DMAC-DPS

DMAC-DPS, blue dopant material in TADF-OLED devices

Bipolar charge-transporting capability and high (PLQYs)

DMAC-DPS is great for applications in TADF-OLED devices, thanks to its rather broad blue emission nature with a full width at half-maximum of ≈ 80 nm, short lived excited-state (≈3.0 µs in solid films), bipolar charge-transporting capability, and high photoluminescence quantum yields (PLQYs).

PLQYs of blue-emitting DMAC–DPS can be increased from 0.80 to 0.90 by changing the host from mCP to bis(2-(diphenylphosphino)phenyl)ether oxide (DPEPO).

DMAC-DPS is normally used as a blue dopant material in TADF-OLED devices.

General Information

Product Details

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

Device Structure(s)

Device structure	ITO/HATCN (7 nm)/ TAPC (40 nm)/DCDPA (10 nm)/ CzCbPy: 20 wt% DMAC-DPS (25 nm)/TSPO1 (5 nm)/TPBi (30 nm)/LiF (1.5 nm)/Al (100 nm) [1]
Colour	Blue
Max Current Efficiency	35.0 cd/A
Max EQE	22.9%
Max. Luminance	8, 035 cd/m2

Device structure	ITO/a-NPD (30 nm)/TCTA (20 nm)/CzSi (10 nm)/DMAC–DPS:DPEPO (20 nm)/DPEPO (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al [2]
Colour	Blue
Max EQE	19.5%

Device structure	ITO (180 nm)/ HATCN (10 nm)/ TCTA: 20% HATCN (50 nm)/TCTA (20 nm)/mCP (10 nm)/DMAC-DPS (20 nm)/DPEPO (10 nm)/ BmPyPB:3% Li2CO3 (35 nm)/ Li2CO3(1 nm)/Al (100 nm) [3]
Colour	Blue
Max Current Efficiency	32.3 cd/A
Max EQE	16.6%
Max. Power Efficiency	32.8 lm W-1

Device structure	ITO (180 nm)/ HATCN (10 nm)/ TCTA: 20% HATCN (50 nm)/TCTA (20 nm)/mCP (10 nm)/DPEPO:10% DMAC-DPS (20 nm)/DPEPO (10 nm)/ BmPyPB:3% Li2CO3 (35 nm)/ Li2CO3(1 nm)/Al (100 nm) [3]
Colour	Blue
Max Current Efficiency	40.3 cd/A
Max EQE	20.7%
Max. Power Efficiency	34.3 lm W-1

Device structure	ITO/MoO3 (6 nm)/NPB (70 nm)/mCP (5 nm)/DPDPO2A*:DMAC-DPS (10% wt 20 nm)/DPDPO2A* (5 nm)/BPhen (30 nm)/LiF (1 nm)/Al [4]
Colour	Blue
Max Current Efficiency	42.1 cd/A
Max EQE	22.5%
Max Luminescence	14,626 cd/m2
Max. Power Efficiency	52.9 lm W-1

Pricing

MSDS Documentation

DMAC-DPS MSDS sheet

Literature and Reviews

1. Multi-carbazole encapsulation as a simple strategy for the construction of solution-processed, non-doped thermally activated delayed fluorescence emitters, J. Luo et al., J. Mater. Chem. C, 4, 2442-2446 (2016); DOI: 10.1039/C6TC00418K.
2. Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence, Q. Zhang et al., Nat. Photonics, 8, 326–332 (2014); DOI: 10.1038/nphoton.2014.12.
3. High-Performance Hybrid White Organic Light-Emitting Diodes with Superior Effi ciency/Color Rendering Index/Color Stability and Low Efficiency Roll-Off Based on a Blue Thermally Activated Delayed Fluorescent Emitter, Z. Wu et al., Adv. Funct. Mater., 26, 3306–3313 (2016); DOI: 10.1002/adfm.201505602.
4. A Phosphanthrene Oxide Host with Close Sphere Packing for Ultralow-Voltage-Driven Efficient Blue Thermally Activated Delayed Fluorescence Diodes, H. Yang et al., Adv. Mater., 29, 1700553 (2017); DOI: 10.1002/adma.201700553.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.