TPT10-C8C12, TP10 derivative with improved solubility
High purity (≥98%) TPT10-C8C12 for low cost non-fullerene polymer solar cells
TPT10-C8C12 is a family member of the popular non-fullerene acceptor, TPT10 (itself similar to Y6 and Y7). The only difference in chemical structure between TPT10-C8C12 and TPT10 is that the former has larger butyldodecyl side chains. As a result, TPT10-C8C12 is more soluble in common solvents.
Coupled with the wide bandgap copolymer PTQ11, TPT10 has made low-cost, high efficiency non-fullerene polymer solar cells a realistic possibility. The higher solubility of TPT10-C8C12 also makes it possible for non-fullerene polymer solar cells to be solution processible in non-halogenated solvents such as toluene or THF.
|Full name||2,2'- [[12,13-Bis(2-octyldodecyl)-12,13-dihydro-3,9-dinonylbisthieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-e:2',3'-g][2,1,3]benzothiadiazole-2,10-diyl]bis[methylidyne(5 or 6-bromo-3-oxo-1H-indene-2,1(3H)-diylidene) ]]bis[propanedinitrile]|
|Molecular weight||1874.45 g/mol|
|HOMO / LUMO||HOMO = -5.52 eV, LUMO = -3.99 eV (TPT10)|
|UV-Vis||817 nm (in film)|
|Solubility||Toluene, chloroform, chlorobenzene|
|Form||Dark blue powder/crystal|
|Classification / Family||BTP series NFAs, n-type non-fullerene electron acceptors, organic semiconducting materials, low band-gap small molecule, small molecular acceptor, organic photovoltaics, polymer solar cells, NF-PSCs|
|M2253A1||5 g / 10 g||Please contact us for details|
For orders of 5 g or more, a lead time of 4-6 weeks applies.
Literature and Reviews
- High Efficiency Polymer Solar Cells with Efficient Hole Transfer at Zero Highest Occupied Molecular Orbital Offset between Methylated Polymer Donor and Brominated Acceptor, C. Sun et al., J. Am. Chem. Soc., 142, 1465−1474 (2020); DOI: 10.1021/jacs.9b09939.
- Bromination: An Alternative Strategy for Non‐Fullerene Small Molecule Acceptors, H. Wang et al., Adv. Sci (Weinh), 7(9), 1903784 (2020); DOI: 10.1002/advs.201903784.
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