BPy-OXD, excellent ETL and HBL material
Used with electron donating materials to create highly efficient OLED devices
BPy-OXD, 1,3-Bis[2-(2,2'-bipyridine-6-yl)-1,3,4-oxadiazo-5-yl]benzene, is a bipyridyl-substituted oxadiazole derivative with a symmetrical chemical structure of two bipyridyl oxadiazole units being attached on a benzene ring at meta-positions.
Due to the electron deficient nature of both bipyridine and oxadiazole, BPy-OXD has excellent electron accepting, electron transporting, and hole blocking abilities. It also exhibits electrical operation durability with a high glass transition temperature (Tg = 106 ℃). The electron mobility in the vacuum-deposited films of Bpy-OXD is 30 times higher than that of OXD-7.
Compared to OXD-7, which has bulky tert-butyl terminals, BPy-OXD is completely planar due to the intramolecular H---N hydrogen bonding. This leads to significantly large anisotropy of molecular orientation in the film.
BPy-OXD can also be used with electron donating materials, i.e. m-MTDATA, to form exciplexes as active emitting layer materials for highly efficient OLED devices.
|Molecular weight||522.52 g/mol|
|Absorption||λmax 276 nm, 308 nm (in THF)|
|Phosphorescene||λmax 348 nm (in THF)|
|HOMO/LUMO||HOMO = 6.60 eV, LUMO = 2.90 eV |
|Classification / Family||Oxadiazole derivatives, Electron transport layer, Hole blocking layer, Phosphorescent host materials, Light-emitting diodes, Organic electronics, , Sublimed materials.|
|Purity||Sublimed >99.0% (HPLC)|
|Melting point||Tg = 106 ℃|
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
|Device structure||ITO/2-TNATA (10 nm)/NPB (30 nm)/TCTA (10 nm)/CBP:6 wt% Ir(ppy)3 (30 nm)/BCP (10 nm)/Bpy-OXD (30 nm)/LiF/Al |
|Max. Current Efficiency||35.42 cd/A|
|Device structure||ITO/2-TNATA (10 nm)/NPB (30 nm)/TCTA (10 nm)/CBP:6 wt% Ir(ppy)3 (30 nm)/Bphen (10 nm)/Bpy-OXD (30 nm)/LiF/Al |
|Max. Current Efficiency||43.18 cd/A|
|Device structure||ITO/2-TNATA (10 nm)/NPB (30 nm)/TCTA : 10 nm)/CBP : 6 wt% Ir(ppy)3 (20 nm)/Bpy-OXD:6 wt% Ir(ppy)3 (10 nm)/Bphen(10 nm)/Bpy-OXD (30 nm)/LiF/Al |
|Max. Current Efficiency||56.75 cd/A|
*For chemical structure information, please refer to the cited references.
|Sublimed (>99.0% purity)||M2339A1||100 mg||£200|
|Sublimed (>99.0% purity)||M2339A1||250 mg||£400|
|Sublimed (>99.0% purity)||M2339A1||500 mg||£680|
|Sublimed (>99.0% purity)||M2339A1||1 g||£1150|
MSDS DocumentationBPy-OXD MSDS Sheet
Literature and Reviews
- Bipyridyl oxadiazoles as efficient and durable electron-transporting and hole-blocking molecular materials, M. Ichikawa et al., J. Mater. Chem., 16, 221-225 (2006); DOI: 10.1039/B510720B.
- Enhanced electroluminescence and reduced efficiency roll-off in electrophosphorescent devices using a very high electron mobility material as emitter host and electron transporter, T. Li et al., J. Phys. D: Appl. Phys. 42, 065103 (2009); DOI: 10.1088/0022-3727/42/6/065103.
- Reduced efficiency roll-off in phosphorescent organic light emitting diodes at ultrahigh current densities by suppression of triplet-polaron quenching, F. Zang et al., Appl. Phys. Lett. 93, 023309 (2008); DOI: 10.1063/1.2955527.
- Enhancement of electron transport by horizontal molecular orientation of oxadiazole planar molecules in organic amorphous films, D. Yokoyama et al., Appl. Phys. Lett. 95, 243303 (2009); DOI: 10.1063/1.3274135.
- Molecular orientation in small-molecule organic light-emitting diodes, D Yokoyama, J. Mater. Chem., 21, 19187 (2011); DOI: 10.1039/c1jm13417e.
- Many Exciplex Systems Exhibit Organic Long-Persistent Luminescence, N. Nishimura et al., Adv. Funct. Mater., 30 (22), 2000795 (2020); DOI: 10.1002/adfm.202000795.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.