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What is a Perovskite Solar Cell?


A perovskite solar cell (PSC) is a thin film photovoltaic device which uses a layer of perovskite material to absorb sunlight. This light energy is then converted into electrical energy which can be used in an external circuit. 

Perovskite materials have fundamental properties which make them perfect for use in solar cells. In some ways perovskites are, in fact, even better than the materials used in current solar technology. These impressive photovoltaic properties mean that perovskite solar cells could be used in a lot of interesting situations, and this is one of many reasons why PSCs have caused a lot of excitement in the scientific community.

perovskite solar cell device
Perovskite solar cell fabricated at the University of Sheffield by PhD candidate Timothy Thornber

What is a Perovskite?


Broadly speaking, the term perovskite describes a material with a specific crystal structure. These crystals are naturally occurring in the form of calcium titanate, and have few practical uses. However, if you combine certain organic and inorganic materials in the same structure, you can create a perovskite semiconductor. It is these synthetic perovskites which can be used to make highly efficient solar cells.

perovskite crystal structure
Perovskite crystal structure

One reason why perovskites have excited researchers is that perovskite solar cells have achieved impressive device efficiencies very quickly. In less than 15 years, the maximum efficiency of perovskite solar cells has risen from 3.9% to 25.7%. For context, most solar panels you find today are crystalline silicon (c-Si) solar cells, and it took 37 years for C-Si solar cells to achieve comparable efficiencies.

Advantages of Perovskite Solar Cells


Silicon solar cells currently dominate the market, and have had a considerable head-start compared to perovskite solar cells. However, perovskites have several exciting qualities which mean that they could be very useful when implementing different types of solar technology.

They can be flexible, lightweight, and even semi-transparent

Perovskites absorb visible light very efficiently as they are a direct band gap semiconductor. This means that high efficiency devices can be achieved with a very thin perovskite layer (often less than 1µm thickness).

Perovskite solar cells could potentially be used in situations where silicon solar cells are too heavy, thick , or rigid. For example, flexible PSC devices have been made on plastic substrates, semi-transparent PSCs devices have been used to shade windows while producing small amounts of electricity, and ultra-thin PSC modules have even been used to power a very tiny plane.

They could be cheaply and easily manufactured

Perovskite solar cells can be entirely solution processed. This means that they can be made with methods like slot-die coating and ink jet printing, which are often used in large scale manufacturing. This indicates they could be easily adapted for large area manufacturing. For the dreamers among us, we imagine factories printing solar modules at an extraordinary rate on massive rolls or even a future with paint-on (or spray-on) solar cells. However, PSCs are still a long way from this yet. Perovskites solar cells can be created and deposited through other techniques, such as vacuum deposition and atomic layer deposition – so they are extremely adaptable materials.

Tandem Solar Cells

In a tandem solar cell, multiple solar devices are stacked on top of one another to increase the amount of electrical energy that we can gain from solar irradiance. Perovskites can more efficiently use smaller wavelengths of the sun’s spectrum, so the efficiency of a C-Si solar cell can be improved by depositing a perovskite solar cell on top! Perovskite-silicon tandem devices have achieved efficiencies of up to 31.3%, which is significantly higher than either C-Si or perovskite solar cells individually!

Tandem Solar Cells
Tandem solar cell, multiple solar devices stacked on top

How Are Perovskite Solar Cells Made?


Perovskites have a similar structure to a lot of 3rd generation photovoltaic devices. The perovskite absorber material is placed between two electrodes or electrical contacts. These contacts are connected to an external circuit.

Perovskite solar cell device structure

There are often layers between the perovskite and electrodes, which help draw out specific charges. This structure allows current to flow through the device. These layers on deposited top of one another, and this stack is deposited on a substrate (often glass, but sometimes other materials can be used such as flexible PET).

Each layer needs optimised conditions in order to make a a smooth film. As mentioned before, most of these layers can be deposited using solution processing techniques. Spin coating is the most common method of depositing perovskite layers. Yet, more and more research focuses on scaling up this process. This involves using methods such as slot-die coating or blade coating.

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The Future of Perovskite Solar Cells


Currently, perovskite solar cells are at the research stage of development. Although they have very high efficiencies, they still have some stability issues which need to be tackled before they hit the marketplace. Researchers also need to work out how to convert small area devices to large-area devices and modules without sacrificing efficiency.

However, there are a few companies currently working on commercialising perovskite solar cells, and there is huge scientific interest in this subject. There is plenty of scope for perovskite solar cells to be improved, optimised, and scaled in the not-too-distant future.

  

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Contributing Authors


  • Mary O'Kane
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