Thienothiophene, Thieno[3,2-b]thiophene
Thienothiophene, for the synthesis of small molecules and polymers
Available online for fast, secure dispatch
Thieno[3,2-b]thiophene, also known as thienothiophene (TT), is a heterocyclic compound. It belongs to the family of fused thiopehenes and is widely used as an intermediate for the synthesis of small molecules and polymers in the application of organic field-effect transistors (OFETs) and organic photovoltaic devices (OPV).
Fused thiophenes are more electron-rich and more structurally rigid, with extended π-conjugation so they are good candidates for adjusting the band gap of the organic polymer semiconducting materials, i.e. Poly[2,5-bis(3-hexadecylthiophen-2-yl)thieno[3,2-b]thiophene] (also known as PBTTT).
![pbttt synthesis with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene and 5,5'-dibromo-4,4'-didodecyl-2,2'-bithiophene or 5,5'-dibromo-4,4'-dihexadecyl-2,2'-bithiophene or 5,5'-dibromo-4,4'-ditetradecyl-2,2'-bithiophene](http://cdn.shopify.com/s/files/1/0823/0287/files/pbttt-synthesis_480x112.jpg?6038470244592440286)
General Information
CAS number | 251-41-2 |
Chemical formula | C6H4S2 |
Molecular weight | 140.23 g/mol |
Synonyms |
|
Classification / Family | Thiophene, Fused thiophene, Dithiapentalene, Heterocylic aromatics, Five-membered ring, Semiconductor synthesis intermediates, Low band gap polymers OFETs, Organic Photovoltaics, Polymer solar cells |
Product Details
Purity | >95% |
Melting point | 56-58°C |
Color | White crystals |
Chemical Structure

MSDS Documentation
Thieno[3,2-b]thiophene MSDS sheet
Literature and Reviews
- Thienothiophenes, Dithienothiophenes, and Thienoacenes: Syntheses, Oligomers, Polymers, and Properties, M. E. Cinar et al., Chem. Rev., (2015), DOI: 10.1021/cr500271a
- A stable solution-processed polymer semiconductor with record high-mobility for printed transistors, Li et al., Sci. Reports, 2, 754, (2012) DOI: 10.1038/srep00754.
- Liquid-crystalline semiconducting polymers with high charge-carrier mobility, I. McCulloch et al., Nat. Mater., 5, 328 (2006)
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.