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Ir(dpm)(piq)2

Ir(dpm)(piq)2
Product Code M2310A1
Price $300.00 ex. VAT
$ USD

Ir(dpm)(piq)2, deep red emitting phosphorescent dopant

High-purity (>99.0%) and available online for priority dispatch

Ir(dpm)(piq)2, namely bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III), is an iso-structure to Ir(dpm)PQ2. Ir(dpm)(piq)2 has one  2,2,6,6-tetramethylheptane-3,5-dionate with two bulky tert-butyl groups and two phenylisoquinoline ligands coordinated to the iridium core.

Ir(dpm)(piq)2 is a deep red emitting phosphorescent dopant and relatively about 30 nm red-shifted while comparing that of Ir(dpm)PQ2.

General Information

CAS number 1202867-58-0
Chemical formula C41H39IrN2O2
Molecular weight 783.98 g/mol
Absorption λmax 354, 479 nm (in DCM)
Photoluminescence λem 628 nm (in DCM)
HOMO/LUMO ET = 2.07 eV [1]
Chemical name Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III)
Synonyms
  • Ir(piq)2(tmd)
  • Piq2Ir(dpm)
  • Bis[2-(1-isoquinolinyl)phenyl](2,2,6,6-tetramethyl-3,5-heptanedionato)iridium
Classification / Family Iridium Complex, Organic electronics, TADF-OLEDs, Panchromatic photoinitiating systems, Red phosphorescent dopant materials, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point TGA > 310 °C (0.5% weight loss)
Appearance Red powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials for OLED devices page.

Chemical Structure

Chemical structure of Ir(dpm)(piq)2, CAS No. 1202867-58-0
Chemical structure of Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III) [Ir(dpm)(piq)2], CAS 1202867-58-0.

Device Structure(s)

Device structure ITO/MoO3/TAPC/BSB:Ir(dpm)(piq)3 (4 wt%)/Eu(TTA)3Phen (0.3 wt%): Ir(dpm)(piq)3:BCBP/TPBi/LiF/Al
Colour red light emitting device Red
Max. Luminance 63,110 cd/m2
Max. current Efficiency 61.71 cd/A
Max. Power Efficiency 64.59 Im/W

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2310A1 100 mg £240
Sublimed (>99.0% purity) M2310A1 250 mg £480
Sublimed (>99.0% purity) M2310A1 500 mg £850
Sublimed (>99.0% purity) M2310A1 1 g £1450

MSDS Documentation

Ir(dpm)(piq)2 MSDS sheet

Literature and Reviews

  1. Photoredox process induced polymerization reactions: Iridium complexes for panchromatic photoinitiating systems, S. Telitel et al., C. R. Chim 19, 71-78 (2016); DOI: 10.1016/j.crci.2015.06.016.
  2. Solution-Processed Organic Light-Emitting Diodes Using a Photo-Crosslinkable Hole-Transporting Layer, J. Park et al., J. Nanosci. Nanotechnol., 20 (8), 4661-4665(2020); DOI: 10.1166/jnn.2020.17832..

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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