5TCzBN is another sky-blue emitter from the cabzolyl benzonitrile (CBN) family that is used in TADF-OLED devices with great performance.
Acting as an encapsulation shell to the luminophore in 5TCzBN, tert-butyl units are believed to reduce the singlet–triplet splitting (ΔEST) of the compounds, which gives rise to a more efficient reverse inter-system crossing (RISC) process by effectively separating the neighbouring molecules.
|Molecular weight||1490.13 g/mol|
|Absorption*||λmax 420 nm in toluene|
||λem 480 nm in toluene|
|HOMO/LUMO||HOMO = 5.75 eV, LUMO = 2.74 eV, T1 = 2.60 eV |
|Classification / Family||Carbazole, Phthalonitrile, TADF materials, Blue dopant materials, Sublimed materials|
|Purity||Sublimed* >99.0% (1H NMR)|
Tg = 325 °C (lit.)
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
|Device structure||ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCBP:5TCzBN (20 wt%) (30 nm)/DpyPA:Liq (1:1, 30 nm)/LiF (0.5 nm)/Al (150 nm) |
|Max. Power Efficiency||56.1 Im/W|
|Device structure||ITO/HATCN (5 nm)/NPB (40 nm)/TCTA (10 nm)/30 wt% 5TCzBN: DMIC-TRZ (30 nm)/B3PyMPM (40 nm)/LiF (1 nm)/Al (150 nm) |
|Max. Power Efficiency||33.8 Im/W|
|Device structure||ITO/HATCN/NPB (30 nm)/TCTA (10 nm)/5TCzBN: mCBP (30 nm)/DPyPA:Liq (1:1, 30 nm)/Al/LiF (0.5 nm) |
|Half-life Time||12,873h @ 100cd/m2|
*For chemical structure information, please refer to the cited references.
|Sublimed (>99.0% purity)||M2220A1||250 mg||£315.00|
|Sublimed (>99.0% purity)||M2220A1||500 mg||£537.00|
|Sublimed (>99.0% purity)||M2220A1||1 g||£857.00|
Literature and Reviews
- Sterically shielded blue thermally activated delayed fluorescence emitters with improved efficiency and stability, D. Zhang et al., Mater. Horiz., 3, 145-151 (2016); doi: 10.1039/C5MH00258C.
- Highly efficient and stable blue thermally activated delayed fluorescence emitters, D. Zhang et al., SPIE (2016); DIO: 10.1117/2.1201611.006797.
- Perspective on carbazole-based organic compounds as emitters and hosts in TADF applications, B. Wex et al., J. Mater. Chem. C, 5, 8622 (2017); DOI: 10.1039/c7tc02156a.
- Critical role of intermediate electronic states for spin-flip processes in charge-transfer-type organic molecules with multiple donors and acceptors, H. Noda et al., Nat. Mater., 18(10), 1-7 (2019); DOI: 10.1038/s41563-019-0465-6.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.