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Hex-Ir(phq)3, phosphorescent orange to red emitter
For easy device fabrication and large-area solution processing
Hex-Ir(phq)3, tris[2-(4-n-hexylphenyl)quinoline)]iridium(III), has three phenylquinoline ligands chelated to the iridium centre. Different to Ir(phq)3,The hexyl chain attached to the benzene ring makes Hex-Ir(phq)3 highly soluble in common organic solvents for easy device fabrication and large-area solution processing, i.e. spin-coating or inkjet printing.
Hex-Ir(phq)3 is a phosphorescent orange to red emitting and slight red-shifted in emission while compared to Ir(phq)3.
General Information
CAS number
1268460-37-2
Chemical formula
C63H66IrN3
Molecular weight
1057.43 g/mol
Absorption
λmax 323 nm (dichloromethane)
Photoluminescence
λem 583 nm (dichloromethane)
HOMO/LUMO
HOMO = 4.9 eV, LUMO = 2.8 eV [1]
Chemical name
Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III)
Synonyms
Hex-Ir(phq)3
Classification / Family
Iridium complex, Orange to red phosphorescent materials, Blue dopant materials, Electron transport materials, Sublimed materials, Semiconducting small molecules
Product Details
Purity
Sublimed >99.0% (HPLC)
Melting point
> 260 °C (0.5% weight loss)
Appearance
Red powder/crystals
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials for OLED devices page.
Chemical Structure
Chemical structure of Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III) (Hex-Ir(phq)3)
Highly efficient solution-processed red organic light-emitting diodes with long-side-chained triplet emitter, Y-C. Chao et al., Synth. Met., 161, 148-152 (2011); DOI:10.1016/j.synthmet.2010.11.013.
An Indolocarbazole-Based Thermally Activated Delayed Fluorescence Host for Solution-Processed Phosphorescent Tandem Organic Light-Emitting Devices Exhibiting Extremely Small Efficiency Roll-Off, S. Ohisa et al., Adv. Funct. Mater., 29 (16); 1808022 (2019); DOI: 10.1002/adfm.201808022.
Solution processed multilayer red, green and blue phosphorescent organic light emitting diodes using carbazole dendrimer as a host, a. Hasan et al., J. Luminescence, 183, 150-158 (2017); DOI: 10.1016/j.jlumin.2016.11.054.
ZnO/Polyethyleneimine Ethoxylated/Lithium Bis(trifluoromethanesulfonyl)imide for Solution-Processed Electron Injection Layers in Organic Light-Emitting Devices, Y. Chikayasu et al., J. Photopolym. Sci. Technol., 32 (4); 577-583 (2019); DOI: 10.2494/photopolymer.32.577..
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.
Red
Hex-Ir(phq)3 MSDS sheet