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CbBPCb

CbBPCb
Product Code M2289A1
Price $263.00 ex. VAT
$ USD

CbBPCb, highly efficient bipolar phosphorescent host

Can achieve high quantum efficiencies in blue PhOLEDs

CbBPCb, having similar structure to the well-known host material mCBP, is a highly efficient carboline-based phosphorescent host with oligophenyl spacer. CbBPCb is bipolar, but shows a higher electron mobility of 3.83×10-6 cm2 V-1 s-1 than its hole mobility of 6.33×10-7 cm2 V-1 s-1.

With a wide bandgap and high triplet energy level, CbBPCb can achieve high quantum efficiencies of over 30.0% in blue phosphorescent organic light emitting diodes. This is due to the host-guest energy transfer, balanced charge injection / transporting and effective exciton confinement within the emitting layer [1, 2]

General Information

CAS number 1469997-91-8
Chemical formula C34H22N4
Molecular weight 486.57 g/mol
Absorption λmax 240 nm, 297 nm (THF)
Photoluminescence λem 382 nm (THF)
HOMO/LUMO HOMO = 6.25 eV, LUMO = 2.79 eV; ET = 2.77 eV [1]
Chemical name 3,3'-Di(9H-pyrido[2,3-b]-indol-9-yl)biphenyl
Synonyms mCbBP
Classification / Family Carboline derivatives, Phosphorescent host materials, Sublimed materials, Semiconducting small molecules

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point mp = 251 °C, Tg = 96 °C (lit.)
Appearance Off-white powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials for OLED devices page.

Chemical Structure

CbBPCb chemical structure, 1469997-91-8
Chemical structure of 3,3'-Di(9H-pyrido[2,3-b]-indol-9-yl)biphenyl (CbBPCb)

Device Structure(s)

Device structure ITO (50 nm)/PEDOT:PSS (60 nm)/TAPC (20 nm)/mCP (10 nm)/CbBPCb:10wt% FIrpic (25 nm)/TSPO1 (35 nm)/LiF (1 nm)/Al (200 nm) [2]
Colour blue light emitting device Blue
Max. Current Efficiency 53.6 cd/A
Max. EQE 30.1
Max. Power Efficiency 50.6 Im/W

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2289A1 100 mg £210
Sublimed (>99.0% purity) M2289A1 250 mg £420
Sublimed (>99.0% purity) M2289A1 500 mg £720
Sublimed (>99.0% purity) M2289A1 1 g £1250

MSDS Documentation

CbBPCb MSDSCbBPCb MSDS sheet

Literature and Reviews

  1. Above 30% External Quantum Efficiency in Blue Phosphorescent Organic Light-Emitting Diodes Using Pyrido[2,3-b]indole Derivatives as Host Materials, C. Lee et al., Adv. Mater., 25(38), 5450-4 (2013); DOI: 10.1002/adma.201301091.
  2. FIrpic: archetypal blue phosphorescent emitter for electroluminescence, E. Baranoff et al., Dalton Trans. 44, 8318-8329 (2015); DOI: 10.1039/C4DT02991G.
  3. Functionalization of phosphorescent emitters and their host materials by main-group elements for phosphorescent organic light-emitting devices, X. Yang et al., Chem. Soc. Rev., 44, 8484-8575 (2015); DOI: 10.1039/C5CS00424A.
  4. High quantum efficiency and color stability in white phosphorescent organic light-emitting diodes using carboline derivative as a host material, B. Kim et al., Org. Electronics, 14 (11), 3024-3029 (2013); DOI: 10.1016/j.orgel.2013.09.005.
  5. A versatile efficient one-step approach for carbazole–pyridine hybrid molecules: highly efficient host materials for blue phosphorescent OLEDs, C. Tang et al., Chem. Commun., 51, 1650-1653 (2015); DOI: 10.1039/C4CC08335K.
  6. Low-Driving-Voltage Blue Phosphorescent Organic Light-Emitting Devices with External Quantum Efficiency of 30%, K. Udagawa et al., 26 (29), 5062-5066 (2014); DOI: 10.1002/adma.201401621.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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