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DCJTB, DCM derivate

chemical structure of dcjtb
Product Code M2177B1
Price $288.00 ex. VAT
$ USD

DCJTB, a dicyanomethylene-4H-pyran (DCM) derivative, is one of the most promising dopant materials. It has been widely used in red and white OLEDs.

With four methyl bulky substituents on the julolidine moiety, and tert-butyl group on the pyran moiety of DCM backbone stucture, DCJTB can efficiently prevent concentration quenching between the emitting materials, which leads to improved device electroluminescence efficiencies.

DCJTB has also been used as an interface material between the dye and acceptor in small molecule organic heterojunction solar cells, retarding the charge recombinations between the donor and the acceptor.

General Information

CAS number 200052-70-6
Full name 4-(Dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran
Chemical formula C30H35N3O
Molecular weight 453.62 g/mol
Absorption* λmax 502 nm in THF
Fluorescence λmax 602 nm in THF
HOMO/LUMO HOMO = 5.4 eV, LUMO = 3.2 eV [1]
Synonyms

4-(Dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran, 
2-tert-Butyl-4-(dicyanomethylene)-6-[2-(1,1,7,7-tetramethyljulolidin-9-yl)vinyl]-4H-pyran
Classification / Family Red dopant materials, OLED red emitters, TADF materials.

* Measurable with an optical spectrometer, see our spectrometer application notes.

Product Details

Purity Unsublimed > 98.0% (HPLC)
Melting point n/a
Appearance Deep red crystals/powder

Chemical Structure

Chemical structure of DCJTB
Chemical structure of DCJTB

Device Structure(s)

Device structure ITO/MoO3 (3 nm)/NPB (20 nm)/TCTA (8 nm)/TCTA:3P-T2T (1:1): 1 wt% DCJTB (15 nm)/3P-T2T (45 nm)/LiF (1 nm)/Al [1]
Colour Red  red
Max. Power Efficiency 21.5 lm W−1
Max. Current Efficiency 22.7 cd/A
Max. EQE  10.15%
Device structure ITO/MoO3 (3 nm)/mCBP (20 nm)/mCBP:PO-T2T:0.4 wt.% DCJTB (20 nm)/PO-T2T (40 nm)/LiF (0.8 nm)/Al [2]
Colour White  white
Max. Power Efficiency 10.39 lm W−1
Max. Current Efficiency 13.25 cd/A
Max. EQE  6.16%
Device structure ITO/HAT-CN (10 nm)/TAPC (55 nm)/TCTA (10 nm)/TCTA:B4PyMPM:2 wt% 4CzIPN:0.5 wt% DCJTB (30 nm)/B4PYMPM (55 nm)/Liq (2 nm)/Al (110 nm) [3]
Colour Orange  orange
Max. Power Efficiency 26.3 lm W−1
Max. Current Efficiency 23.0 cd/A
Max. EQE  12.3%
Device structure ITO/PEDOT:PSS (35 nm)/26DCzPPy:TCTA:10 wt % DMAC-TRZ/1 wt % DCJTB (45 nm)/TmPyPB (50 nm)/CsF(1 nm)/Al [2]
Colour White  white
Max. Power Efficiency 10.3 lm W−1
Max. Current Efficiency 16.4 cd/A
Max. EQE  6.58%
*For chemical structure information, please refer to the cited references

Pricing

Grade Order Code Quantity Price
Unsublimed (>98% purity) M2177B1 250 mg £221.00
Unsublimed (>98% purity) M2177B1 500 mg £359.00
Unsublimed (>98% purity) M2177B1 1 g £590.00

MSDS Documentation

DCJTB MSDSDCJTB MSDS sheet

Literature and Reviews

  1. Highly efficient red OLEDs using DCJTB as the dopant and delayed fluorescent exciplex as the host, B. Zhao et al., Sci. Rep., 5, 10697 (2015); DOI: 10.1038/srep10697.
  2. Simple structured hybrid WOLEDs based on incomplete energy transfer mechanism: from blue exciplex to orange dopant, T. Zhang et al., Sci. Rep., 5, 10234 (2015); DOI: 10.1038/srep10234.
  3. Triplet exciton harvesting by multi-process energy transfer in fluorescent organic light-emitting diodes, D. Li et al., J. Mater. Chem. C, 7, 977 (2019); DOI: 10.1039/c8tc05141k.
  4. Development of a Highly Efficient Hybrid White Organic-LightEmitting Diode with a Single Emission Layer by Solution Processing, J. Wu et al., ACS Appl. Mater. Interfaces, 10, 4851−4859 (2018); DOI: 10.1021/acsami.7b14695.
  5. Simultaneous enhancement of photo- and electroluminescence in white organic light emitting devices by localized surface plasmons of silver nanoclusters, J. Yu et al., Nanotechnology 28, 085206 (2017); doi:10.1088/1361-6528/aa56e3.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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