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PNDI-T10, PCE9 CAS 1977539-03-9
Product Code M2086A1-100mg
Price $500 ex. VAT
$ USD

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PNDI-T10, polymer acceptor for high-efficiency all-PSCs and OFETs

High purity polymer with high electron mobility

PNDI-T10 (also known as PCE9) is a polymer acceptor used in high-efficiency all-polymer solar cells (all-PSCs) and organic field-effect transistors (OFETs).

PNDI-T10 is a family member of polynaphthalene diimide (which is a copolymer of naphthalene diimide with bithiophene and thiophene unit.)

All-PSCs have received great research interest in recent years. This is thanks to the blend of both electron donor and acceptor being polymers in the active layer, and how having complementary absorption covers a wider range of the solar spectrum. Using polymer acceptors (instead of fullerene) in all-PScs also has the advantages of greater morphological stability, superior mechanical properties, and higher capability of being processed with ink-jet printing techniques in flexible devices.

PNDI-T10 has been successfully used in ternary all-PSCs, achieving record performances with PCE of 9% [1]. PNDI-T10 is also a potential candidate for high performance OFET with high electron mobility.

Luminosyn™ PNDI-T10

Luminosyn™ PNDI-T10 is now available.

High molecular weight and high purity
PNDI-T10 is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Large quantity orders
Plan your experiments with the confidence of polymers from the same batch

General Information

Full name Poly{{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}-ran-{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}}
Synonyms PCE9, PNDI-Th10, PNDI(2OD)-T10
Chemical formula (C62H88N2O4S2)0.9 ▪ (C58H86N2O4S)0.1
CAS number 1977539-03-9
HOMO / LUMO HOMO = -6.40 eV, LUMO = -4.10 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, PNDI polymers, Organic photovoltaics, All Polymer solar cells (all-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene

Chemical Structure

PNDI-T10 chemical structure
Chemical structure of PNDI-T10 (PCE9)

MSDS Documentation

PNDI-T10 MSDSPNDI-T10 MSDS sheet

Pricing

Batch Quantity Price
M2086A1 100 mg £400
M2086A1 250 mg £800
M2086A1 500 mg £1450
M2086A1 1 g £2600

Batch details

Batch Mw PDI Stock Info
M2086A1 189,514 2.40 In stock

Literature and Reviews

  1. 9.0% power conversion efficiency from ternary all-polymer solar cells, Z. Li et al., Energy Environ. Sci., 10, 2212 (2017); DOI: 10.1039/c7ee01858d.
  2. High Performance All-Polymer Solar Cells by Synergistic Effects of Fine-Tuned Crystallinity and Solvent Annealing, Z. Li et al., J. Am. Chem. Soc., 138 (34), 10935–10944 (2016); DOI: 10.1021/jacs.6b04822.
  3. Energy-​effectively printed all-​polymer solar cells exceeding 8.61​% efficiency, Y. Lin et al., Nano Energy 46, 428-435 (2018); https://doi.org/10.1016/j.nanoen.2018.02.035.
  4. High-​performance all-​polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-​tuned crystallinity and enhanced dielectric constants, X. Xu et al., Nano Energy 45, 368-379 (2018); https://doi.org/10.1016/j.nanoen.2018.01.012.
  5. High‐Performance and Stable All‐Polymer Solar Cells Using Donor and Acceptor Polymers with Complementary Absorption, Z. Li et al., Adv. Energy Mater., 7 (14), 201602722 (2017); https://doi.org/10.1002/aenm.201602722
  6. Effects of incorporating different chalcogenophene comonomers into random acceptor terpolymers on the morphology and performance of all-polymer solar cells, Y. An et al., Polym. Chem., 9, 593-602 (2018); DIO:10.1039/C7PY01907F.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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