eC9-2Cl for devices with efficiencies approaching 19%
Sister compound to BTP-eC9, available from £271
eC9-2Cl is another highly efficient non-fullerene acceptor that belongs to the Y6 acceptors family. With a fused thienothienopyrrolo-thienothienoindole (TTP-TTI) core, eC9-2Cl is a sister compound to BTP-eC9 with two less chlorine atoms on the peripheral benzene end groups. Comparing to BTP-eC9, the absorption of eC9-2Cl is blue shifted for about 20 nm at its maximum absorption with elevated HOMO/LUMO energy levels.
Device efficiency approaching 19% (certified value of 18.7%) has been achieved by using PBQx-TF as the polymer donor and eC9-2Cl and F-BTA3 as a mixed electron acceptors in single junction organic photovoltaic cells.
Device structure: ITO/PEDOT:PSS/PBQx-TF:eC9-2Cl:F-BTA3 (1:1.2:0.2)/PNDIT-F3N-Br/Al
|Thickness (nm)||VOC (V)||JSC (mA cm-2)||FF (%)||PCE (%)|
|Purity||≥98% (1H NMR)|
|Full name||2,2'- [[12,13-Bis(2-butyloctyl)-12,13-dihydro-3,9-dinonylbisthieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-e:2',3'-g][2,1,3]benzothiadiazole-2,10-diyl]bis[methylidyne(2 or 3-chloro-3-oxo-1H-indene-2,1(3H)-diylidene) ]]bis[propanedinitrile]|
|Molecular weight||1504.96 g/mol|
|HOMO / LUMO||HOMO = -5.57 eV, LUMO = -3.74 eV |
|Solubility||Chloroform, chlorobenzene and dichlorobenzene|
|Form||Dark blue powder/crystal|
|Classification / Family||BTP series NFAs, n-type non-fullerene electron acceptors, Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptor, Organic photovoltaics, Polymer solar cells, NF-PSCs.|
|M2301A1||5 g / 10 g*||Please contact us for details|
*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.
Literature and Reviews
Single-Junction Organic Photovoltaic Cell with 19% Efficiency, Y Cui et al., Adv. Mater., 2102420 (2021); DOI: 10.1002/adma.202102420..
- Self-assembled Monolayer Enables Hole Transport Layer-Free Organic Solar Cells with18% Efficiency and Improved Operational Stability, Y. Lin et al., ACS Energy Lett., 5, 9, 2935–2944 (2020); DOI: 10.1021/acsenergylett.0c01421.
- Chlorination: An Effective Strategy for High-Performance. Organic Solar Cells, Q. Zhao et al., Adv. Sci., 7, 2000509 (2020); DOI: 10.1002/advs.202000509.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.