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mCPPO1

mCPPO1
Product Code M2335A1
Price $246.00 ex. VAT
$ USD

mCPPO1, 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole, has a bipolar character with an electron rich 1,3-di(9H-carbazol-9-yl)benzene core unit and an electron deficient diphenylphosphine oxide attachment.

mCPPO1 is an extended family member of mCP with a higher glass transition temperature (Tg = 114.7 °C), and can be used as a phosphorescent host material for blue, green and red organic light emitting diodes. The bipolar charge transport properties of mCPPO1 can effectively balance holes and electrons in the emitting layer, improving device performance.

General Information

CAS number 1296229-26-9
Full name 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole
Chemical formula C42H29N2OP
Molecular weight 608.67 g/mol
Absorption λmax 324 nm, 338 nm (in DCM)
Phosphorescene λmax 361 nm (in DCM)
HOMO/LUMO HOMO 6.13 eV, LUMO 2.64 eV [1]
Synonyms [9-[3-(9H-Carbazol-9-yl)phenyl]-9H-carbazol-3-yl]diphenylphosphine oxide
Classification / Family Carbazole derivatives, TADF Light-emitting diodes, Organic electronics, PHOLEDs host materials, Sublimed materials.

Product Details

Purity >99.0% (HPLC)
Melting point Tg = 114.7 °C
Appearance White powder/crystals


Chemical Structure

mCPPO1, 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole, 1296229-26-9

Chemical structure of 9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole (mCPPO1), CAS# 1296229-26-9.

Device Structure(s)

Device structure ITO (70 nm)/4wt% ReO3:mCP (30 nm)/mCP (10 nm)/10wt% (HFP)2Ir(mpic):mCPPO1 (30 nm)/TSPO1 (10 nm)/8wt%Rb2CO3:mCP (30 nm)/Al (100 nm) [3]
Colour Blue blue
Max Current Efficiency 27.2 cd/A
Max. Power Efficiency 25.9 lm W-1
Max. EQE 21.4%

 

Device structure ITO (50 nm)/PEDOT(CH8000, 60 nm)/TAPC(20 nm)/mCP(10 nm)/mCPPO1:3wt% Ir(dfpypy)dpm  (25 nm)/TSPO1(35 nm)/LiF(1 nm)/Al (200 nm) [4]
Colour Blue blue
Max Current Efficiency 20.4 cd/A
Max. Power Efficiency 24.7 lm W-1

 

Device structure ITO/PEDOT:PSS (45 nm)/TFB (40 nm)/R-QDs:G-QDs* (18 nm, 1:9)/ZnMgO (40 nm)/Al (2 nm)/IZO (60 nm)/HATCN (20 nm)/TAPC (40 nm)/mCP (5 nm)/Firpic:mCPPO1 (30 nm)/TmPyPB (30 nm)/LiF (1 nm)/Al (100 nm) [5]
Colour White white
Max. Power Efficiency 20.31 lm W-1
Max. EQE 26.02%

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed >99.0% purity M2335A1 100 mg £189.00
Sublimed >99.0% purity M2335A1 250 mg £378.00
Sublimed >99.0% purity M2335A1 500 mg £656.00
Sublimed >99.0% purity M2335A1 1 g £1080.00

MSDS Documentation

mCPPO1 MSDSmCPPO1 MSDS Sheet

Literature and Reviews

  1. External Quantum Efficiency Above 20% in Deep Blue Phosphorescent Organic Light-Emitting Diodes, S. Jeon et al., Adv. Mater., 23 (12), 1436-1441 (2011); DOI: 10.1002/adma.201004372.
  2. Solution processed deep blue phosphorescent organic light-emitting diodes with over 20% external quantum efficiency, K. Yook et al., Org. Electronics, 12 (10); 1711-1715 (2011); DOI: 10.1016/j.orgel.2011.07.004.
  3. Highly efficient deep-blue phosphorescence from heptafluoropropyl-substituted iridium complexes, J. Kim et al., Chem. Commun., 51, 58-61 (2015); DOI: 10.1039/C4CC07768G.
  4. Deep blue phosphorescent organic light-emitting diodes with excellent external quantum efficiency, J. Park et al., Org. Electronics, 14, 3228-3233 (2013); DOI: 10.1016/j.orgel.2013.09.017.
  5. Quantum-dot and organic hybrid tandem light-emitting diodes with multi-functionality of full-color-tunability and white-light-emission, H. Zhang et al., Nat. Commun 11, 2826 (2020), DOI: 10.1038/s41467-020-16659-x.
  6. Fluorine-free Blue Phosphorescent Emitters for Efficient Phosphorescent Organic Light Emitting Diodes, J. Lee et al., J. Mater. Chem. C, 2, 6040-6047 (2014); DOI: 10.1039/C4TC00715H.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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