ch3\u003eThe Luminosyn™ Range\u003c\/h3\u003e\n\u003chr\u003e\n\u003cdiv class=\"row\"\u003e\n\u003cdiv class=\"col-xs-12\"\u003e\n\u003cimg height=\"30\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/icon-tick.svg\" style=\"float: left; padding-right: 10px; padding-bottom: 10px;\" width=\"30\"\u003e\u003cstrong\u003eHigh Purity Materials:\u003c\/strong\u003e Purified by Soxhlet extraction with methanol, hexane, and chlorobenzene under argon atmosphere.\u003c\/div\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"row\"\u003e\n\u003cdiv class=\"col-xs-12\"\u003e\n\u003cimg height=\"30\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/icon-tick.svg\" style=\"float: left; padding-right: 10px; padding-bottom: 10px;\" width=\"30\"\u003e\u003cstrong\u003eBatch-Specific Data:\u003c\/strong\u003e Confidence in your materials with batch-specific GPC data for your thesis or publications.\u003c\/div\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"row\"\u003e\n\u003cdiv class=\"col-xs-12\"\u003e\n\u003cimg height=\"30\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/icon-tick.svg\" style=\"float: left; padding-right: 10px; padding-bottom: 10px;\" width=\"30\"\u003e\u003cstrong\u003eLarge Quantity Orders:\u003c\/strong\u003e Plan your experiments with confidence using polymers from the same batch.\u003c\/div\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eCAS Number\u003c\/th\u003e\n\u003ctd\u003e1800206-46-5\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eFull Name\u003c\/th\u003e\n\u003ctd\u003ePoly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-5,5′-bis(2,2′-thiophene)-2,6-naphthalene-1,4,5,8-tetracaboxylic-N,N′-di(2-ethylhexyl)imide]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eChemical Formula\u003c\/th\u003e\n\u003ctd\u003e(C\u003csub\u003e61\u003c\/sub\u003eH\u003csub\u003e70\u003c\/sub\u003eN\u003csub\u003e4\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003eS\u003csub\u003e2\u003c\/sub\u003e)\u003csub\u003en\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eHOMO\/LUMO\u003c\/th\u003e\n\u003ctd\u003e\n\u003cp\u003eHOMO = −5.55 eV\u003c\/p\u003e\n\u003cp class=\"no-margin\"\u003eLUMO = −3.91 eV [1]\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eProcessing Solvents\u003c\/th\u003e\n\u003ctd\u003eMethanol (typically 0.5 mg\/ml in methanol with 0.5% vol acetic acid)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eSynonyms\u003c\/th\u003e\n\u003ctd\u003ePF3N-2TNDI\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eClassification or Family\u003c\/th\u003e\n\u003ctd\u003eHole transport material (HTL), Hole injection material (HIL), OLEDs, Perovskite solar cells, Polymer solar cells\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eBatch Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eBatch Number\u003c\/th\u003e\n\u003cth\u003eMw\u003c\/th\u003e\n\u003cth\u003eMn\u003c\/th\u003e\n\u003cth\u003ePDI\u003c\/th\u003e\n\u003cth\u003eStock Info\u003c\/th\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eM2472A1\u003c\/td\u003e\n\u003ctd\u003e42,808\u003c\/td\u003e\n\u003ctd\u003e11,847\u003c\/td\u003e\n\u003ctd\u003e3.6\u003c\/td\u003e\n\u003ctd\u003eIn stock\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/pndit-f3n-chemical-structure-body-1800206-46-5.png\" title=\"Chemical structure of PNDIT-F3N\" rel=\"noopener\" target=\"_blank\"\u003e\u003cimg loading=\"lazy\" alt=\"Chemical structure of PNDIT-F3N\" width=\"320\" height=\"240\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/pndit-f3n-chemical-structure-body-1800206-46-5.png?height=240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003ePNDIT-F3N Chemical Structure, CAS No. 1800206-46-5\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2 id=\"pricing\"\u003ePricing\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eProduct Code\u003c\/th\u003e\n\u003cth\u003eQuantity\u003c\/th\u003e\n\u003cth\u003ePrice\u003c\/th\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eM2472A1\u003c\/td\u003e\n\u003ctd\u003e100 mg\u003c\/td\u003e\n\u003ctd\u003e[[price gbp=\"310\"]]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eM2472A1\u003c\/td\u003e\n\u003ctd\u003e250 mg\u003c\/td\u003e\n\u003ctd\u003e[[price gbp=\"620\"]]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eM2472A1\u003c\/td\u003e\n\u003ctd\u003e500 mg\u003c\/td\u003e\n\u003ctd\u003e[[price gbp=\"1060\"]]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eM2472A1\u003c\/td\u003e\n\u003ctd\u003e1 g\u003c\/td\u003e\n\u003ctd\u003e[[price gbp=\"1760\"]]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca title=\"PNDIT-F3N MSDS Sheet\" href=\"https:\/\/downloads.ossila.com\/msds\/pndit-f3n.pdf\" target=\"_blank\"\u003e\u003cimg width=\"30\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" loading=\"lazy\" height=\"39\" class=\"msds-icon\" alt=\"PNDIT-F3N MSDS Sheet\"\u003ePNDIT-F3N MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003eC. Sun et al. (2017); \u003cem\u003eInterface Design for High-Efficiency Non-Fullerene Polymer Solar Cells, \u003c\/em\u003eEnergy Environ. Sci., 10, 1784-1791; DOI: 10.1039\/C7EE00601B.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003eZ. Wu et al. (2016); \u003cem\u003en-Type Water\/Alcohol-Soluble Naphthalene Diimide-Based Conjugated Polymers for High-Performance Polymer Solar Cells,\u003c\/em\u003e J. Am. Chem. Soc., 138 (6), 2004-2013; DOI: 10.1021\/jacs.5b12664.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003eS. Ding et al. (2021); \u003cem\u003eBoosting the Efficiency of Non-fullerene Organic Solar Cells via a Simple Cathode Modification Method,\u003c\/em\u003e ACS Appl. Mater. Interfaces, 13, (43), 51078–51085; DOI: 10.1021\/acsami.1c16550.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv id=\"Literature-and-Reviews\" class=\"expandable\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003eH. Song et al. (2022); \u003cem\u003eHybrid Cathode Interlayer Enables 17.4% Efficiency Binary Organic Solar Cells,\u003c\/em\u003e Adv. Sci., 9 (8), 2105575; DOI: 10.1002\/advs.202105575.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003eM. Deng et al. (2023); \u003cem\u003e19.32% Efficiency Polymer Solar Cells Enabled by Fine-Tuning Stacking Modes of Y-Type Molecule Acceptors: Synergistic Bromine and Fluorine Substitution of the End Groups, \u003c\/em\u003eAdv. Mater., 36 (11), 2308216; DOI: 10.1002\/adma.202308216.\u003c\/li\u003e\n\u003cli\u003eY. Li et al. (2022); \u003cem\u003eAn n-n Heterojunction Configuration for Efficient Electron \u003c\/em\u003e\u003cem\u003eTransport in Organic Photovoltaic Devices, \u003c\/em\u003e33 (9), 2209728; Adv. Funct. Mater., 33 (9), 2209728; DOI: 10.1002\/adfm.202209728. (Solubility)\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton type=\"button\" class=\"anchor expand-link\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n\u003ch2 id=\"related-products\"\u003eRelated Products\u003c\/h2\u003e\n\u003chr\u003e\n\u003cdiv class=\"collection-container\"\u003e\n\u003cdiv class=\"collection-tile\"\u003e\u003ca href=\"\/collections\/luminosyn-polymers\"\u003e\n\u003cdiv class=\"collection-button background-light-blue\"\u003e\n\u003cimg alt=\"Luminosyn Polymers Collection\" height=\"109\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/collection-link-luminosyn-polymers.png?width=140\u0026amp;height=109\" width=\"140\"\u003e\n\u003cp\u003e\u003cstrong\u003eLuminosyn™\u003cbr\u003ePolymers\u003c\/strong\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\u003c\/div\u003e\n\u003cdiv class=\"collection-tile\"\u003e\u003ca href=\"\/collections\/interface-polymers\"\u003e\n\u003cdiv class=\"collection-button background-ossila-blue\"\u003e\n\u003cimg alt=\"Luminosyn Polymers Collection\" height=\"109\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/collection-link-Interface-Polymers.png?width=140\u0026amp;height=109\" width=\"140\"\u003e\n\u003cp\u003e\u003cstrong\u003eInterface Polymers\u003c\/strong\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\u003c\/div\u003e\n\u003cdiv class=\"collection-tile\"\u003e\u003ca href=\"\/collections\/transport-layer-materials\"\u003e\n\u003cdiv class=\"collection-button background-light-blue\"\u003e\n\u003cimg alt=\"Charge Transport Layer Collection\" height=\"109\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/collection-link-Electron-Hole-Transport-Layer.png?width=140\u0026amp;height=109\" width=\"140\"\u003e\n\u003cp\u003e\u003cstrong\u003eCharge Transport\u003cbr\u003eLayer Materials\u003c\/strong\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\u003c\/div\u003e\n\u003c\/div\u003e","brand":"Ossila","offers":[{"title":"100 mg","offer_id":48849835819224,"sku":"M2472A1-100mg","price":465.0,"currency_code":"USD","in_stock":true},{"title":"250 mg","offer_id":48849835851992,"sku":"M2472A1-250mg","price":930.0,"currency_code":"USD","in_stock":true},{"title":"500 mg","offer_id":48849835884760,"sku":"M2472A1-500mg","price":1590.0,"currency_code":"USD","in_stock":true},{"title":"1 g","offer_id":48849835917528,"sku":"M2472A1-1g","price":2640.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/pndit-f3n-chemical-structure-title-1800206-46-5.png?v=1726059878","url":"https:\/\/www.ossila.com\/products\/pndit-f3n","provider":"Ossila","version":"1.0","type":"link"}