PFN-bromide, PFN-Br

CAS Number 889672-99-5

Cathode Interlayer Materials (CIMs), Interface Polymers, Organic Conductors, Perovskite Interface Materials, Perovskite Materials, Semiconducting Polymers

MSDS

PFN-Br, used to improve extraction efficiencies in organic electronic devices

High quality polymer available for fast, secure dispatch

With hydrophobic backbone and hydrophilic side chains, PFN-Br (CAS number 889672-99-5) is a conjugated polymer electrolyte (CPE). It serves as an electron-interface layer material in organic electronic devices (including OFET, OLED, OPV and perovskite solar cells) to improve the interfacial properties such as extraction efficiency.

PFN-Br interfacial layer embedded in OPV devices gives overall enhanced open-circuit voltage, short-circuit current density and fill factor thus improved device performance. It is also believed that the device performance of polymer LEDs with bilayer cathodes (e.g. PFN-Br/Al), can be enhanced to levels comparable to (and even higher than) those obtained from using Ca or Ba cathodes due to its strong polar ionic pendant groups.

Cathode interlayer molecule

For high efficient OPV applications

Improve extraction efficiency

as a conjugated polyelectrolyte

Worldwide shipping

Quick and reliable shipping

Enhance device performance

strong polar ionic pendant groups

PFN-Br has been used in highly efficient OPV tandem structures with device efficiency over 17%.

General Information

Full name	Poly(9,9-bis(3’-(N,N-dimethyl)-N-ethylammoinium-propyl-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene))dibromide
Synonyms	PFN-bromide PFNBr
Chemical formula	(C₅₆H₈₀N₂Br₂)_n
CAS number	889672-99-5
Classification/Family	Conjugated polymers, Polymer electrolyte, Polyfluorenes, Electron interface layer materials, OLED, OPV, Perovskite materials

Chemical Structure

pfn-br, pfnbr structure — Chemical structure of PFN-Br, CAS# 889672-99-5.

MSDS Documentation

PFN-Br MSDS sheet

Batch information

Batch	Mw	Mn	PDI	Stock info
M2230A1	165 kDa	57 kDa	2.9	Discontinued
M2230A2	190 kDa	61 kDa	3.1	Discontinued
M2230A3	84 kDa	40 kDa	2.1	Out of stock
M2230A4	131 kDa	42 kDa	3.1	In Stock

Pricing

Batch	Quantity	Price
M2230A	100 mg	£280
M2230A	250 mg	£560
M2230A	500 mg	£950

Literature and References

Efficient Electron Injection from a Bilayer Cathode Consisting of Aluminum and Alcohol-/Water-Soluble Conjugated Polymers, H. Wu et al., Adv. Mater., 16, 1826–1830 (2004), DOI: 10.1002/adma.200400067.
High-Performance Polymer Solar Cells Based on a Wide Bandgap Polymer Containing Pyrrolo[3,4- f]benzotriazole5,7-dione with a Power Conversion Efficiency of 8.63%, L. Lan et al., Adv. Sci., 3, 1600032 (2016); DOI: 10.1002/advs.201600032.
Toward high performance inverted polymer solar cells, X. Gong et al., Polymer 53, 5437e5448 (2012); DOI: 10.1016/j.polymer.2012.09.023.

ZnO:Polymer Composite Material to Eliminate Kink in J-V Curves of Inverted Polymer Solar Cells, T. Jin et al., ECS Sol. Stat. Lett., 3 (3) Q9-Q12 (2014); DOI: 10.1149/2.006403ssl.
Organic and solution-processed tandem solar cells with 17.3% efficiency, L. Meng et al., Science 361 (6407), 1094-1098 (2018); DOI: 10.1126/science.aat2612.
Interfacial Modification in Organic and Perovskite Solar Cells, S. Bi et al., Adv. Mater., 1805708 (2018); DOI: 10.1002/adma.201805708.