DDCzTRZ
DDCzTRZ, high quality and high purity bipolar material
Paired with the donor DMAC-DPS for green TADF-OLED devices with high PLQY and quantum efficiency
DDCzTRZ, has a bipolar structure with four electron donating carbazole moieties attached to two of the phenyl rings of an electron deficient 1,3,5-triphenyltriazine unit at meta-positions.
DDCzTRZ can also form exciplex with electron donor, i.e. DMAC-DPS for green TADF-OLED devices with high photoluminescence quantum yield and high quantum efficiency. Exciplex TADF device with DMAC-DPS:DDCzTrz as active layer materials achieved high quantum efficiency of 13.4%.
Comparing to DCzTRZ, DDCzTrz has greater stability and shows an LT80 of 52 h, while DCzTrz has an LT80 of only 5 h.
General Information
| CAS number | 1685282-47-6 |
|---|---|
| Full name | 9,9',9'',9'''-((6-Phenyl-1,3,5-triazine-2,4-diyl)bis(benzene-5,3,1-triyl))tetrakis(9H -carbazole) |
| Chemical formula | C69H43N7 |
| Molecular weight | 970.13 g/mol |
| Absorption | λmax 337 nm (in toluene) |
| Phosphorescene | λmax 461 nm (in toluene) |
| HOMO/LUMO | HOMO = 6.01 eV, LUMO = 2.90 eV [1] |
| Synonyms | 9-(3-(4-(3,5-Di(9H-carbazol-9-yl)phenyl)-6-phenyl-1,3,5-triazin-2-yl)-5-(9H-carbazol-9-yl)phenyl)-9H-carbazole |
| Classification / Family | Triazine derivatives, Light-emitting diodes, Organic electronics, TADF blue emitter, Exciplex green emitter, Sublimed materials. |
Product Details
| Purity | Sublimed >99.0% (HPLC) |
|---|---|
| Melting point | Tg = 218 ℃, Td (Temperature at 5% weight loss) = 493 ℃. |
| Appearance | Pale yellow powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Chemical Structure
Device Structure(s)
| Device structure | ITO/PEDOT:PSS/TAPC/mCP/25 wt% DDCzTRZ:DPEPO/TSPO1/TPBI/LiF/Al [1] |
|---|---|
| Colour |
 Blue |
| Max. Current Efficiency | 31.3 cd/A |
| Max. Power Efficiency | 26.21 lm W-1 |
| Max. EQE | 18.9% |
| Device structure | ITO/MoO3/TAPC/DDCzTRZ/TmPyPb/LiF/Al [2] |
|---|---|
| Colour |
 White |
| Max. Luminance | 18,796 cd/m2 |
| Max. Current Efficiency | 65.4 cd/A |
| Max. Power Efficiency | 68.5 lm W-1 |
| Max. EQE | 28.4% |
| Device structure | ITO/HAT-CN (100 nm)/TAPC (20 nm)/mCP: DDCzTrz (10 nm, 20%)/26DCzPPy (3 nm)/Bepp2: Ir(dmppy)2(dpp) (15 nm, 1: 2%)/Bepp2 (35 nm)/LiF (1 nm)/Al (160 nm) [2] |
|---|---|
| Colour |
White |
| Max. Luminance | 103,756 cd/m2 |
| Max. Power Efficiency | 70.92 lm W-1 |
| Max. EQE | 23.5% |
*For chemical structure information, please refer to the cited references.
Pricing
| Grade | Order Code | Quantity | Price |
|---|---|---|---|
| Sublimed (>99.0% purity) | M2286A1 | 100 mg | £230 |
| Sublimed (>99.0% purity) | M2286A1 | 250 mg | £460 |
| Sublimed (>99.0% purity) | M2286A1 | 500 mg | £780 |
| Sublimed (>99.0% purity) | M2286A1 | 1 g | £1300 |
MSDS Documentation
DDCzTRZ MSDS Sheet
Literature and Reviews
- Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes, M. Kim et al., Adv. Mater., 27 (15), 2515-2520 (2015); DOI: 10.1002/adma.201500267.
- Extremely Simplified, High-Performance, and Doping-Free White Organic Light-Emitting Diodes Based on a Single Thermally Activated Delayed Fluorescent Emitter, D. Lou et al., ACS Energy Lett., 3, 7, 1531–1538 (2018); DOI: 10.1021/acsenergylett.8b00711.
- High-performance hybrid white organic light-emitting diodes exploiting blue thermally activated delayed fluorescent dyes, D. Luo et al., Dyes Pigm., 147, 83-89 (2017); DOI: 10.1016/j.dyepig.2017.07.072.
- Highly efficient exciplex organic light-emitting diodes using thermally activated delayed fluorescent emitters as donor and acceptor materials, Nanotechnology, 27 (22), 224001 (2016); S. Jeon et al., DOI: 10.1088/0957-4484/27/22/224001.
- Recent Progress in High-Efficiency Blue-Light-Emitting Materials for Organic Light-Emitting Diodes, Y. Im et al., Adv. Funct. Mater., 27, 1603007 (2017); DOI: 10.1002/adfm.201603007.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.