{"title":"MOF Ligands","description":"\u003cp\u003eMetal organic framework (MOF) ligands are vital connectors between metal centers and clusters, also known as nodes. Our range of MOF materials are perfect for unlocking the possibilities of novel, functional applications in your research.\u003c\/p\u003e\n\u003ch2 class=\"h3\"\u003eKey Features\u003cbr\u003e\n\u003c\/h2\u003e\n\u003cul\u003e\n\u003cli\u003eOur MOF ligands boast a rigid backbone with a variety of functional groups, including mono-, bi-, tri-, or tetra-carboxylic acids, hydroxyl groups, nitrogen-containing heterocyclic structures, or mixed functional groups. This diversity enables a wide range of applications.\u003c\/li\u003e\n\u003cli\u003eEach MOF ligand carries two sets of functional groups. One set binds to metals, forming the MOF structure. The other set engages in secondary reactivity, post-MOF formation, opening up endless possibilities in material functionality.\u003c\/li\u003e\n\u003cli\u003eThe physical and chemical properties of the connectors play a decisive role in the properties of the resultant MOFs.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch2\u003eBrowse MOF Ligands\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003eRelated categories: \u003ca title=\"Porous Organic Frameworks\" href=\"\/collections\/organic-frameworks\"\u003eporous organic frameworks\u003c\/a\u003e, \u003ca href=\"https:\/\/www.ossila.com\/collections\/metal-organic-frameworks\"\u003emetal-organic frameworks (MOFs)\u003c\/a\u003e, \u003ca title=\"COF Ligands\" href=\"https:\/\/www.ossila.com\/collections\/cof-ligands\"\u003eCOF ligands\u003c\/a\u003e\u003c\/p\u003e\n\u003cp\u003e[[filterby group=\"functional group\" tags=\"aldehyde, amine, anhydride, aniline, boronic acid, carbazole, carboxylic acid, carboxylic acid hydrazide, ether, ethynyl, ethynyl bridge, pyridine, triphenylamine\"]] [[filterby group=\"Number of reaction sites\" tags=\"6 reaction sites, 5 reaction sites, 4 reaction sites, 3 reaction sites, 2 reaction sites\"]] [[filterby group=\"Number of coordination sites\" tags=\"6 coordination sites, 4 coordination sites, 3 coordination sites, 2 coordination sites\"]]\u003c\/p\u003e\n\u003cp\u003e[[split]]\u003c\/p\u003e\n\u003ch2\u003eResources and Support\u003c\/h2\u003e\n\u003chr\u003e\n\u003cdiv class=\"tile-container\"\u003e\n\u003cdiv class=\"card-box card-truncate\"\u003e\n\u003ca href=\"\/pages\/what-are-metal-organic-frameworks\"\u003e\u003cimg width=\"160\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/MOF_with_pore.png?width=160\u0026amp;height=160\u0026amp;crop=center\" loading=\"lazy\" height=\"160\" alt=\"What are Metal Organic Frameworks?\"\u003e\u003c\/a\u003e \u003ca href=\"\/pages\/what-are-metal-organic-frameworks\"\u003eWhat are Metal Organic Frameworks?\u003c\/a\u003e\n\u003cp\u003eMetal-Organic Frameworks (MOFs) are a class of 3D materials that are made up of metals connected by organic linker compounds. Think of metals and organic compounds as building blocks that form structures. These structures come in a variety of shapes and sizes, ranging from 1D to 3D.\u003c\/p\u003e\n\u003ca href=\"\/pages\/what-are-metal-organic-frameworks\"\u003eLearn more...\u003c\/a\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"card-box card-truncate\"\u003e\n\u003ca href=\"\/pages\/how-to-make-metal-organic-frameworks\"\u003e\u003cimg width=\"160\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Solvothermal_MOF_synthesis.svg?v=1718868490\" loading=\"lazy\" height=\"160\" alt=\"How to Make Metal-Organic Frameworks\"\u003e\u003c\/a\u003e \u003ca href=\"\/pages\/how-to-make-metal-organic-frameworks\"\u003eHow to Make Metal-Organic Frameworks\u003c\/a\u003e\n\u003cp\u003eMetal-organic frameworks (MOFs) are made by connecting metal centers with organic linkers through coordination bonds. The process of creating MOFs plays a crucial role in crystal structure formation. This determines their properties and how well they perform in various applications.\u003c\/p\u003e\n\u003ca href=\"\/pages\/how-to-make-metal-organic-frameworks\"\u003eLearn more...\u003c\/a\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e","products":[{"product_id":"2-2-bipyridine-4-4-dicarboxylic-acid","title":"2,2′-Bipyridine-4,4′-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eA well-known bipyridyl ligand with dicarboxylic acid anchoring groups\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eFor the synthesis of organometallic photosensitizer dyes in DSSCs, gap filling self-assembled monolayers or electron selective contact\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2,2′-Bipyridine-4,4′-dicarboxylic acid (dcbpy, CAS number 6813-38-3), have two carboxylic electron withdrawing groups at 4,4'-position, is a well-known bipyridyl derivate that is used for the synthesis of organometallic compounds in application of dye-sensitized solar cells (DSSCs).\u003c\/p\u003e\n\u003cp\u003eIn DSSCs, the double carboxylic groups are chemically anchored onto the nanocrystalline TiO\u003csub\u003e2\u003c\/sub\u003e thin films by forming ester-like linkage to improve the adsorption stability and the electronic coupling between the dye and the semiconductor film surface. Once a dye molecule absorbs the energy from the light, an exciton enters the lowest unoccupied molecular orbital (LUMO), which is localized onto the anchor-containing bipyridyl ligand with conjugation being extended from the pyridine into the anchor group. The exciton can then be effectively injected into the semiconductor film while the bipyridyl groups are chemically bonded to the film.\u003c\/p\u003e\n\u003cp\u003e2,2′-Bipyridine-4,4′-dicarboxylic acid are found in the well-established DSSCs dyes such as \u003ca href=\"https:\/\/www.ossila.com\/products\/n3-dye\" title=\"n3 dye\"\u003eN3\u003c\/a\u003e, \u003ca href=\"https:\/\/www.ossila.com\/products\/n719-dye\" title=\"n719 dye\"\u003eN719\u003c\/a\u003e, \u003ca href=\"https:\/\/www.ossila.com\/products\/z907-dye\" target=\"_blank\" title=\"z907 dye\"\u003eZ907\u003c\/a\u003e and \u003ca href=\"https:\/\/www.ossila.com\/products\/k19-dye\" title=\"k19 dye\"\u003eK19\u003c\/a\u003e dyes, with energy conversion efficiency from light to electricity over 10% recorded under AM 1.5 irradiation.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"MOF and COF ligands\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eMOF and COF ligands\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003ebipyridine ligand for cross-linked COF\/MOF networks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 margin-top text-center\"\u003e\n\u003cimg alt=\"6813-38-3 Worldwide shipping\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Capped with carboxylic acid\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Lab_Proof.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eCapped with carboxylic acid\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003efor coordinating to metal centers\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High purity\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;98% Purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e6813-38-3\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e12\u003c\/sub\u003eH\u003csub\u003e8\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2,2′-Bipyridine-4,4′-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e244.20 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDcbpy, 2,2′-Bipyridyl-4,4′-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBipyridyl derivatives, Semiconductor synthesis intermediates, Dye-sensitized solar cells (DSSCs)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2-2-bipyridine-4-4-dicarboxylic-acid-chemical-structure-body.png\" target=\"_blank\" title=\"2,2′-Bipyridyl-4,4′-dicarboxylic acid, dcbpy, 6813-38-3\"\u003e\u003cimg alt=\"2,2′-Bipyridine-4,4′-dicarboxylic acid (dcbpy) chemical structure, 6813-38-3\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2-2-bipyridine-4-4-dicarboxylic-acid-chemical-structure-body.png?v=1676460363\u0026amp;width=240\u0026amp;height=180\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2,2′-Bipyridine-4,4′-dicarboxylic acid (dcbpy), CAS 6813-38-3\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98% (\u003csup\u003e1\u003c\/sup\u003eH NMR)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;250 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/2-2-bipyridine-4-4-dicarboxylic-acid.pdf\" target=\"_blank\" title=\"2,2′-Bipyridine-4,4′-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"2,2′-bipyridine-4,4′-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2,2′-Bipyridine-4,4′-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eStable, High-Efficiency Ionic-Liquid-Based Mesoscopic Dye-Sensitized Solar Cells,\u003c\/em\u003e D. Kuang et al., Small, 3 (12), 2094-2102 (2007); DOI: 10.1002\/smll.200700211.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHigh molar extinction coefficient amphiphilic ruthenium sensitizers for efficient and stable mesoscopic dye-sensitized solar cells,\u003c\/em\u003e L. Giribabu et al., Energy Environ. Sci., 2, 770-773 (2009); DOI: 10.1039\/B903967H.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eThe photovoltaic stability of, bis(isothiocyanato)rlutheniurn(II)-bis-2, 2′bipyridine-4, 4′-dicarboxylic acid and related sensitizers,\u003c\/em\u003e O. Kohle et al., Adv. Mater., 9 (11), 904-906 (1997); DOI: 10.1002\/adma.19970091111.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eRedox and photochemical behavior of ruthenium(II) complexes with H2dcbpy ligand (H2dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid),\u003c\/em\u003e E. Eskelinen et al., J. Chem. Soc., Dalton Trans., 2745-2752 (2000); DOI: 10.1039\/B004751L.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHigh Molar Extinction Coefficient Heteroleptic Ruthenium Complexes for Thin Film Dye-Sensitized Solar Cells,\u003c\/em\u003e D. Kuan et al., J. Am. Chem. Soc., 128 (12), 4146–4154 (2006); DOI: 10.1021\/ja058540p.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHighly efficient dye sensitized solar cells based on a novel ruthenium sensitizer,\u003c\/em\u003e S. Lu et al., J. Mater. Sci.: Mater. Electron. 24, 2346–2350 (2013): DOI: 10.1007\/s10854-013-1099-0.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHigh Molar Extinction Coefficient Ion-Coordinating Ruthenium Sensitizer for Efficient and Stable Mesoscopic Dye-Sensitized Solar Cells,\u003c\/em\u003e D. Kuang et al., Adv. Funct. Mater., 17 (1), 154-160 (2007); DOI: 10.1002\/adfm.200600483.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHeteroleptic ruthenium complex containing substituted triphenylamine hole-transport unit as sensitizer for stable dye-sensitized solar cell,\u003c\/em\u003e J. Yum et al., Nano energy, 1 (1), 6-12 (2012); DOI: 10.1016\/j.nanoen.2011.08.004.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003ePerovskite Solar Cell Using Isonicotinic Acid as a Gap-Filling Self-Assembled Monolayer with High Photovoltaic Performance and Light Stability,\u003c\/em\u003e T. Sekimoto et al., ACS Appl. Mater. Interfaces, 15 (28), 33581–33592 (2023); DOI: 10.1021\/acsami.3c05215.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"10 g","offer_id":43682263892184,"sku":"B1391-10g","price":280.0,"currency_code":"GBP","in_stock":true},{"title":"25 g","offer_id":43682263924952,"sku":"B1391-25g","price":560.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":43682263859416,"sku":"B1391-5g","price":175.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/2-2-bipyridine-4-4-dicarboxylic-acid-chemical-structure.png?v=1718706710"},{"product_id":"2-2-bipyridine-5-5-dicarboxylic-acid","title":"2,2′-Bipyridine-5,5′-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eA frequent bipyridyl ligand with dicarboxylic acid anchoring groups\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eAs the building block for the synthesis of organometallic compounds and the dicarboxylic acid anchoring groups are key functional groups to form 3D metal-organic frameworks (MOF)\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2,2'-Bipyridine-5,5'-dicarboxylic acid (CAS number 1802-30-8), an isomer to 2,2'-bipyridine-4,4'-dicarboxylic acid, is another bipyridyl structure with dicarboxylic acid anchoring groups at 5,-5'-postions. It is one of the most frequently used heterocyclic building blocks in the synthesis of organometallic compounds and the dicarboxylic acid anchoring groups are key functional groups to form 3D metal-organic frameworks (MOF) which find application in carbon dioxide reduction, organic photocatalysis, water oxidation, antioxidants and lithium- and sodium-ion batteries.\u003c\/p\u003e\n\u003cp\u003eDue to the highly ordered stacking structure of 2,2′-bipyridine-5,5′-dicarboxylic acid (H2bpy) imposed by hydrogen bonding, 2,2′-bipyridine-5,5′-dicarboxylic acid can be employed as anode material showing high specific capacity, good cycle stability, and remarkable rate performance in both lithium and sodium-ion batteries. 2,2′-bipyridine-5,5′-dicarboxylic acid has been reported to possess an ultrahigh initial capacity of lithium-ion battery of 1200 mAh•g\u003csup\u003e-1\u003c\/sup\u003e at a current density of 200 mA•g\u003csup\u003e-1\u003c\/sup\u003e, and the specific capacity can maintain 550 mAh•g\u003csup\u003e-1\u003c\/sup\u003e after 100 cycles.\u003c\/p\u003e\n\u003cp\u003eUsing 2,2'-bipyridine-5,5'-dicarboxylic acid as the binding ligand, both RuH(H2bpy)(PPh3)2(CO)] (I) and [RuH(H2bpy)(AsPh3)2(CO)] (II) shows excellent radical scavenging properties as potential cancer treating agents with less toxicity on normal cell NIH 3T3 and considerable cyto-toxic activity against HeLa and HepG2 cancer cell lines.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Bipyridine building block\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eBipyridine building block\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eas a ligand for porous organic frameworks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 margin-top text-center\"\u003e\n\u003cimg alt=\"Worldwide shipping\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"With multiple functionalities\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Versitile.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eMultiple functionalities\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eused in batteries, photocatalysis and medicinal chemistry\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-6 col-sm-4 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High purity\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;98% Purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1802-30-8\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e12\u003c\/sub\u003eH\u003csub\u003e8\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2,2′-Bipyridine-5,5′-dicarboxylic acid\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e244.20 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e5,5'-Dcbpy, 2,2′-Bipyridyl-5,5′-dicarboxylic acid, 6,6′-Binicotinic acid\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBipyridyl derivatives, Semiconductor synthesis intermediates, Dye-sensitized solar cells (DSSCs)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2-2-bipyridine-5-5-dicarboxylic-acid-chemical-structure-body.png\" target=\"_blank\" title=\"2,2′-Bipyridine-5,5′-dicarboxylic acid, 1802-30-8 chemical structure\"\u003e\u003cimg alt=\"2,2′-Bipyridine-5,5′-dicarboxylic acid chemical structure, 1802-30-8\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2-2-bipyridine-5-5-dicarboxylic-acid-chemical-structure-body.png?v=1676904620\u0026amp;width=240\u0026amp;height=180\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2,2′-Bipyridine-5,5′-dicarboxylic acid (5,5'-dcbpy), CAS 1802-30-8\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98% (\u003csup\u003e1\u003c\/sup\u003eH NMR)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;365 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite off-white to orange powder\/crystals\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/2-2-bipyridine-5-5-dicarboxylic-acid.pdf\" target=\"_blank\" title=\"2,2′-Bipyridine-5,5′-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"2,2′-bipyridine-5,5′-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2,2′-Bipyridine-5,5′-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eBipyridine carboxylic acid as a high-performance anode material for lithium- and sodium-ion batteries,\u003c\/em\u003e Y. Bo et al., Electrochim. Acta, 405, 139628 (2022); DOI: 10.1016\/j.electacta.2021.139628.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCationic Zr-based metal-organic framework via post-synthetic alkylation for selective adsorption and separation of anionic dyes, \u003c\/em\u003eJ. Liu et al., Mater. Today Chem., 24, 100897 (2022); DOI: 10.1016\/j.mtchem.2022.100897.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eProtection Against Cu(II)-Induced Oxidative Stress and Toxicity to Chlorella vulgaris by 2,2′-Bipyridine-5,5′-dicarboxylic Acid,\u003c\/em\u003e Y. Wen et al., Arch. Environ. Contam. Toxicol. 66, 400–406 (2014); DOI: 10.1007\/s00244-013-9977-2\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eSynthesis and Properties of Polyamides and Polyesters On the basis of 2,2‘-Bipyridine-5,5‘-Dicarboxylic Acid and the Corresponding Polymer−Ruthenium Complexes,\u003c\/em\u003e S. Yu et al., Macromolecules, 33 (9), 3259–3273 (2000); DOI: 10.1021\/ma991863j.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eRuthenium(II) complexes of 2,2′-bipyridine-5,5′-dicarboxylic acid: Synthesis, structure, DNA binding, cytotoxicity and antioxidant activity,\u003c\/em\u003e T. Kamatchi et al., Inorganica Chim. Acta, 404, 58-67 (2013); DOI: 10.1016\/j.ica.2013.04.029.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCu2+-Modified Metal–Organic Framework Nanoparticles: A Peroxidase-Mimicking Nanoenzyme,\u003c\/em\u003e W. Chen et al., Small, 14 (5), 1703149 (2018); DOI: 10.1002\/smll.201703149.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eNickel(II) and manganese(II) metal–organic networks driven by 2,2′-bipyridine-5,5′-dicarboxylate blocks: synthesis, structural features, and magnetic properties,\u003c\/em\u003e G. Zhang et al., Transition Met Chem 41, 153–160 (2016); DOI: 10.1007\/s11243-015-0007-2.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDoping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis,\u003c\/em\u003e C. Wang et al., J. Am. Chem. Soc., 133, 34, 13445–13454 (2011); DOI: 10.1021\/ja203564w.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003ePhotoexcitationof Fe3O Nodesin MOFDrivesWaterOxidationat pH=1 WhenRu CatalystIs,\u003c\/em\u003e R. Ezhov et al., hemSusChem, e202202124 (2023); DOI: 10.1002\/cssc.202202124.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"10 g","offer_id":43691655758040,"sku":"B1411-10g","price":200.0,"currency_code":"GBP","in_stock":true},{"title":"25 g","offer_id":43691655790808,"sku":"B1411-25g","price":440.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":43691655725272,"sku":"B1411-5g","price":110.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/2-2-bipyridine-5-5-dicarboxylic-acid-chemical-structure.png?v=1718706710"},{"product_id":"bicyclo2-2-2oct-7-ene-2-3-5-6-tetracarboxylic-acid-dianhydride-coeda","title":"Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA)","description":"\u003ch2 id=\"product-oneliner\"\u003eA dianhydride with a bicyclooctene core\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eMainly used as an intermediate for the preparation of imides and MOFs in application of molecular scaffolds, carbon fixation, and supramolecular architectures\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eBicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA, CAS number 1719-83-1) has a bicyclooctene fused with two succinic anhydrides. The rigidity of Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride enables it to be a robust molecular scaffold for derivatization. COeDA can be derivatised by amines for succinimides while the octene favors electrophilic substitution and olefin metathesis. An inhibitor made from COeDA has shown effectiveness (half maximal inhibitory concentration IC\u003csub\u003e50\u003c\/sub\u003e = 102.2 µM) against SAR-CoV-2 main protease in the inhibition assays. The succinimide derivatives have shown blue\/violet fluorescent under UV radiation, hence they can be applied in bioimaging to monitor their bioactivity.\u003c\/p\u003e\n\u003cp\u003eCOeDA is used to synthesize metal organic cages (MOCs) ligands. The lantern-type MOCs have record high surface area up to 521 m\u003csup\u003e2\u003c\/sup\u003e\/g. Those metal organic complexes can catalyze reaction of CO\u003csub\u003e2\u003c\/sub\u003e and epoxides for the purpose of carbon fixation.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"multi-functional materials\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Versitile.svg?v=1697195129\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eFor multi-functional materials\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eHigh surface area, carbon fixation and fluorescent dye\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Carboxylic building block\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_Polymers.svg?v=1698833718\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eCarboxylic acid dianhydride building block\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eFor the synthesis of MOF and polyimides\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Worldwide shipping for 1719-83-1\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High purity 1719-83-1\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;99% High purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1719-83-1\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e12\u003c\/sub\u003eH\u003csub\u003e8\u003c\/sub\u003eO\u003csub\u003e6\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e249.19 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,10-Dioxatetracyclo[5.5.2.02,6.08,12]tetradec-13-ene-3,5,9,11-tetrone\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDianhydride building block, Polyimides, Molecular scaffolds, MOFs\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/coeda-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA) chemical structure, CAS 1719-83-1.\"\u003e\u003cimg alt=\"Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA) chemical structure, CAS 1719-83-1.\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/coeda-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eBicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA) chemical structure, CAS 1719-83-1\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;99%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cem\u003eT\u003csub\u003em\u003c\/sub\u003e\u003c\/em\u003e = 382 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite to pale yellow powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/bicyclo2-2-2oct-7-ene-2-3-5-6-tetracarboxylic-acid-dianhydride-coeda.pdf\" target=\"_blank\" title=\"Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA) MSDS Sheet\"\u003e\u003cimg alt=\"Bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA)\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003eBicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride (COeDA) MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eDesign, synthesis and evaluation of fused bicyclo[2.2.2]octene as a potential core scaffold for the non-covalent inhibitors of SARS-CoV-2 3CL\u003csup\u003epro\u003c\/sup\u003e main protease\u003c\/em\u003e, B. Herlah et al., Pharmaceuticals, 15, 539(2022); DOI: 10.3390\/ph15050539.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003ePorous metal-organic cages based on rigid bicyclo[2.2.2]oct-7-ene type ligands: synthesis, structure, and gas uptake properties\u003c\/em\u003e, B. Suso et al., Chem. Eur. J., e202300732(2023); DOI: 10.1002\/chem.202300732.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eStructural design of Mn-metal-organic frameworks toward highly efficient solvent-free cycloaddition of CO\u003csub\u003e2\u003c\/sub\u003e\u003c\/em\u003e, H. Li et al., Cryst. Growth Des., 21(7), 3728–3735(2021); DOI: 10.1021\/acs.cgd.1c00037.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eSynthesis, characterization, and crystal structures of imides condensed with p-phenylamino(phenyl) amine and fluorescence property\u003c\/em\u003e, J. Zhang et al., Materials, 12, 1873(2019); DOI: 10.3390\/ma12111873.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTwo unexpected temperature-induced supermolecular isomers from multi-topic carboxylic acid: hydrogen bonding layer or helix tube\u003c\/em\u003e, C. Li et al., Molecules,26, 6938(2021); DOI: 10.3390\/molecules26226938.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"25 g","offer_id":43814280986840,"sku":"B2111-25g","price":110.0,"currency_code":"GBP","in_stock":true},{"title":"50 g","offer_id":43814281019608,"sku":"B2111-50g","price":175.0,"currency_code":"GBP","in_stock":true},{"title":"100 g","offer_id":43814281052376,"sku":"B2111-100g","price":290.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/coeda-chemical-structure-title.png?v=1718706710"},{"product_id":"h2qpdc","title":"[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Quaterphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear ligand linker for MOFs in applications of artificial photosynthesis dyes, gas adsorption and separation, and catalysis\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid, also known as H2QPDC (CAS number 143613-17-6), is consisted of four phenyl rings joined linearly at 1,4-postions of each phenyl ring and two carboxyl groups (-COOH) at each end of the structure. With a hydrophobic body and hydrophilic heads, H2QPDC tends to form vertically self-assembled monolayers and Langmuir-Blodgett (LB) films.\u003c\/p\u003e\n\u003cp\u003eThe carboxyl group (-COOH) at both ends makes [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid an ideal intermediate for the synthesis of metal organic framework (MOF) clusters as linkers. MOFs have shown great potential in various applications, such as heterogeneous catalysis, gas adsorption and separation, sensing, drug delivery, and artificial photosynthesis dyes etc. The unique physical and chemical properties of H2QPBC make it also a potential candidate for application in optoelectronic devices, such as bioelectronics and organic field-effect transistors (OFETs).\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e143613-17-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e26\u003c\/sub\u003eH\u003csub\u003e18\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e394.42 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2QPDC, 4-[4-[4-(4-Carboxyphenyl)phenyl]phenyl]benzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cspan data-mce-fragment=\"1\"\u003eQuaterphenyls, \u003c\/span\u003eMOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2qpdc-143613-17-6-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"143613-17-6 chemical structure, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid\"\u003e\u003cimg alt=\"H2QPDC-143613-17-6 chemical structure, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2qpdc-143613-17-6-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid (H2QPDC) Chemical Structure, 143613-17-6\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cem\u003eT\u003csub\u003em\u003c\/sub\u003e\u003c\/em\u003e = 235 °C – 240 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2qpdc.pdf\" target=\"_blank\" title=\"143613-17-6, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"143613-17-6, [1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e[1,1':4',1'':4'',1'''-Quaterphenyl]-4,4'''-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eA novel series of isoreticular metal organic frameworks: realizing metastable structures by liquid phase epitaxy,\u003c\/em\u003e J. Liu et al., Sci Rep 2, 921 (2012); DOI: 10.1038\/srep00921\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSynergistic Steric and Electronic Effects on the Photoredox Catalysis by a Multivariate Library of Titania Metal–Organic Frameworks,\u003c\/em\u003e J. Bryant et al., J. Am. Chem. Soc., 145 (8), 4589–4600 (2023); DOI: 10.1021\/jacs.2c12147.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eThermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”,\u003c\/em\u003e A. Ejegbavwo et al., J. Am. Chem. Soc., 141 (29), 11628–11640 (2019); DOI: 10.1021\/jacs.9b04737.\u003c\/li\u003e\n\u003c\/ol\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44013311492312,"sku":"B3001-1g","price":220.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44013311459544,"sku":"B3001-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44013311525080,"sku":"B3001-5g","price":650.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2qpdc-143613-17-6-chemical-structure-title.png?v=1718706710"},{"product_id":"h2abedb","title":"4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) 9,10-Bis(phenylethynyl)anthracene Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear ligand linker for MOFs in applications of hydrogen evolution and CO\u003csub\u003e2\u003c\/sub\u003e reduction reactions.\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid, also referred to as H2ABEDB (CAS number 1562777-29-0), is an anthracene derivative with 4-benzoic acids joined linearly at 9,10-poisitons of the central ring of anthracene by two ethynyl groups.\u003c\/p\u003e\n\u003cp\u003eThree-dimensional microporous NNU-27 using 4,4'-(anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid ligand shows new charge transport pathway of long-range π-conjugation of ligand in a zig-zag fashion with a high conductivity of 1.3 (±0.5) × 10\u003csup\u003e-3\u003c\/sup\u003e S\/cm. NNU-28, a Zirconium- ABEDB MOF, is highly efficient for visible light driven CO\u003csub\u003e2\u003c\/sub\u003e reduction with a formate formation rate of 183.3 μmol h\u003csup\u003e−1\u003c\/sup\u003e mmol MOF\u003csup\u003e−1\u003c\/sup\u003e. Anthracene-based ligand serves as an antenna for light harvesting and participates in CO\u003csub\u003e2\u003c\/sub\u003e reduction reaction by radical formation.\u003c\/p\u003e\n\u003cp\u003eZr–ABEDB MOF photocatalyst decorated by 1.0 wt% amount of Pt cocatalyst exhibited a hydrogen evolution rate as high as 704 μmol·h\u003csup\u003e−1\u003c\/sup\u003e·g\u003csup\u003e−1\u003c\/sup\u003e, ca. 220 times of that of pristine Zr–ABEDB MOF (3.2 μmol· h\u003csup\u003e−1\u003c\/sup\u003e·g\u003csup\u003e−1\u003c\/sup\u003e).\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1562777-29-0\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e32\u003c\/sub\u003eH\u003csub\u003e18\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e466.48 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2ABEDB, ADBEB, 4,​4'-​(Diethynylanthracene-​9,​10-​diyl)dibenzoic acid, 4,4'-(9,10-Anthracenediyldi-2,1-ethynediyl)bis-benzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDiethynylanthracene, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2abedb-1562777-29-0-chemical-structure-body.png\" target=\"_blank\" title=\"H2ABEDB chemical structure\"\u003e\u003cimg alt=\"H2ABEDB chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2abedb-1562777-29-0-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid chemical structure, CAS 1562777-29-0\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u003cem\u003en.a.\u003c\/em\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOrange powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2abedb.pdf\" target=\"_blank\" title=\"1562777-29-0 - 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid MSDS Sheet\"\u003e\u003cimg alt=\"1562777-29-0 - 4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzoic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eEffect of Pt cocatalyst on visible light driven hydrogen evolution of anthracene-based zirconium metal-organic framework,\u003c\/em\u003e H. Xing et al., Appl. Surf. Sci., 532 (1), 147000 (2020); DOI: 10.1016\/j.apsusc.2020.147000.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHighly efficient visible-light-driven CO2 reduction to formate by a new anthracene-based zirconium MOF via dual catalytic routes,\u003c\/em\u003e D. Chen et al., J. Mater. Chem. A, 4, 2657-2662 (2016); DOI: 10.1039\/C6TA00429F.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eElectrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains,\u003c\/em\u003e D. Chen et al., Chem. Commun., 52, 2019-2022 (2016); DOI: 10.1039\/C5CC09065B.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eEngineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels,\u003c\/em\u003e C. Ezugwu et al., Coor. Chem., Rev., 450, 214245 (2022); DOI: 10.1016\/j.ccr.2021.214245.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eThe chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion,\u003c\/em\u003e C. Trickett et al., Nat. Rev. Mater., 2, 17045 (2017); DOI: 10.1038\/natrevmats.2017.45.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA visible-light-responsive metal–organic framework for highly efficient and selective photocatalytic oxidation of amines and reduction of nitroaromatics,\u003c\/em\u003e P. Chen et al., J. Mater. Chem. A, 7, 27074-27080 (2019); DOI: 10.1039\/C9TA10723A.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCritical Aspects of Metal–Organic Framework-Based Materials for Solar-Driven CO2 Reduction into Valuable Fuels,\u003c\/em\u003e Y. He et al., Global Chall., 5, 2000082 (2020); DOI: 10.1002\/gch2.202000082.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44019675463896,"sku":"B3011-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44019675398360,"sku":"B3011-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44019675496664,"sku":"B3011-5g","price":690.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2abedb-1562777-29-0-chemical-structure-title.png?v=1718720107"},{"product_id":"h4tcpt","title":"3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) \u003cem\u003ep-T\u003c\/em\u003eerphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear branched ligand linker for MOFs in applications of oxygen, methane and CO\u003csub\u003e2\u003c\/sub\u003e adsorption and iron detection\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-\u003cem\u003ep-\u003c\/em\u003eterphenyl (H4TCPT), CAS number 1816997-25-7, is a linear terphenyl ligand with four side arms of 4-carboxyphenyl groups.\u003c\/p\u003e\n\u003cp\u003eHighly stable MOFs, [Zr\u003csub\u003e6\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e(OH)8(HO)\u003csub\u003e4\u003c\/sub\u003e(L)\u003csub\u003e2\u003c\/sub\u003e ] (BUT-14), where L is H4TCPT, is highly porous with BET surface areas of 3,595 m\u003csup\u003e2\u003c\/sup\u003e g\u003csup\u003e−1\u003c\/sup\u003e , exhibiting excellent selective detection ability toward trace amounts of Fe\u003csup\u003e3+\u003c\/sup\u003e ion over other metal ions in water system in terms of distinct fluorescent quenching. with a detection limit of 212 ppb.\u003c\/p\u003e\n\u003cp\u003eChemically and hydrolytically stable chromium-based MOF Cr-soc-MOF-1 shows extraordinarily high porosity with a surface area of 4,549 m\u003csup\u003e2\u003c\/sup\u003e\/g with the ability to capture 200 wt % of water of its body weight over more than 100 adsorption-desorption cycles. Cr-soc-MOF-1 as an adsorbent find potential applications for water\/moisture adsorption such as moisture control, dehumidification, adsorption-based desalination, and adsorption heating and cooling pumps.\u003c\/p\u003e\n\u003cp\u003eAl-soc-MOF, another MOF platform using H4TCPT ligand as the linkers and aluminum ion clusters as the nodes, can address the challenging dual target of 0.5 g\/g (gravimetric) and 264 cm3 (STP)\/cm\u003csup\u003e3\u003c\/sup\u003e (volumetric) methane storage. Al-soc-MOF also exhibits the highest total gravimetric and volumetric uptake for carbon dioxide and oxygen at relatively high pressures among all microporous MOFs.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1816997-25-7\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e48\u003c\/sub\u003eH\u003csub\u003e30\u003c\/sub\u003eO\u003csub\u003e8\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e710.73 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH4TCPT, 5',5'''-Bis(4-carboxyphenyl)-[1,1':3',1'':4'',1''':3''',1''''-quinquephenyl]-4,4''''- dicarboxylic acid, 5,5-Bis(4-carboxyphenyl)[1,1:3,1:4,1:3,1-quinquephenyl]-4,4-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cem\u003ep-T\u003c\/em\u003eerphenyl, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4tcpt-1816997-25-7-chemical-structure-body.png\" target=\"_blank\" title=\"3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl chemical structure\"\u003e\u003cimg alt=\"3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4tcpt-1816997-25-7-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl chemical structure (H4TCPT) chemical structure, CAS 1816997-25-7\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u003cem\u003en.a.\u003c\/em\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff-white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h4tcpt.pdf\" target=\"_blank\" title=\"1816997-25-7 - 3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl MSDS Sheet\"\u003e\u003cimg alt=\"1816997-25-7 - 3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e3,3′′,5,5′′-tetrakis(4-carboxyphenyl)-p-terphenyl MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eStable fluorescent Zr(IV)-Based Metal−Organic Frameworks with Predesigned Functionalized Ligands for Highly Selective Detection of Fe(III) Ions in Water,\u003c\/em\u003e B. Wang et al., ACS Appl. Mater. Interfaces, 9, 10286−10295 (2017); DOI: 10.1021\/acsami.7b00918.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eReticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water,\u003c\/em\u003e T. Abtab et al., Chem, 4, 94–105 (2018); DOI: 10.1016\/j.chempr.2017.11.005.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMetal organic frameworks and their composites as effective tools for sensing environmental hazards: An up to date tale of mechanism, current trends and future prospects,\u003c\/em\u003e S. Kamal et al., Coor. Chem. Rev., 474, 214859 (2023); DOI: 10.1016\/j.ccr.2022.214859.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eRecent Progress on Microfine Design of Metal–Organic Frameworks: Structure Regulation and Gas Sorption and Separation,\u003c\/em\u003e J. Li et al., Adv. Mater., 32 (44), 2002563 (2020); DOI: 10.1002\/adma.202002563.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage,\u003c\/em\u003e D. Alezi et al., J. Am. Chem. Soc., 137 (41), 13308–13318 (2015); DOI: 10.1021\/jacs.5b07053.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44019886915800,"sku":"B3021-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44019886883032,"sku":"B3021-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44019886948568,"sku":"B3021-5g","price":880.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h4tcpt-1816997-25-7-chemical-structure-title.png?v=1718720078"},{"product_id":"h3ptb","title":"2,4,6-Tris-(p-carboxyphenyl)pyrdin","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Triphenylpyridyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA triangular ligand linker for MOFs in applications of iron detection, carbon dioxide fixation and catalytic reactions\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2,4,6-Tris-(\u003cem\u003ep-\u003c\/em\u003ecarboxyphenyl)pyrdin (H3PTB), CAS number 107063-53-6, is a pyridine-based tritopic linker with three 4-carboxyphenyl groups at 2,4,6-positions of the central pyridine ring.\u003c\/p\u003e\n\u003cp\u003eLuminescent MOF PCN‐604, based on 2,4,6-tris-(\u003cem\u003ep-\u003c\/em\u003ecarboxyphenyl)pyrdin as the ligand linkers and aluminum ion cluster nodes, shows excellent thermal and chemical stability. As a luminescent senor, PCN‐604 shows intense luminescence in water and promising sensitivity and selectivity towards trace amount of Fe\u003csup\u003e3+\u003c\/sup\u003e ions with quenching constant of 2.85 x 10\u003csup\u003e4\u003c\/sup\u003e M\u003csup\u003e‐1\u003c\/sup\u003e and low detection limit of 6.2 μM.\u003c\/p\u003e\n\u003cp\u003eCrystalline framework, [Cu\u003csub\u003e3\u003c\/sub\u003e(H3PTB)\u003csub\u003e2\u003c\/sub\u003e(H\u003csub data-mce-fragment=\"1\"\u003e2\u003c\/sub\u003eO)\u003csub data-mce-fragment=\"1\"\u003e3\u003c\/sub\u003e]\u003csub\u003en\u003c\/sub\u003e, is mesoporous in nature and it is showing dual functionality in the removal of organic dyes. Microporous Zn-H3PTB based anionic MOF shows open channels capturing the cationic dye methylene blue. The Zn-MOF also demonstrates excellent catalytic activity for CO\u003csub\u003e2\u003c\/sub\u003e fixation by cycloaddition reaction with epoxides for the generation of cyclic carbonates.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e107063-53-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e26\u003c\/sub\u003eH\u003csub\u003e17\u003c\/sub\u003eNO\u003csub\u003e6\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2,4,6-Tris-(\u003cem\u003ep-\u003c\/em\u003ecarboxyphenyl)pyrdin\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e439.42 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH3PTB, 4,4',4''-(Pyridine-2,4,6-triyl)tribenzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2,4,6-triphenylpyridine, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h3ptb-107063-53-6-chemical-structure-body.png\" target=\"_blank\" title=\"2,4,6-Tris-(p-carboxyphenyl)pyrdin chemical structure\"\u003e\u003cimg alt=\"2,4,6-Tris-(p-carboxyphenyl)pyrdin chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h3ptb-107063-53-6-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2,4,6-Tris-(\u003cem\u003ep-\u003c\/em\u003ecarboxyphenyl)pyrdin (H3PTB) chemical structure, CAS 107063-53-6\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e368-373 °C \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h3ptb.pdf\" target=\"_blank\" title=\"107063-53-6 - 2,4,6-tris-(p-carboxyphenyl)pyrdin MSDS Sheet\"\u003e\u003cimg alt=\"107063-53-6 - 2,4,6-tris-(p-carboxyphenyl)pyrdin\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2,4,6-Tris-(p-carboxyphenyl)pyrdin MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eDirect synthesis of functionalized PCN-333 via linker design for Fe3+ detection in aqueous media,\u003c\/em\u003e Y. Zhang et al., Dalton Trans., 47, 11806-11811 (2018); DOI: 10.1039\/C8DT01508B.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDual-Functional Mesoporous Copper(II) Metal-Organic Frameworks for the Remediation of Organic Dyes,\u003c\/em\u003e V. Au et al., Chem. Eur. J. 27 (35), 9174-9179 (2021); DOI: 10.1002\/chem.202100289.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eIsoreticular chemistry of scandium analogs of the multicomponent metal–organic framework MIL-142,\u003c\/em\u003e R. Prasad et al., CrystEngComm, 23, 804-812 (2021); DOI: 10.1039\/D0CE01593H.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eAnionic Metal–Organic Framework for Selective Dye Removal and CO2 Fixation,\u003c\/em\u003e S. Kumar et al., Eur. J. Inorg. Chem., 2016 (27), 4373-4377 (2016); DOI: 10.1002\/ejic.201600218.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDirect Catalytic Conversion of CO2 to Cyclic Organic Carbonates under Mild Reaction Conditions by Metal—Organic Frameworks,\u003c\/em\u003e S. Huh, Catalyst, 9 (34), 2019; DOI: 10.3390\/catal9010034\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44020329414872,"sku":"B3031-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44020329349336,"sku":"B3031-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44020329447640,"sku":"B3031-5g","price":690.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h3ptb-107063-53-6-chemical-structure-title.png?v=1718706710"},{"product_id":"h2tpdc-nh2","title":"2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Terphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear ligand linker for MOFs in applications of detection of Al\u003csup\u003e3+\u003c\/sup\u003e, Cr\u003csup\u003e3+\u003c\/sup\u003e and Fe\u003csup\u003e3+\u003c\/sup\u003e ions and trinitrophenol (TNP) in water systems\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eThe organic linker 2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid (H2tpdc-NH2), CAS number 1312703-28-8, contains an electron-accepting carboxylic acid at both end of the linear structure and an electron-donating amino groups in the center of the benzene ring.\u003c\/p\u003e\n\u003cp\u003e2D porous MOF Tb-DBA, consisted of Tb\u003csup\u003e3+\u003c\/sup\u003e cluster nodes and H2tpdc-NH2 linear ligand linkers by a solvothermal method, could detect Al\u003csup\u003e3+\u003c\/sup\u003e, Cr\u003csup\u003e3+\u003c\/sup\u003e and Fe\u003csup\u003e3+\u003c\/sup\u003e ions sensitively, selectively and reversibly. The detection limit is as low as the nM level. Tb-DBA displayed fluorescence enhancement in the presence of Al\u003csup\u003e3+\u003c\/sup\u003e, Cr\u003csup\u003e3+\u003c\/sup\u003e and Fe\u003csup\u003e3+\u003c\/sup\u003e ions. Significantly, Al\u003csup\u003e3+\u003c\/sup\u003e, Cr\u003csup\u003e3+\u003c\/sup\u003e and Fe\u003csup\u003e3+\u003c\/sup\u003e ions could be visually detected under UV light.\u003c\/p\u003e\n\u003cp\u003eChemically stable porous metal organic framework UiO-68@NH2 can detect the presence of trinitrophenol (TNP) in water system at a concentration as low as 0.4 ppm with a response time of a few seconds. Both excitation and emission wavelengths of the MOF are in the visible region with a quenching constant for TNP being found to be 5.8 × 10\u003csup\u003e4\u003c\/sup\u003e M\u003csup\u003e−1\u003c\/sup\u003e.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1312703-28-8\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e20\u003c\/sub\u003eH\u003csub\u003e15\u003c\/sub\u003eNO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e333.34 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2TPDC-NH2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTerphenyl, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2tpdc-nh2-1312703-28-8-chemical-structure-body.png\" target=\"_blank\" title=\"2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid chemical structure\"\u003e\u003cimg alt=\"2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2tpdc-nh2-1312703-28-8-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid (H2TPDC-NH2) chemical structure, CAS 1312703-28-8\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e349 °C (decomp.) \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eYellow powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2tpdc-nh2.pdf\" target=\"_blank\" title=\"1312703-28-8 - 2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"1312703-28-8 - 2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2'-amino-1,1':4,1''-terphenyl-4,4''-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eModulated Synthesis of Zr-Based Metal–Organic Frameworks: From Nano to Single Crystals,\u003c\/em\u003e A. Schaate et al., Chem. Eur. J. 17 (24), 6643-6651 (2011); DOI: 10.1002\/chem.201003211.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA novel 2D metal–organic framework probe: a highly sensitive and visual fluorescent sensor for Al3+, Cr3+ and Fe3+ ions,\u003c\/em\u003e M. Shi et al., New J. Chem., 46, 18911-18916 (2014); DOI: 10.1039\/D2NJ03911G.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eAqueous phase selective detection of 2,4,6-trinitrophenol using a fluorescent metal–organic framework with a pendant recognition site,\u003c\/em\u003e A. Nagarkar et al., Dalton Trans., 44, 15175-15180 (2015); DOI: 10.1039\/C5DT00397K.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eBridging the interfacial gap in mixed-matrix membranes by nature-inspired design: precise molecular sieving with polymer-grafted metal–organic frameworks,\u003c\/em\u003e L. Cseri et al., J. Mater. Chem. A, 9, 23793-23801 (2021); DOI: 10.1039\/D1TA06205K.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMetal–Organic Framework Nanoparticles,\u003c\/em\u003e S. Wang et al., Adv. Mater., 30 (37), 1800202 (2018); DOI: 10.1002\/adma.201800202.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"500 mg","offer_id":44020667220184,"sku":"B3041-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"1 g","offer_id":44020667285720,"sku":"B3041-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44020667318488,"sku":"B3041-5g","price":1055.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2tpdc-nh2-1312703-28-8-chemical-structure-title.png?v=1718706710"},{"product_id":"deedb","title":"Diethyl 4,4′-(ethyne-1,2-diyl)dibenzoate","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Diphenylacetylene Ligand\u003cbr\u003e\n\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear ligand linker for MOFs in applications of hydrogen storage\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eDiethyl 4,4'-(Ethyne-1,2-diyl)dibenzoate (DEEDB) has a triple bond that connects two diethyl 4-benzoates at 1,1'-positions.\u003c\/p\u003e\n\u003cp\u003eIsoquinoline derivatives as potential antifungal agents can be synthesized by reacting diethyl 4,4'-(ethyne-1,2-diyl)dibenzoate with di(phenylmethylene)hydrazine in the presence of Cu(OAc)\u003csub\u003e2\u003c\/sub\u003e·H\u003csub\u003e2\u003c\/sub\u003eO as catalyst and AgSbF\u003csub\u003e6\u003c\/sub\u003e as additive.\u003c\/p\u003e\n\u003cp\u003eGUF-1, an interpenetrated MIL-53 topology Sc-MOF based on 4,4'-(ethyne-1,2-diyl)dibenzoate linker ligand shows excellent volumetric hydrogen storage and working capacity of 41 g\/L in a temperature-pressure swing system.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eCAS Number\u003c\/th\u003e\n\u003ctd\u003e83536-13-4\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eChemical Formula\u003c\/th\u003e\n\u003ctd\u003eC\u003csub\u003e20\u003c\/sub\u003eH\u003csub\u003e18\u003c\/sub\u003eNO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eFull Name\u003c\/th\u003e\n\u003ctd\u003eDiethyl 4,4′-(ethyne-1,2-diyl)dibenzoate\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eMolecular Weight\u003c\/th\u003e\n\u003ctd\u003e322.36 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eSynonyms\u003c\/th\u003e\n\u003ctd\u003eDEEDB, Ethyl 4-[[4-(Ethoxycarbonyl)phenyl]ethynyl]benzoate, Bis[4-(ethoxycarbonyl)phenyl]acetylene, 4,4‘-bis(ethoxycarbonyl)diphenylacetylene\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eClassification \/ Family\u003c\/th\u003e\n\u003ctd\u003eDiphenylacetylene, MOF ligands\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dedbe-83536-13-4-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"DEEDB chemical structure\"\u003e\u003cimg alt=\"DEEDB chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dedbe-83536-13-4-chemical-structure-title.png?height=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eDiethyl 4,4'-(Ethyne-1,2-diyl)dibenzoate (DEEDB) chemical structure, CAS 83536-13-4\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003ePurity\u003c\/th\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eMelting Point\u003c\/th\u003e\n\u003ctd\u003e147.0 to 151.0 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eAppearance\u003c\/th\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/deedb.pdf\" target=\"_blank\" title=\"83536-13-4 - diethyl 4,4'-(Ethyne-1,2-diyl)dibenzoate MSDS Sheet\"\u003e\u003cimg alt=\"83536-13-4 - diethyl 4,4'-(Ethyne-1,2-diyl)dibenzoate\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003eDiethyl 4,4'-(Ethyne-1,2-diyl)dibenzoate MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eModulated self-assembly of an interpenetrated MIL-53 Sc metaleorganic framework with excellent volumetric H2 storage and working capacity,\u003c\/em\u003e A. Thom et al., Mater. Today Chem., 24, 100887 (2022); DOI: 10.1016\/j.mtchem.2022.100887.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eModulated self-assembly of hcp topology MOFs of Zr\/Hf and the extended 4,4′-(ethyne-1,2-diyl)dibenzoate linker\u003c\/em\u003e, S. Boyadjieva et al., CrystEngComm, 25, 2119-2124 (2023); DOI: 10.1039\/D2CE01529C .\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eRegio- and Stereoselective Synthesis of Thiazole-Containing Triarylethylenes by Hydroarylation of Alkynes,\u003c\/em\u003e W. Lee et al., J. Org. Chem., 84 (20), 12913–12924; DOI: 10.1021\/acs.joc.9b01619.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCu(OAc)2.H2O Catalyzed C− H\/C− N Bond Functionalization for the Synthesis of Isoquinoline Derivatives as Potential Antifungal Agent,\u003c\/em\u003e V. Suryawanshi et al., Polycycl. Aromat. Compd., 42 (7), 4404-4412 (2022); DOI: 10.1080\/10406638.2021.1892777.\u003c\/li\u003e\n\u003c\/ol\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44020805042392,"sku":"B3051-1g","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44020805271768,"sku":"B3051-5g","price":600.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/dedbe-83536-13-4-chemical-structure-title.png?v=1718706710"},{"product_id":"h3tcbpb","title":"1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Trigonal Terphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA trigonal nanosized ligand linker for MOFs in applications of hydrogen adsorption\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e1,3,5-Tris[4′-carboxy(1,1′-biphenyl-4-yl)]-benzene (H3TCBPB), CAS number 911818-75-2, a trigonal nanosized carboxylate ligand, has a biphenyl linker between the central phenyl ring and the carboxylic groups. The distance between two carboxylate groups is about 2 nm, and the distance between a carboxylate group and the central benzene ring is 1.2 nm.\u003c\/p\u003e\n\u003cp\u003eAs opposed to other carboxylic acid assemblies, dimers of H3TCBPB furnishes a deformed hexagonal porous network based on energetically inferior 2-fold C−H···O hydrogen bond, instead of 2-fold O−H···O hydrogen bonds as expected. This bonding pattern results in displaced dimers, instead of the much ordered head-to-head arrangement, which allow for higher packing density, and give rise to chiral polymorphs due to their lower symmetry.\u003c\/p\u003e\n\u003cp\u003eMOF based on aluminum ion cluster nodes and H3TCBPB ligand linkers, titled as Al-TCBPB, with a monoclinic crystal structure and a space group c2\/m, exhibits a high BET surface area of 2,311 m\u003csup\u003e2\u003c\/sup\u003e\/g and a total pore volume of 0.80 cm\u003csup\u003e3\u003c\/sup\u003e\/g. It shows an excess hydrogen adsorption of 4.8 and 1.4 wt.% at 9 MPa and 77 and 298 K, respectively.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e911818-75-2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e45\u003c\/sub\u003eH\u003csub\u003e30\u003c\/sub\u003eO\u003csub\u003e6\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e666.72 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH3TCBPB, H3BBC, TCBTB, TCBPB\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTerphenyl, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h3tcbpb-911818-75-2-chemical-structure-body.png\" target=\"_blank\" title=\"Chemical structure of 1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene\"\u003e\u003cimg alt=\"Chemical structure of 1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h3tcbpb-911818-75-2-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene (H3TCBPB) Chemical Structure, CAS 911818-75-2\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e 326 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h3tcbpb.pdf\" target=\"_blank\" title=\"911818-75-2 - 1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene MSDS Sheet\"\u003e\u003cimg alt=\"911818-75-2 - 1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eVersatile Role of Molecule–Surface Interactions for Monolayer Self-Assembly at Liquid–Solid Interfaces: Substrate-Induced Polymorphism, Thermodynamic Stability, and New Polymorphs,\u003c\/em\u003e A. Badami-Behjat et al., Chem. Mater., 34 (19), 8876–8884 (2022); DOI: 10.1021\/acs.chemmater.2c02177.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eStability and Porosity Enhancement through Concurrent Ligand Extension and Secondary Building Unit Stabilization,\u003c\/em\u003e D. Sun et al., Inorg. Chem., 45, 7566−7568 (2006); DOI: 10.1021\/ic0609002.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSynthesis, characterization and hydrogen adsorption properties of metal–organic framework Al-TCBPB,\u003c\/em\u003e D. Saha et al., Intl. J. hydrog. Energy, 37 (6), 5100-5107 (2012); DOI: 10.1016\/j.ijhydene.2011.12.072.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eOn the Scalability of Supramolecular Networks − High Packing Density vs. Optimized Hydrogen Bonds in Tricarboxylic Acid Monolayers,\u003c\/em\u003e J. Dienstmaier et al., Langmuir, 26 (13), 10708–10716 (2010), DOI: 10.1021\/la101634w.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHost–guest chemistry in two-dimensional supramolecular networks,\u003c\/em\u003e J. Teyssandier et al., Chem. Commun., 52, 11465-11487 (2016); DOI: 10.1039\/C6CC05256H.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44020935000280,"sku":"B3061-1g","price":180.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44020935327960,"sku":"B3061-5g","price":720.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h3tcbpb-911818-75-2-chemical-structure-title.png?v=1718706710"},{"product_id":"h4cztb","title":"4,4',4'',4'''-(9H-Carbazole-1,3,6,8-tetrayl)tetrabenzoic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Carbazolyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA star-shaped ligand linker for MOFs in applications of methane adsorption\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4,4',4'',4'''-(9\u003cem\u003eH\u003c\/em\u003e-Carbazole-1,3,6,8-tetrayl)tetrabenzoic acid (H4CzTB) has a cabzolyl core with four 4-benzoic acids side arms around the carbazole ring at 1,3,6,8-poisitions.\u003c\/p\u003e\n\u003cp\u003eMesoporous MOF, PCN-668, Fe3O cluster using 4,4',4'',4'''-(9\u003cem\u003eH\u003c\/em\u003e-carbazole-1,3,6,8-tetrayl)tetrabenzoic acid as ligand linker, shows both nanoscale cage-like building units and one-dimensional (1D) channels with neighbouring cages being mutual diastereomers. Acid stability of PCN-668 can be improved via post-synthetic metal exchange to chromium. PCN-668-Cr exhibits very high stability in both acidic and basic aqueous solutions (pH = 1–11). Additionally, the mesoporous MOF showed a high total gravimetric methane uptake of ∼ 500 cm\u003csup\u003e3\u003c\/sup\u003e g\u003csup\u003e-1\u003c\/sup\u003e at 100 bar.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2097131-99-0\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e40\u003c\/sub\u003eH\u003csub\u003e25\u003c\/sub\u003eO\u003csub\u003e8\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,4',4'',4'''-(9H-Carbazole-1,3,6,8-tetrayl)tetrabenzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e647.63 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH4CzTB, H4BDC, 4-[1,6,8-tris(4-carboxyphenyl)-9H-carbazol-3-yl]-Benzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eCarbazoles, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4cztb-2097131-99-0-chemical-structure-body.png\" target=\"_blank\" title=\"H4CzTB chemical structure\"\u003e\u003cimg alt=\"H4CzTB chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4cztb-2097131-99-0-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e4,4',4'',4'''-(9H-Carbazole-1,3,6,8-tetrayl)tetrabenzoic acid chemical structure, CAS 2097131-99-0\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;97%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e n.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003ePale yellow powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h4cztb.pdf\" target=\"_blank\" title=\"2097131-99-0 - 4,4',4'',4'''-(9H-carbazole-1,3,6,8-tetrayl)tetrabenzoic acid MSDS Sheet\"\u003e\u003cimg alt=\"2097131-99-0 - 4,4',4'',4'''-(9H-carbazole-1,3,6,8-tetrayl)tetrabenzoic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e4,4',4'',4'''-(9H-Carbazole-1,3,6,8-tetrayl)tetrabenzoic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eTuning the Structure of Fe-Tetracarboxylate Frameworks Through Linker-Symmetry Reduction,\u003c\/em\u003e J. Pang et al., CCS Chem., 3 (2), 1701-1709 (2020); DOI: 10.31635\/ccschem.020.202000348.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eVisual pH Sensors: From a Chemical Perspective to New Bioengineered Materials,\u003c\/em\u003e L. Costanzo et al., Molecules, 26, 2952 (2021); DOI: 10.3390\/molecules26102952.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eStable metal–organic frameworks for PEC water splitting,\u003c\/em\u003e Y. Gong et al., Flatchem, 27, 100240 (2021); DOI: 10.1016\/j.flatc.2021.100240.\u003c\/li\u003e\n\u003c\/ol\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44024156881112,"sku":"B3071-1g","price":300.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44024156848344,"sku":"B3071-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44024156913880,"sku":"B3071-5g","price":900.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h4cztb-2097131-99-0-chemical-structure-title.png?v=1718706710"},{"product_id":"h6tphc","title":"[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Terphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA linear ligand linker for MOFs in applications of removing methane blue and highly efficient ion conductivity batteries\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid (H6TPHC), CAS number 1542274-12-3, has a linear terphenyl core with two carboxylic acid groups on each of the benzene rings, 2,5-positions of the central one and 3,5-positions on each of the end ones.\u003c\/p\u003e\n\u003cp\u003ePorous metal–organic framework ZJU-24 with H4TPHC\/H6TPHC as ligand linkers, shows strong interactions with methylene blue and thus the complete removal of methylene blue from aqueous solution can be realized.\u003c\/p\u003e\n\u003cp\u003eHighly electronegative carboxyl-decorated anionic metal–organic framework (MOF), InOF based on indium ion cluster nodes and H6TPHC as the ligand linkers, possesses 12 negative sites that originate from the negatively charged secondary building unit and exposed carboxyl groups on the ligand in one unit cell. The abundant electronegative sites can facilitate the hopping of ions in channels and thus result in highly efficient ion conductivities for various metal ions.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1542274-12-3\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e24\u003c\/sub\u003eH\u003csub\u003e14\u003c\/sub\u003eO\u003csub\u003e12\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e494.36 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH6TPHC, 4-(3,5-dicarboxyphenyl)-[1,1'-biphenyl]-2,3',5,5'-tetracarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTerphenyl, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003cdiv\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h6tphc-1542274-12-3-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"1542274-12-3 - [1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid chemical structure\"\u003e\u003cimg alt=\"1542274-12-3 - [1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid chemical structure\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h6tphc-1542274-12-3-chemical-structure-title.png?v=1718706710\u0026amp;width=240\"\u003e\u003c\/a\u003e\u003c\/div\u003e\n\u003cfigcaption\u003e[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid (H6TPHC) Chemical Structure, 1542274-12-3\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h6tphc.pdf\" target=\"_blank\" title=\"1542274-12-3 - [1,1':4',1''-terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"1542274-12-3 - [1,1':4',1''-terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e[1,1':4',1''-Terphenyl]-2',3,3'',5,5',5''-hexacarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eA porous metal–organic framework with –COOH groups for highly efficient pollutant removal,\u003c\/em\u003e Q. Zhang et al., Chem. Commun., 2014, 14455-14458 (2014); DOI: 10.1039\/C4CC06648K.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMetal-organic frameworks bearing free carboxylic acids: Preparation, modification, and applications,\u003c\/em\u003e B. Bhadra et al., 450, 214237 (2022); DOI: 10.1016\/j.ccr.2021.214237.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eStructural variability, unusual thermochromic luminescence and nitrobenzene sensing properties of five Zn(ii) coordination polymers assembled from a terphenyl-hexacarboxylate ligand,\u003c\/em\u003e X. Wan et al., CrystEngComm, 17, 3829-3837 (2015); DOI: 10.1039\/C5CE00420A.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eTwo Carboxyl-Decorated Anionic Metal–Organic Frameworks as Solid-State Electrolytes Exhibiting High Li+ and Zn2+ Conductivity,\u003c\/em\u003e X. Duan et al., Inorg. Chem., 60, 15, 11032–11037 (2021); DOI: 10.1021\/acs.inorgchem.1c00744.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44024165433560,"sku":"B3081-1g","price":220.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44024165400792,"sku":"B3081-500mg","price":110.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44024165466328,"sku":"B3081-5g","price":750.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h6tphc-1542274-12-3-chemical-structure-title.png?v=1718706710"},{"product_id":"tppm","title":"Tetra(4-(4-pyridyl)phenyl)methane","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Tetraphenylmethane Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid tetrahedral aromatic tecton ligand linker for MOFs in applications of chemisorption of iodine\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eTetra(4-(4-pyridyl)phenyl)methane (TPPM), is a rigid tetrahedral aromatic tecton which can be considered as the decoration of tetraphenylmethane with four \u003cem\u003ep-\u003c\/em\u003esubstituted pyridyl rings. TPPM can act as hydrogen bond acceptor with its four nitrogen atoms forming N···H bondings. Meanwhile, due to the the presence of aromatic rings, TPPM can also give rise to π···π and C-H···π interactions as weak hydrogen bond donor.\u003c\/p\u003e\n\u003cp\u003eThermally stable network [Cu\u003csub\u003e4\u003c\/sub\u003eI\u003csub\u003e4\u003c\/sub\u003e(PPh\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e4\u003c\/sub\u003e]-L, where L is TPPM, uniquely adsorbs iodine (I\u003csub\u003e2\u003c\/sub\u003e) by chemisorption through I\u003csub\u003e3\u003c\/sub\u003e\u003csup\u003e−\u003c\/sup\u003e formation. The chemisorbed I\u003csub\u003e2\u003c\/sub\u003e readily desorbs above 380 K owing to the dynamic motion of the framework.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1319736-15-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e45\u003c\/sub\u003eH\u003csub\u003e32\u003c\/sub\u003eN\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTetra(4-(4-pyridyl)phenyl)methane\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e628.76 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTPPM, Tetrakis(4-(pyridin-4-yl)phenyl)methane\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTetraphenylmethane, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003cdiv\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tppm-1319736-15-6-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"1319736-15-6 - tetra(4-(4-pyridyl)phenyl)methane chemical structure\"\u003e\u003cimg alt=\"1319736-15-6 - tetra(4-(4-pyridyl)phenyl)methane chemical structure\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tppm-1319736-15-6-chemical-structure-title.png?v=1718706710\u0026amp;width=240\"\u003e\u003c\/a\u003e\u003c\/div\u003e\n\u003cfigcaption\u003eTetra(4-(4-pyridyl)phenyl)methane (TPPM) Chemical Structure, 1319736-15-6\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e323 °C (decomp)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/tppm.pdf\" target=\"_blank\" title=\"1319736-15-6 - tetra(4-(4-pyridyl)phenyl)methane MSDS Sheet\"\u003e\u003cimg alt=\"1319736-15-6 - tetra(4-(4-pyridyl)phenyl)methane\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003eTetra(4-(4-pyridyl)phenyl)methane MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eSelective and Reversible Solvent Uptake in Tetra-4-(4-pyridyl)phenylmethane-based Supramolecular Organic Frameworks,\u003c\/em\u003e D. Marchetti et al., Chem. Eur. J., 28, e202202977 (2022); DOI: 10.1002\/chem.202202977.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eKinetic Assembly of a Thermally Stable Porous Coordination Network Based on Labile CuI Units and the Visualization of I2 Sorption,\u003c\/em\u003e H. Kitagawa et al., Angew. Chem., 125 (47), 12621-12625 (2013); DOI: 10.1002\/ange.201306776.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA tetrapyridine ligand with a rigid tetrahedral core forms metal–organic frameworks with PtS type architecture,\u003c\/em\u003e Chem. Commun., 47, 8545–8547 (2011); DOI: 10.1039\/c1cc12188j.\u003c\/li\u003e\n\u003c\/ol\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44024210063576,"sku":"B3091-1g","price":300.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44024210030808,"sku":"B3091-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44024210096344,"sku":"B3091-5g","price":900.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/tppm-1319736-15-6-chemical-structure-title.png?v=1718706710"},{"product_id":"h4qptc","title":"1,1':4',1'':4'',1'''-Quarterphenyl-3,3''',5,5'''-tetracarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Quarterphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of drug delivery and temperature-dependent luminescence\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e1,1':4',1'':4'',1'''-quaterphenyl-3,3''',5,5'''-tetracarboxylic acid (H4QPTC), CAS number 921619-91-2, is a linear quarterphenyl with two carboxylic acid groups at 3,5-positions of each end benzene rings.\u003c\/p\u003e\n\u003cp\u003eMOF with the chemical formula (NH\u003csub\u003e2\u003c\/sub\u003e(CH\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e2\u003c\/sub\u003e[Zn\u003csub\u003e3\u003c\/sub\u003e(L)\u003csub\u003e2\u003c\/sub\u003e·3.5DMF]) (MOF-Zn-H4QPTC) (H4L = 1,1′,4′,1″,4″,1‴-quaterphenyl-3,5,3‴,5‴-tetracarboxylic acid) shows an unusual 4,8-connected 3D structure. The drug 5-fluorouracil (5-FU) uptake into the complex was about 22.5 wt.% per gram of dehydrated form of MOF-Zn-H4QPTC. 5-Fu is then released in a highly controlled and progressive fashion with 92% of the drug being released in 120 h.\u003c\/p\u003e\n\u003cp\u003eAnionic MOF with In(III) centers and tetracarboxylic acid ligands (MOF-In-H4QPTC) shows kinetic trapping behavior of hydrogen. With piperazinium dications in its pores, the framework exhibits hysteretic hydrogen adsorption. \u003c\/p\u003e\n\u003cp\u003eRatiometric thermometer encapsulating luminescent perylene dye into the pores of a europium metal–organic framework (MOF-Eu-H4QPTC), exhibits highly temperature dependent luminescence intensity ratio over the physiological temperature range, with a maximum sensiti­vity of 1.28% °C\u003csup\u003e−1\u003c\/sup\u003e at 20 °C.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e921619-91-2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e28\u003c\/sub\u003eH\u003csub\u003e18\u003c\/sub\u003eO\u003csub\u003e8\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1,1':4',1'':4'',1'''-quaterphenyl-3,3''',5,5'''-tetracarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e482.44 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH4QPTC, Quarterphenyl-3,3''',5,5'''-tetracarboxylic acid\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eQuarterphenyl, MOF ligands, \u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4qptc-921619-91-2-chemical-structure-body.png\" target=\"_blank\" title=\"Chemical structure of 1,1':4',1'':4'',1'''-Quarterphenyl-3,3''',5,5'''-tetracarboxylic acid\"\u003e\u003cimg alt=\"Chemical structure of 1,1':4',1'':4'',1'''-Quarterphenyl-3,3''',5,5'''-tetracarboxylic acid\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4qptc-921619-91-2-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e1,1':4',1'':4'',1'''-quaterphenyl-3,3''',5,5'''-tetracarboxylic acid (H4QPTC) Chemical Structure, 921619-91-2\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff White powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h4qptc.pdf\" target=\"_blank\" title=\"921619-91-2 - 1,1':4',1'':4'',1'''-quaterphenyl-3,3''',5,5'''-tetracarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"921619-91-2 - 1,1':4',1'':4'',1'''-quaterphenyl-3,3''',5,5'''-tetracarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e1,1':4',1'':4'',1'''-Quaterphenyl-3,3''',5,5'''-tetracarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eA new (4,8)-connected topological MOF as potential drug delivery,\u003c\/em\u003e Q. Li et al., Inorg. Chem. Commun., 55, 8-10 (2015); DOI: 10.1016\/j.inoche.2015.02.023.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eLoading Photochromic Molecules into a Luminescent Metal–Organic Framework for Information Anticounterfeiting,\u003c\/em\u003e Z. Li et al., Angew. Chem., 131 (50), 18193-18199 (2019); DOI: 10.1002\/ange.201910467.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCation-induced kinetic trapping and enhanced hydrogen adsorption in a modulated anionic metal–organic framework,\u003c\/em\u003e S. Yang et al., Nat. Chem., 1, 487–493 (2009); DOi: 10.1038\/nchem.333\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eOur journey of developing dual-emitting metal-organic framework-based fluorescent sensors,\u003c\/em\u003e T. Xia et al., ZAAC, 648 (9), e202100355 (2022); DOI: 10.1002\/zaac.202100355.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eEnergy Transfer in Metal–Organic Frameworks for Fluorescence Sensing,\u003c\/em\u003e J. Wang et al., ACS Appl. Mater. Interfaces, 14 (8), 9970–9986 (2022); DOI: 10.1021\/acsami.1c24759.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDual-Emitting MOF⊃Dye Composite for Ratiometric Temperature Sensing,\u003c\/em\u003e Y. Cui et al., 27 (8), 1420-1425 (2015); DOI: 10.1002\/adma.201404700.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44024292081880,"sku":"B3101-1g","price":220.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44024291983576,"sku":"B3101-500mg","price":110.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44024292114648,"sku":"B3101-5g","price":660.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h4qptc-921619-91-2-chemical-structure-title.png?v=1718706710"},{"product_id":"dpybz","title":"1,4-Di(4-pyridyl)benzene","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Dipyridylbenzene Ligand\u003cbr\u003e\n\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of environmental protection and separation of the isomers\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e1,4-Di(4-pyridyl)benzene (DPyBz), CAS number 113682-56-7, has two end 4-pyridine units joined by a benzene ring at 1,4-positions.\u003c\/p\u003e\n\u003cp\u003eHighly porous metal–organic framework Zn\u003csub\u003e2\u003c\/sub\u003e(TCPP)(DPyBz) (H4TCPP = 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine) has permanent porosity with high BET areas 1,324 m\u003csup\u003e2\u003c\/sup\u003e g\u003csup\u003e−1\u003c\/sup\u003e. The Zn\u003csub\u003e2\u003c\/sub\u003e(COO)\u003csub\u003e4\u003c\/sub\u003e paddlewheel units of the metal-organic framework are fitted together by the TCPP\u003csup\u003e4−\u003c\/sup\u003e ligands to form two-dimensional layers and then further connected by DPyBz ligands as pillars to construct a two-fold catenated 3D framework. Zn\u003csub\u003e2\u003c\/sub\u003e(TCPP)(DPyBz) shows selective CO\u003csub\u003e2\u003c\/sub\u003e and light hydrocarbon capture with potential applications for environmental protection.\u003c\/p\u003e\n\u003cp\u003eMetallacycle iridium complex, also bearing 1,4-di(4-pyridyl)benzene, can produce n-hexane with a purity of \u0026gt;99% in a single adsorption–desorption cycle from an equimolar mixture of all five isomers of hexane, taking advantage of these dihydrogen bond interactions (B–H\u003csup\u003eδ−\u003c\/sup\u003e···H\u003csup\u003eδ+\u003c\/sup\u003e–C ) for the separation of the isomers.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e113682-56-7\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e16\u003c\/sub\u003eH\u003csub\u003e12\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1,4-Di(4-pyridyl)benzene\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e232.29 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDPyBz, 4,4'-(1,4-Phenylene)bispyridine\u003cbr\u003e1,4-Di(pyridin-4-yl)benzene\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDipyridylbenzene, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dpb-113682-56-7-chemical-structure-body.png\" target=\"_blank\" title=\"1,4-di(4-pyridyl)benzene chemical structure\"\u003e\u003cimg alt=\"1,4-di(4-pyridyl)benzene chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dpb-113682-56-7-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e1,4-Di(4-pyridyl)benzene (DPyBz) chemical structure, CAS 113682-56-7\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e193 °C\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/dpybz.pdf\" target=\"_blank\" title=\"113682-56-7 - 1,4-di(4-pyridyl)benzene MSDS Sheet\"\u003e\u003cimg alt=\"113682-56-7 - 1,4-di(4-pyridyl)benzene\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e1,4-Di(4-pyridyl)benzene MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eSynthesis and structural characterization of a flexible metal organic framework {[Ni(dpbz)][Ni(CN)4]}n, dpbz = 1,4-bis(4-pyridyl)benzene) with an unusual Ni–N bond,\u003c\/em\u003e W. Wong-Ng et al., Solid State Sci., 52, 1-9 (52); DOI: 10.1016\/j.solidstatesciences.2015.11.010.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eOne-Dimensional Chain-Type Dicopper Coordination Polymer Linked by 1,4-Di(4-pyridyl)benzene; Synthesis, Crystal Structure, Magnetic Property, and Gas-Adsorption Property,\u003c\/em\u003e N. Yano et al., Magnetochem., 4(2), 26 (2018); DOI: 10.3390\/magnetochemistry4020026.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eProton-Assisted Self-Assemblies of Linear Di-Pyridyl Polyaromatic Molecules at Solid\/Liquid Interface,\u003c\/em\u003e H. Li et al., J. Phys. Chem. C, 116 (41), 21753–21761 (2012); DOI: 10.1021\/jp303352h.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eDihydrogen Bond Interaction Induced Separation of Hexane Isomers by Self-Assembled Carborane Metallacycles,\u003c\/em\u003e P. Cui et al., J. Am. Chem. Soc., 142 (18), 8532–8538 (2020); DOI: 10.1021\/jacs.0c03176.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTwo zinc metal–organic framework isomers based on pyrazine tetracarboxylic acid and dipyridinylbenzene for adsorption and separation of CO2 and light hydrocarbons,\u003c\/em\u003e Y. Ye et al., Dalton Trans., 49, 1135-1142 (2020); DOI: 10.1039\/C9DT04305E.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44024943804632,"sku":"B3111-1g","price":140.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44024943837400,"sku":"B3111-5g","price":490.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/dpb-113682-56-7-chemical-structure-title.png?v=1718706710"},{"product_id":"h2tpdc","title":"[p-Terphenyl]-4,4''-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Terphenyl Ligand\u003cbr\u003e\n\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of carbon dioxide storage\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e[\u003cem\u003ep-\u003c\/em\u003eTerphenyl]-4,4''-dicarboxylic acid (H2TPDC) is a linear terphenyl with one carboxylic acid group on each end of the structure at 4,4'-positions.\u003c\/p\u003e\n\u003cp\u003eThermal annealing treatment for the reticular dysprosium (Dy) with rigid molecular ligand linker [\u003cem\u003ep-\u003c\/em\u003eterphenyl]-4,4''-dicarboxylic acid (Dy:H2TPDC) architecture gives rise to an unprecedented quasi-hexagonal nanostructure. The structure is based on dinuclear dysprosium clusters, exhibiting a unique six-fold Dy⋯O bonding motif.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e13653-84-4\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e20\u003c\/sub\u003eH\u003csub\u003e14\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e[\u003cem\u003ep-\u003c\/em\u003eTerphenyl]-4,4''-dicarboxylic acid \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e318.32 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2TPDC, H2TDA, [1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTerphenyl, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003cdiv\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2tpdc-13653-84-4-chemical-structure-title.png?v=1718706710\" target=\"_blank\" title=\"13653-84-4 - [p-terphenyl]-4,4''-dicarboxylic acid chemical structure\"\u003e\u003cimg alt=\"13653-84-4 - [p-Terphenyl]-4,4''-dicarboxylic acid chemical structure\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2tpdc-13653-84-4-chemical-structure-title.png?v=1718706710\u0026amp;width=240\"\u003e\u003c\/a\u003e\u003c\/div\u003e\n\u003cfigcaption\u003e[\u003cem\u003ep-\u003c\/em\u003eTerphenyl]-4,4''-dicarboxylic acid (H2TPDC) Chemical Structure, 13653-84-4\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;97%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2tpdc.pdf\" target=\"_blank\" title=\"13653-84-4 - p-terphenyl-4,4''-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"13653-84-4 - p-terphenyl-4,4''-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e[\u003cem\u003ep-\u003c\/em\u003eterphenyl]-4,4''-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eModulated Synthesis of Zr-Based Metal–Organic Frameworks: From Nano to Single Crystals,\u003c\/em\u003e A. Schaate et al., Chem, Euro. J., 17 (24), 6643-6651 (2011); DOI: 10.1002\/chem.201003211.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDysprosium-carboxylate nanomeshes with tunable cavity size and assembly motif through ionic interactions,\u003c\/em\u003e B. Cirera et al., Chem. Commun., 52, 11227-11230 (2016); DOI: 10.1039\/C6CC04874A.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eEnhanced water stability and high CO2 storage capacity of a Lewis basic sites-containing zirconium metal–organic framework,\u003c\/em\u003e S. Demir et al., Dalton Trans., 50, 16587-16592 (2021); DOI: 10.1039\/D1DT02772G.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eLanthanide metal–organic network featuring strong perpendicular magnetic anisotropy,\u003c\/em\u003e S. Parreiras et al., Nanoscale, 15, 7267-7271 (2023); DOI: 10.1039\/D2NR07189D.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eInterpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption,\u003c\/em\u003e Y. Ju et al., Inorg. Chem., 60 (8), 5617–5626 (2021); DOI: 10.1021\/acs.inorgchem.0c03586.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal–Organic Frameworks,\u003c\/em\u003e I. Kochetygov et al., Angew. Chem. Int. Ed., e202215595 (2023); DOI: 10.1002\/anie.202215595.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"10 g","offer_id":44025183338712,"sku":"B3121-10g","price":350.0,"currency_code":"GBP","in_stock":false},{"title":"1 g","offer_id":44025182748888,"sku":"B3121-1g","price":70.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44025183273176,"sku":"B3121-5g","price":220.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2tpdc-13653-84-4-chemical-structure-title.png?v=1718706710"},{"product_id":"h2tpdc-ome","title":"2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Terphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker with flexible side functional groups for MOFs in applications of carbon dioxide storage and separation of CO\u003csub\u003e2\u003c\/sub\u003e and CH\u003csub\u003e4\u003c\/sub\u003e.\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2′,5′-Dimethoxy-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid (H2TPDC-OMe), a rigid terphenyl ligand with flexible functional groups, can provide various coordination modes and diverse architectures with inorganic metal cluster centers. With three linearly connected phenyl rings, 2′,5′-dimethoxy-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid is also capable of showing photoluminescence.\u003c\/p\u003e\n\u003cp\u003ePorous MOF [Cd(L)(OBA)]·DMF·H\u003csub\u003e2\u003c\/sub\u003eO, where L is H2TPDC-OMe, shows high adsorption for CO\u003csub\u003e2\u003c\/sub\u003e with an uptake of 26.75 cm\u003csup\u003e3\u003c\/sup\u003e\/g at 295 K. {[Cd(L)(OBA)]·DMF·H2O}\u003csub\u003en\u003c\/sub\u003e also demonstrates great potential for selective separation of CO\u003csub\u003e2\u003c\/sub\u003e and CH\u003csub\u003e4\u003c\/sub\u003e, due to the different interaction mechanism between the gases and the open metal sites.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1392416-19-1\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e22\u003c\/sub\u003eH\u003csub\u003e18\u003c\/sub\u003eO\u003csub\u003e6\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e378.37 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2TPDC-OMe\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTerphenyl, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tpdc-ome2-1392416-19-1-chemical-structure-body.png\" target=\"_blank\" title=\"2',5'-dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid chemical structure\"\u003e\u003cimg alt=\"2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tpdc-ome2-1392416-19-1-chemical-structure-title.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid (H2TPDC-OMe) chemical structure, CAS 1392416-19-1\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2tpdc-ome.pdf\" target=\"_blank\" title=\"1392416-19-1 - 2',5'-dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"1392416-19-1 - 2',5'-dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eModulated Synthesis of Zr-Based Metal–Organic Frameworks: From Nano to Single Crystals,\u003c\/em\u003e A. Schaate et al., Chem, Euro. J., 17 (24), 6643-6651 (2011); DOI: 10.1002\/chem.201003211.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDysprosium-carboxylate nanomeshes with tunable cavity size and assembly motif through ionic interactions,\u003c\/em\u003e B. Cirera et al., Chem. Commun., 52, 11227-11230 (2016); DOI: 10.1039\/C6CC04874A.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eEnhanced water stability and high CO2 storage capacity of a Lewis basic sites-containing zirconium metal–organic framework,\u003c\/em\u003e S. Demir et al., Dalton Trans., 50, 16587-16592 (2021); DOI: 10.1039\/D1DT02772G.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eLanthanide metal–organic network featuring strong perpendicular magnetic anisotropy,\u003c\/em\u003e S. Parreiras et al., Nanoscale, 15, 7267-7271 (2023); DOI: 10.1039\/D2NR07189D.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eInterpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption,\u003c\/em\u003e Y. Ju et al., Inorg. Chem., 60 (8), 5617–5626 (2021); DOI: 10.1021\/acs.inorgchem.0c03586.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal–Organic Frameworks,\u003c\/em\u003e I. Kochetygov et al., Angew. Chem. Int. Ed., e202215595 (2023); DOI: 10.1002\/anie.202215595.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44025267716312,"sku":"B3131-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44025267650776,"sku":"B3131-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44025267781848,"sku":"B3131-5g","price":750.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/tpdc-ome2-1392416-19-1-chemical-structure-title.png?v=1718706710"},{"product_id":"hpbpc","title":"4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Biphenylpyridine Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of methane storage\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4'-(Pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid (HPBPC), CAS number 1393711-96-0, has a rigid linear structure of biphenylpyridine with a carboxylic acid at the end of benzene rings.\u003c\/p\u003e\n\u003cp\u003eMOF NiL2 (L=4-(4-pyridyl)-biphenyl-4-carboxylic acid), shows a dynamic feature of diamondoid topology switches between closed non-porous and several open porous phases at specific CO\u003csub\u003e2\u003c\/sub\u003e and CH\u003csub\u003e4\u003c\/sub\u003e pressures. Metal doping of the MOF with cobalt ions enables control over the gate opening between non-porous and porous phases. By adjusting the ratio of Ni\/Co, methane-induced phase transformations can be fine-tuned to enhance methane working capacity. The optimal working capacity from 5 to 35 bar at 298 K (153 cm\u003csup\u003e3\u003c\/sup\u003e cm\u003csup\u003e−3\u003c\/sup\u003e) was found for Ni\u003csub\u003e0.89\u003c\/sub\u003eCo\u003csub\u003e0.11\u003c\/sub\u003eL\u003csub\u003e2\u003c\/sub\u003e (X-dia-1- Ni\u003csub\u003e0.89\u003c\/sub\u003eCo\u003csub\u003e0.11\u003c\/sub\u003e), which is greater than that of benchmark rigid MOFs.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1393711-96-0\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e18\u003c\/sub\u003eH\u003csub\u003e13\u003c\/sub\u003eNO\u003csub\u003e2\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e275.30 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eHPBPC, 4-PBP, 4-(4-pyridyl)-biphenyl-4-carboxylic acid, 4-(pyridine-4-yl)phenylbenzoate\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBiphenylpyridine MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/hpbpc-1393711-96-0-chemical-structure-body.png\" target=\"_blank\" title=\"HPBPC chemical structure\"\u003e\u003cimg alt=\"HPBPC chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/hpbpc-1393711-96-0-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid chemical structure, CAS 1393711-96-0\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/hpbpc.pdf\" target=\"_blank\" title=\"1393711-96-0 - 4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"1393711-96-0 - 4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e4'-(Pyridin-4-yl)-[1,1'-biphenyl]-4-carboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eWindmill Co4{Co4(μ4-O)} with 16 Divergent Branches Forming a Family of Metal–Organic Frameworks: Organic Metrics Control Topology, Gas Sorption, and Magnetism,\u003c\/em\u003e Q. Chen et al., Chem. Eur. J., 22 (34), 12088-12094 (2016); DOI: 10.1002\/chem.201601826.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eReversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate-Opening at Methane Storage Pressures,\u003c\/em\u003e Q. Yang et al., Angew. Chem., Int. Ed., 57 (20), 5684-5689 (2018); DOI: 10.1002\/anie.201800820.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eRegulation of the Degree of Interpenetration in Metal–Organic Frameworks,\u003c\/em\u003e G. Verma et al., Top Curr Chem (Z) 378, 4 (2020); DOI: 10.1007\/s41061-019-0268-x.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eMetal Doping to Control Gate Opening and Increase Methane Working Capacity in Isostructural Flexible Diamondoid Networks,\u003c\/em\u003e S. Wang et al., ChemSusChem, 16 (9), e202300069 (2023); DOI: 10.1002\/cssc.202300069.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44029873225944,"sku":"B3141-1g","price":310.0,"currency_code":"GBP","in_stock":true},{"title":"250 mg","offer_id":44029872865496,"sku":"B3141-250mg","price":120.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44029873193176,"sku":"B3141-500mg","price":190.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44029873258712,"sku":"B3141-5g","price":930.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/hpbpc-1393711-96-0-chemical-structure-title.png?v=1718706710"},{"product_id":"h2bpdc-nh2","title":"2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Biphenyl Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid ligand linker for MOFs in applications of catalysts in cross coupling reactions\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid is a biphenyl backboned ligand with carboxylic acid groups at the end 4,4'-positions and an amino group at 2-position of the biphenyl rings.\u003c\/p\u003e\n\u003cp\u003eZirconium-Based MOFs (UiO-67-Mix) with different ratio of 4,4′-biphenyldicarboxylic acid\/2-amino-biphenyl-4,4′-dicarboxylic acid rigid ligand linkers incorporated into their structure and Pd metal centers anchored onto the MOF as pendant, shows great efficiency as catalyst in Suzuki and Heck cross-coupling reactions with a very low Pd loading (0.054 mol %). The porous catalyst can be readily recovered and recycled in at least 10 cycles without significant leaching or loss of catalytic activity.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1240557-01-0\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e14\u003c\/sub\u003eH\u003csub\u003e11\u003c\/sub\u003eNO\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e257.24 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2BPDC-NH2\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBiphenyl, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2bpdc-nh2-1240557-01-0-chemical-struture-body.png\" target=\"_blank\" title=\"2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid chemical structure\"\u003e\u003cimg alt=\"2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2bpdc-nh2-1240557-01-0-chemical-struture-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid (H2BPDC) chemical structure, CAS 1240557-01-0\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003ePale yellow powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2bpdc-nh2.pdf\" target=\"_blank\" title=\"1240557-01-0 - 2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid MSDS Sheet\"\u003e\u003cimg alt=\"1240557-01-0 - 2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eThermolabile Groups in Metal–Organic Frameworks: Suppression of Network Interpenetration, Post-Synthetic Cavity Expansion, and Protection of Reactive Functional Groups,\u003c\/em\u003e R. Deshpande et al., Angew. Chem., 49 (27), 4598-4602 (2010); DOI: 10.1002\/anie.200905960.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMetal–organic frameworks post-synthetically modified with ferrocenyl groups: framework effects on redox processes and surface conduction,\u003c\/em\u003e Dalton Trans., 41, 1475-1480 (2012); DOI: 10.1039\/C1DT10734H.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eInterpenetration isomers in isoreticular amine-tagged zinc MOFs,\u003c\/em\u003e A. Khansari et al., CrystEngComm, 21, 7498-7506 (2019); DOI: 10.1039\/C9CE01669D.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eTuning the Lewis acidity of metal–organic frameworks for enhanced catalysis,\u003c\/em\u003e Dalton Trans., 50, 3116-3120 (2021); DOI: 10.1039\/D1DT00180A.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eZirconium Materials from Mixed Dicarboxylate Linkers: Enhancing the Stability for Catalytic Applications,\u003c\/em\u003e A. Rasero-Almansa et al., ChemCatChem, 6 (12), 3426-3433 (2012); DOI: 10.1002\/cctc.201402546.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003ePalladium(II)@Zirconium-Based Mixed-Linker Metal–Organic Frameworks as Highly Efficient and Recyclable Catalysts for Suzuki and Heck Cross-Coupling Reactions,\u003c\/em\u003e R. Sun et al., ChemCatChem, 8 (20), 3261-3271 (2016); DOI: 10.1002\/cctc.201600774.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eOrthogonal Ternary Functionalization of a Mesoporous Metal–Organic Framework via Sequential Postsynthetic Ligand Exchange,\u003c\/em\u003e C. Liu et al., J. Am. Chem. Soc., 137 (33), 10508–10511 (2015); DOI: 10.1021\/jacs.5b06780.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eBridging the interfacial gap in mixed-matrix membranes by nature-inspired design: precise molecular sieving with polymer-grafted metal–organic frameworks,\u003c\/em\u003e L. Cseri et al., J. Mater. Chem. A, 9, 23793-23801 (2021); DOI: 10.1039\/D1TA06205K.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"10 g","offer_id":44030076125400,"sku":"B3151-10g","price":700.0,"currency_code":"GBP","in_stock":true},{"title":"1 g","offer_id":44030075994328,"sku":"B3151-1g","price":110.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44030076092632,"sku":"B3151-5g","price":420.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2bpdc-nh2-1240557-01-0-chemical-struture-title.png?v=1718706710"},{"product_id":"h2edb","title":"4,4'-(Ethyne-1,2-diyl)dibenzoic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Biphenylethyne Ligand\u003cbr\u003e\n\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid ligand linker for MOFs in applications of hydrogen storage and oxygen sensing\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4,4'-(Ethyne-1,2-diyl)dibenzoic acid, CAS number 16819-43-5, is rigid biphenylethyne with carboxylic acids at both end of the benzene rings.\u003c\/p\u003e\n\u003cp\u003eStable up to 400 °C, Zr(IV)-based highly porous MOF, [Zr\u003csub\u003e6\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e(OH)\u003csub\u003e4\u003c\/sub\u003e(L)\u003csub\u003e6\u003c\/sub\u003e] (BUT-30, H2L = 4,4′-(ethyne-1,2-diyl)dibenzoic acid), has a BET surface area as high as 3,940.6 m\u003csup\u003e2\u003c\/sup\u003eg\u003csup\u003e−1\u003c\/sup\u003e and total pore volume of 1.55 cm\u003csup\u003e3\u003c\/sup\u003e g\u003csup\u003e−1\u003c\/sup\u003e. Fcu-type framework [Zr\u003csub\u003e6\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e(OH)\u003csub\u003e4\u003c\/sub\u003e(L)\u003csub\u003e6\u003c\/sub\u003e], an expanded version of UiO-66, exhibits not only large negative thermal expansion, but also notable oxygen sensing properties.\u003c\/p\u003e\n\u003cp\u003eMOF, named GUF-1, where one-dimensional Sc(μ2-OH) chains are connected by 4,4′-(ethyne-1,2-diyl)dibenzoic acid ligand linkers, shows a moderately high adsorption for H\u003csub\u003e2\u003c\/sub\u003e of 7.6 kJ\/mol and a working capacity of 41 g\/L in a temperature–pressure swing system.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e16819-43-5\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e16\u003c\/sub\u003e\u003cspan\u003eH\u003c\/span\u003e\u003csub\u003e10\u003c\/sub\u003e\u003cspan\u003eO\u003c\/span\u003e\u003csub\u003e4\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,4'-(Ethyne-1,2-diyl)dibenzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e266.25 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,4'-(1,2-Ethynediyl)dibenzoic acid, H2EDDB, H2EDBA\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cspan\u003eBiphenylethyne,\u003c\/span\u003e MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2edb-16819-43-5-chemical-sructure-body.png\" target=\"_blank\" title=\"H2BPDC chemical structure\"\u003e\u003cimg alt=\"H2BPDC chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2edb-16819-43-5-chemical-sructure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2-Amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid chemical structure, CAS 1240557-01-0\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h2edb.pdf\" target=\"_blank\" title=\"16819-43-5 - 4,4'-(ethyne-1,2-diyl)dibenzoic acid MSDS Sheet\"\u003e\u003cimg alt=\"16819-43-5 - 4,4'-(ethyne-1,2-diyl)dibenzoic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e4,4'-(Ethyne-1,2-diyl)dibenzoic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eAdsorption of iodine in metal–organic framework materials,\u003c\/em\u003e X. Zhang et al., Chem. Soc. Rev., 51, 3243-3262 (2022); DOI: 10.1039\/D0CS01192D.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake,\u003c\/em\u003e X. Lv et al., J. Solid State Chem., 223, 104-108 (2015); DOI: 10.1016\/j.jssc.2014.07.001.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSurface-Specific Functionalization of Nanoscale Metal–Organic Frameworks,\u003c\/em\u003e S. Wang et al., Angew. Chem., 54 (49), 14738-14742 (2015); DOI: 10.1002\/anie.201506888.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eOne dimensional infinite water wires incorporated in isostructural organic crystalline supermolecules with zwitterionic channels,\u003c\/em\u003e Z. Yu et al., CrystEngComm, 13, 1287-1290 (2011); DOI: 10.1039\/C0CE00659A.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eThermal and Gas Dual-Responsive Behaviors of an Expanded UiO-66-Type Porous Coordination Polymer,\u003c\/em\u003e H. Zhou et al., ChemPlusChem, 81 (8), 817-821 (2016); DOI: 10.1002\/cplu.201600145.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eModulated self-assembly of an interpenetrated MIL-53 Sc metal-organic framework with excellent volumetric H2 storage and working capacity,\u003c\/em\u003e Mater. Today Chem., 24, 100887 (2022); DOI: 10.1016\/j.mtchem.2022.100887.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44030416552152,"sku":"B3161-1g","price":350.0,"currency_code":"GBP","in_stock":true},{"title":"250 mg","offer_id":44030416421080,"sku":"B3161-250mg","price":140.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44030416519384,"sku":"B3161-500mg","price":220.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2edb-16819-43-5-chemical-sructure-title.png?v=1718706710"},{"product_id":"h4pydip","title":"5,5’-(Pyridine-3,5-diyl)diisophthalic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Biphenylpyridine Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid bridging ligand linker for MOFs in applications of iron detection and selective adsorption of carbon dioxide\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e5,5′-(Pyridine-3,5-diyl)diisophthalic acid (H4PyDIP), CAS number 1433029-60-7, is a rigid bridging-type tetracarboxylic acid molecule containing two isophthalic acid moieties and one pyridine spacer.\u003c\/p\u003e\n\u003cp\u003eLn-metal–organic framework (Ln-MOF) materials [(CH\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e2\u003c\/sub\u003eNH\u003csub\u003e2\u003c\/sub\u003e]\u003csub\u003e2\u003c\/sub\u003e[Ln\u003csub\u003e2\u003c\/sub\u003e(L)\u003csub\u003e2\u003c\/sub\u003e(H\u003csub\u003e2\u003c\/sub\u003eO)\u003csub\u003e2\u003c\/sub\u003e]·2DMF·2H\u003csub\u003e2\u003c\/sub\u003eO (H4L = H4PyDIP) can not only selectively detect polychlorinated benzenes, but also highly sensitively detect the Fe\u003csup\u003e3+\u003c\/sup\u003e ion (K\u003csub\u003eSV\u003c\/sub\u003e = 7.58 × 10\u003csup\u003e4\u003c\/sup\u003e M\u003csup\u003e–1\u003c\/sup\u003e).\u003c\/p\u003e\n\u003cp\u003eZn(II) metal–organic framework (MOF) [Me\u003csub\u003e2\u003c\/sub\u003eNH\u003csub\u003e2\u003c\/sub\u003e][Zn\u003csub\u003e2\u003c\/sub\u003e(PyDIP)(HTZ)]·4DMF (HTZ = 1H-tetrazole) contains two shapes of 1D open channels with suitable pore sizes, high porosity, and a highly polar pore system decorated with uncoordinated N atoms and carboxylic O atoms, providing a good environment for selective adsorption of CO\u003csub\u003e2\u003c\/sub\u003e.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1433029-60-7\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e21\u003c\/sub\u003eH\u003csub\u003e13\u003c\/sub\u003eNO\u003csub\u003e8\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e5,5’-(Pyridine-3,5-diyl)diisophthalic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e407.33 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e3,5-bis(3,5-dicarboxylphenyl)pyridine, H4PyDIP, H4PDDA, H4BDPP\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBiphenylpyridine, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4pydip-1433029-60-7-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"H4PyDIP chemical structure\"\u003e\u003cimg alt=\"H4PyDIP chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h4pydip-1433029-60-7-chemical-structure-title.png?height=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e5,5’-(Pyridine-3,5-diyl)diisophthalic acid chemical structure, CAS 1433029-60-7\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h4pydip.pdf\" target=\"_blank\" title=\"1433029-60-7 - 5,5’-(pyridine-3,5-diyl)diisophthalic acid MSDS Sheet\"\u003e\u003cimg alt=\"1433029-60-7 - 5,5’-(pyridine-3,5-diyl)diisophthalic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e5,5’-(Pyridine-3,5-diyl)diisophthalic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eWhite-Light-Emitting Materials and Highly Sensitive Detection of Fe3+ and Polychlorinated Benzenes Based on Ln-Metal–Organic Frameworks,\u003c\/em\u003e J. Huang et al., Cryst. Growth Des., 18 (9), 5353–5364 (2018); DOI: 10.1021\/acs.cgd.8b00773.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eIsostructural Metal–Organic Frameworks Assembled from Functionalized Diisophthalate Ligands through a Ligand-Truncation Strategy,\u003c\/em\u003e Y. Liu et al., Chem. Eur. J. 19 (18), 5637-5643 (2013); DOI: 10.1002\/chem.201203297.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eFunctionalization of MOFs via a mixed-ligand strategy: enhanced CO2 uptake by pore surface modification,\u003c\/em\u003e B. Liu et al., Dalton Trans., 47, 5298-5303 (2018); DOI: 10.1039\/C8DT00502H.\u003c\/li\u003e\n\u003c\/ol\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44030673092824,"sku":"B3171-1g","price":350.0,"currency_code":"GBP","in_stock":true},{"title":"250 mg","offer_id":44030673027288,"sku":"B3171-250mg","price":140.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44030673060056,"sku":"B3171-500mg","price":220.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h4pydip-1433029-60-7-chemical-structure-title.png?v=1718706710"},{"product_id":"h2btdb","title":"4,4'-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Benzo[c][1,2,5]thiadiazole Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of Al\u003csup\u003e3+\u003c\/sup\u003e and Ga\u003csup\u003e3+\u003c\/sup\u003e ions and L-histidine (His) detection, CAS No. 1581774-76-6\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4,4'-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid (H2BTDB), CAS number 1581774-76-6, has a benzo[c][1,2,5]thiadiazole core with 4- benzoic acid at 4,7-positions.\u003c\/p\u003e\n\u003cp\u003eFluorescent Eu-MOF with Eu\u003csup\u003e3+\u003c\/sup\u003e ions as metal nodes and electron-deficient, thiadiazole-functionalized ligand H2BTDB as organic linkers is developed for dual-target detection. Sensitive detection of both ethylamine and gossypol was achieved with a detection limit of 1.30 μm and 4.32 μm, respectively, thanks to the large pore structure of the MOF.\u003c\/p\u003e\n\u003cp\u003eTwo-fold interpenetrated metal–organic framework (MOF), {[Cd\u003csub\u003e2\u003c\/sub\u003e(BTDB)\u003csub\u003e2\u003c\/sub\u003e(4,4-bpy)]·DMF}\u003csub\u003en\u003c\/sub\u003e (4,4-bpy = 4,4-bipyridine), JXUST-14, is a highly selective and sensitive luminescent sensor for \u003cem\u003eL-\u003c\/em\u003ehistidine (His) with a detection limit of 11.1 ppm. JXUST-14 is the first Cd(II)-based MOF for the detection of His via turn-on and fluorescence blue-shift effects. Eu-MOF {[(CH\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e2\u003c\/sub\u003eNH\u003csub\u003e2\u003c\/sub\u003e][Eu(BTDB)\u003csub\u003e2\u003c\/sub\u003e]·2H\u003csub\u003e2\u003c\/sub\u003eO}\u003csub\u003en\u003c\/sub\u003e (JXUST-11) exhibits a chain-based three-dimensional framework. Moreover, JXUST-11 is considered as a photoluminescent sensor to identify Al\u003csup\u003e3+\u003c\/sup\u003e and Ga\u003csup\u003e3+\u003c\/sup\u003e ions by fluorescence enhancement with the detection limits of 2.9 and 10.2 ppm, respectively.\u003c\/p\u003e\n\u003cp\u003eLuminescent Zr-based MOF having a UiO-68 framework topology and incorporating the π-conjugated H2BTDB ligand showed a selective sensing behavior towards 2,4,6-trinitrophenol (TNP) even in the presence of other potentially competing nitroaromatic explosive compounds. The detection limit of TNP in methanol suspension was found to be 1.63 ppm. This great fluorescence quenching ability of TNP can be attributed to both energy and electron transfer processes as well as electrostatic interactions between the hydroxyl group of TNP and the Lewis basic N-donor sites of the H2BTDB ligand.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1581774-76-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e20\u003c\/sub\u003eH\u003csub\u003e12\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003eS\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4,4'-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e376.39 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eH2BTDB, H2-TTPDC, 4,4'-(benzothiadiazole-4,7-diyl)dibenzoate\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBenzo[c][1,2,5]thiadiazole , MOF ligands,\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca title=\"Chemical structure of 4,4'-(benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid\" href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2btdb-1581774-76-6-chemical-structure-body.png\" target=\"_blank\"\u003e\u003cimg width=\"320\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h2btdb-1581774-76-6-chemical-structure-body.png?height=240\" loading=\"lazy\" height=\"240\" alt=\"Chemical structure of 4,4'-(benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eChemical structure of 4,4'-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid, CAS No: 1581774-76-6\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eYellow powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca title=\"1581774-76-6 - 4,4'-(benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid MSDS Sheet\" href=\"https:\/\/downloads.ossila.com\/msds\/h2btdb.pdf\" target=\"_blank\"\u003e\u003cimg width=\"30\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" loading=\"lazy\" height=\"39\" class=\"msds-icon\" alt=\"1581774-76-6 - 4,4'-(benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid\"\u003e4,4'-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eThiadiazole-functionalized metal-organic frameworks multifunction-architectonics for dual-target sensing of ethylamine and gossypol,\u003c\/em\u003e Y. Wang et al., Chem. Eng. J., 441, 136049 (2022); DOI: 10.1016\/j.cej.2022.136049.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eBenzo-2,1,3-thiadiazole-based, highly dichroic fluorescent dyes for fluorescent host–guest liquid crystal displays,\u003c\/em\u003e X. Zhang et al., J. Mater. Chem., 14, 1901-1904 (2004); DOI: 10.1039\/B402645D.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTurn-on and blue-shift fluorescence sensor toward l-histidine based on stable CdII metal–organic framework with tetranuclear cluster units,\u003c\/em\u003e J. Li et al., Dalton Trans., 51, 5983-5988 (2022); DOI: 10.1039\/D2DT00390B.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv id=\"literature-and-reviews\" class=\"expandable\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eA thiadiazole-functionalized ZrIJIV)-based metal–organic framework as a highly fluorescent probe for the selective detection of picric acid,\u003c\/em\u003e S. Mostakim et al., CrystEngComm, 18, 3104 (2016); DOI: 10.1039\/c6ce00421k.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eEnhanced luminescence in multivariate metal–organic frameworks through an isolated-ligand strategy,\u003c\/em\u003e Z. Jiang et al., J. Mater. Chem. C, 10, 10473-10479 (2022); DOI: 10.1039\/D2TC01949C.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA Benzothiadiazole-Based Eu3+ Metal–Organic Framework as the Turn-On Luminescent Sensor toward Al3+ and Ga3+ with Potential Bioimaging Application,\u003c\/em\u003e J. Li et al., Inorg. Chem., 61 (8), 3607–3615 (2022); DOI: 10.1021\/acs.inorgchem.1c03661.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton type=\"button\" data-toggle-text=\"Hide Literature and Reviews\" data-expand-target=\"literature-and-reviews\" class=\"anchor expand-link\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e","brand":"Ossila","offers":[{"title":"1 g","offer_id":44039802749144,"sku":"B3181-1g","price":160.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44039802912984,"sku":"B3181-5g","price":540.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h2btdb-1581774-76-6-chemical-structure-title.png?v=1718706709"},{"product_id":"dpyn","title":"2,6-Di(pyridin-4-yl)naphthalene","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Dipyridylnaphthalene Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA rigid linear ligand linker for MOFs in applications of catalysts and pure white LEDs.\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e2,6-Di(pyridin-4-yl)naphthalene (DPyN) has a naphthalene with two 4-pyridyl groups at 2,6-positions.\u003c\/p\u003e\n\u003cp\u003e2,6-Di(pyridin-4-yl)naphthalene is synthesized by reacting 2,6-dibromonaphthalene with 4-pyridylboronic acid via Suzuki coupling reaction using tetrakis(triphenylphosphine)palladium as the catalyst.\u003c\/p\u003e\n\u003cp\u003eWhite-light-emitting systems in water at the single-molecule scale utilizing 2,6-di(pyridin-4-yl)naphthalene core and coumarin pedant groups with natural self-folded conformation can be realized. This particular folding behavior could enhance the ICT efficiency and lead to pure white-light emission.\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e950520-39-5\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e20\u003c\/sub\u003eH\u003csub\u003e14\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e2,6-Di(pyridin-4-yl)naphthalene\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e282.34 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDPyN, 2,6-bis(pyridin-4-yl)naphthalene\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eDipyridylnaphthalene, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dpyn-950520-39-5-chemical-structure-body.png\" target=\"_blank\" title=\"2,6-di(pyridin-4-yl)naphthalene chemical structure\"\u003e\u003cimg alt=\"2,6-di(pyridin-4-yl)naphthalene chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/dpyn-950520-39-5-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e2,6-Di(pyridin-4-yl)naphthalene (DPyN) chemical structure, CAS 950520-39-5\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eN\/A\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOff white powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/dpyn.pdf\" target=\"_blank\" title=\"950520-39-5 - 2,6-di(pyridin-4-yl)naphthalene MSDS Sheet\"\u003e\u003cimg alt=\"950520-39-5 - 2,6-di(pyridin-4-yl)naphthalene\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e2,6-Di(pyridin-4-yl)naphthalene MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eLiquid-Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site-Isolation of Catalytic Centers,\u003c\/em\u003e M. Beyzavi et al., ChemPlusChem, 81 (8), 708-713 (2016); DOI: 10.1002\/cplu.201600046.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eRational Design and Construction of Hierarchical Superstructures Using Shape-Persistent Organic Cages: Porphyrin Box-Based Metallosupramolecular Assemblies,\u003c\/em\u003e Y. Kim et al., J. Am. Chem. Soc., 140 (44), 14547–14551 (2018); DOI: 10.1021\/jacs.8b08030.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eOpening Metal–Organic Frameworks Vol. 2: Inserting Longer Pillars into Pillared-Paddlewheel Structures through Solvent-Assisted Linker Exchange,\u003c\/em\u003e O. Karagiaridi et al., Chem. Mater., 25 (17), 3499–3503 (2013); DOI: 10.1021\/cm401724v.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eMolecular tectonics: control of interpenetration in cuboid 3-D coordination networks,\u003c\/em\u003e M. Lin et al., CrystEngComm, 13, 776-778 (2011); DOI: 10.1039\/C0CE00777C.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eWhite-Light Emission from a Single Organic Compound with Unique Self-Folded Conformation and Multistimuli Responsiveness,\u003c\/em\u003e D. Li et al., Chem. Sci., 9, 5709 (2018); DOI: 10.1039\/c8sc01915k.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44040166473944,"sku":"B3191-1g","price":320.0,"currency_code":"GBP","in_stock":true},{"title":"250 mg","offer_id":44040166015192,"sku":"B3191-250mg","price":120.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44040166441176,"sku":"B3191-500mg","price":200.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44040166506712,"sku":"B3191-5g","price":990.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/dpyn-950520-39-5-chemical-structure-title.png?v=1718706710"},{"product_id":"h6nbpd","title":"4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid))","description":"\u003ch2 id=\"product-oneliner\"\u003eMetal Organic Frameworks (MOFs) Triarylamine Ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eA trigonal bridging ligand linker for MOFs in applications of CH\u003csub\u003e4\u003c\/sub\u003e storage and separation of C\u003csub\u003e2\u003c\/sub\u003eH\u003csub\u003e6\u003c\/sub\u003e\/C\u003csub\u003e2\u003c\/sub\u003eH\u003csub\u003e4\u003c\/sub\u003e.\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid)) (H6NBPD), CAS number 1347748-59-7, has a triphenylamine core center with benzene-3,5-dicarboxylic acid anchoring groups attached to the 4-positions of the phenyl rings, the each end of triphenylamine core.\u003c\/p\u003e\n\u003cp\u003eMetal–organic framework MFM-115a with copper node centers and 4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid)) as the ligand linkers, displays an exceptionally high deliverable CH\u003csub\u003e4\u003c\/sub\u003e capacity of 208 v\/v between 5 and 80 bar at room temperature, making it among the best performing MOFs for CH\u003csub\u003e4\u003c\/sub\u003e storage.\u003c\/p\u003e\n\u003cp\u003eUpon heating, an in situ solid phase transformation can be observed from hydrogen-bonded organic framework HOF-NBPD(DMA) (NBPD = H6NBPD, DMA=dimethylamine cation) to HOF-NBPD, accompanied with transformation of the electronegative skeleton into neutral one. As a result, the pore surface of HOF-NBPD has become nonpolar. Practical breakthrough experiments demonstrate HOF- NBPD could produce polymer-grade C\u003csub\u003e2\u003c\/sub\u003eH\u003csub\u003e4\u003c\/sub\u003e from C\u003csub\u003e2\u003c\/sub\u003eH\u003csub\u003e6\u003c\/sub\u003e\/C\u003csub\u003e2\u003c\/sub\u003eH\u003csub\u003e4\u003c\/sub\u003e (1\/99, v\/v) mixture with a high productivity of 29.2 L kg\u003csup\u003e−1\u003c\/sup\u003e at 298 K, which is about five times as high as HOF- NBPD (DMA) (5.4 L kg\u003csup\u003e−1\u003c\/sup\u003e).\u003c\/p\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1347748-59-7\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e42\u003c\/sub\u003eH\u003csub\u003e27\u003c\/sub\u003eNO\u003csub\u003e1\u003c\/sub\u003e\u003csub\u003e2\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid))\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e737.68 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4′,4″,4‴-nitrilotribiphenyl-3,5-dicarboxylic acid, H6NBPD, H6NBDA, H6NTBD\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTriarylamine, MOF ligands, \u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h6nbpd-1347748-59-7-chemical-structure-body.png\" target=\"_blank\" title=\"H6NBPD chemical structure\"\u003e\u003cimg alt=\"H6NBPD chemical structure\" height=\"240\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/h6nbpd-1347748-59-7-chemical-structure-body.png?height=240\" width=\"320\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid)) chemical structure, CAS 1347748-59-7\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\u0026gt;97%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003en.a.\u003cbr\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBeige powder\/crystal\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/h6nbpd.pdf\" target=\"_blank\" title=\"1347748-59-7 - 4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid)) MSDS Sheet\"\u003e\u003cimg alt=\"1347748-59-7 - 4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid))\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e4',4''',4'''''-Nitrilotris(([1,1'-biphenyl]-3,5-dicarboxylic acid)) MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003ePorous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage,\u003c\/em\u003e Y. Yan et al., J. Am. Chem. Soc., 139 (38), 13349–13360 (2017); DOI: 10.1021\/jacs.7b05453.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eFunctional metal–organic frameworks constructed from triphenylamine-based polycarboxylate ligands,\u003c\/em\u003e Y. He et al., Coord. Chem. Rev., 420 (213354 (2020); DOI: 10.1016\/j.ccr.2020.213354.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTuning Pore Polarization to Boost Ethane\/Ethylene Separation Performance in Hydrogen-Bonded Organic Frameworks,\u003c\/em\u003e Y. Zhou et al., Angew. Chem., 62 (25), e202305041 (2023); DOI: 10.1002\/anie.202305041.\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eModifying Cage Structures in Metal–Organic Polyhedral Frameworks for H2 Storage,\u003c\/em\u003e Y. Yan et al., Chem. Eur. J. 17 (40), 11162-11170 (2011); DOI: 10.1002\/chem.201101341.\u003cbr\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eA dye-loaded nonlinear metal-organic framework as self-calibrated optical thermometer,\u003c\/em\u003e Dyes Pigm., 202, 110234 (2022); DOI: 10.1016\/j.dyepig.2022.110234.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\n","brand":"Ossila","offers":[{"title":"250 mg","offer_id":44040286470360,"sku":"B3201-250mg","price":100.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44040286830808,"sku":"B3201-500mg","price":160.0,"currency_code":"GBP","in_stock":true},{"title":"1 g","offer_id":44040286863576,"sku":"B3201-1g","price":250.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44040286896344,"sku":"B3201-5g","price":750.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/h6nbpd-1347748-59-7-chemical-structure-title.png?v=1718706710"},{"product_id":"tris4-ethynylphenylamine","title":"Tris(4-ethynylphenyl)amine","description":"\u003ch2 id=\"product-oneliner\"\u003eCovalent organic frameworks (COFs) triethynylphenyl amine ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003efor the synthesis of COFs and MOFs for the applications in porous materials, AIEs and dyes\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eTris(4-ethynylphenyl)amine (CAS number 189178-09-4), is a tertiary amine with three 4-ethynlphenyl groups. Tris(4-ethynylphenyl)amine can undergo various reactions for synthesizing COFs, including the Sonogashira reaction and click polymerization. By reacting tris(4-ethynylphenyl)amine with tetrakis(bromophenyl)ethene using the Sonogashira reaction, an aggregation-induced emission (AIE) COF material can be produced. The resulting COF exhibits an efficiency of electrochemiluminescence of 1.72%. Tris(4-ethynylphenyl)amine can also react with ferrocene diazides for polytriazoles \u003cem\u003evia\u003c\/em\u003e azide-alkyne cycloaddition (click reaction). These hyperbranched polytriazoles act as precursors for nanostructured magnetoceramics.\u003c\/p\u003e\n\u003cp\u003eTris(4-ethynylphenyl)amine also engages in a reaction with ruthenium (Ru), resulting in the formation of a Ru-acetylide MOF. The product has multistep reversible redox behavior.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Facile reactions\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Lab_Proof.svg?v=1697623210\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eFacile reactions\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eReadily for click reaction and Sonogashira reaction\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High Purity 189178-09-4\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh Purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;98% Purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Worldwide shipping for 189178-09-4\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"MOF and COF ligands\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg?v=1698833718\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eMOF and COF ligands\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eEthyne ligand for cross-linked COF networks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e189178-09-4\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e24\u003c\/sub\u003eH\u003csub\u003e15\u003c\/sub\u003eN\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e4-Ethynyl-\u003cem\u003eN\u003c\/em\u003e,\u003cem\u003eN\u003c\/em\u003e-bis(4-ethynylphenyl)aniline\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e317.38 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTEPA, \u003cem\u003eN\u003c\/em\u003e,\u003cem\u003eN\u003c\/em\u003e,\u003cem\u003eN\u003c\/em\u003e-tris(4-ethynylphenyl)amine, 4-Ethynyl-\u003cem\u003eN\u003c\/em\u003e,\u003cem\u003eN\u003c\/em\u003e-bis(4-ethynylphenyl)benzenamine\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eTriphenylamine ligands, Alkynyl ligands, AIEs, COFs, MOFs, Macromolecules, Dyes\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tris4-ethynylphenylamine-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"Tris(4-ethynylphenyl)amine chemical structure, CAS 189178-09-4.\"\u003e\u003cimg alt=\"Tris(4-ethynylphenyl)amine chemical structure, CAS 189178-09-4.\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/tris4-ethynylphenylamine-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eTris(4-ethynylphenyl)amine chemical structure, CAS 189178-09-4\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e\n\u003cem\u003eT\u003csub data-mce-fragment=\"1\"\u003em\u003c\/sub\u003e\u003c\/em\u003e = 115 °C\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eOrange to brown powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/tris4-ethynylphenylamine.pdf\" target=\"_blank\" title=\"Tris(4-ethynylphenyl)amine MSDS Sheet\"\u003e\u003cimg alt=\"Tris(4-ethynylphenyl)amine\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003eTris(4-ethynylphenyl)amine MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eTetraphenylenthene-based conjugated microporous polymer for aggregation-induced electrochemiluminescence\u003c\/em\u003e, L. Cui et al., ACS Appl. Mater. Interfaces, 12(7), 7966–7973 (2020); DOI: 10.1021\/acsami.9b21943.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eMicroporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation\u003c\/em\u003e, J. -X. Jiang et al., Macromolecules, 42 (7), 2658–2666 (2008); DOI: 10.1021\/ma802625d.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eFerrocene-based hyperbranched polytriazoles: synthesis by click polymerization and application as precursors to nanostructured magnetoceramics\u003c\/em\u003e, H. Li et al., Macromol. Rapid Commun., 38, 1700075 (2017); DOI: 10.1002\/marc.201700075.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eOrganoruthenium dendrimers possessing tris(4-ethynylphenyl)amine bridges\u003c\/em\u003e, K. Onitsuka et al., Organometallics, 27 (1), 25–27 (2008); DOI: 10.1021\/om7010276.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTris-ethynylphenyl-amine flcuorophores: synthesis, characterization and test of performances in luminescent solar concentrators\u003c\/em\u003e, G. Albano et al, ChemistrySelect, 3, 1749 (2018); DOI: 10.1002\/slct.201800126.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eTripodal molecules with triphenylamine core, diazine peripheral groups and extended π-conjugated linkers\u003c\/em\u003e, D. Cvejn et al., Dyes Pigm., 124, 101–109 (2016); DOI: 10.1016\/j.dyepig.2015.09.012.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44040665268440,"sku":"B3531-1g","price":241.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44040665006296,"sku":"B3531-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44040665333976,"sku":"B3531-5g","price":700.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/tris4-ethynylphenylamine-chemical-structure-title.png?v=1718706710"},{"product_id":"3-3-bipyridine-6-6-dicarboxaldehyde","title":"[3,3-Bipyridine]-6,6-dicarboxaldehyde","description":"\u003ch2 id=\"product-oneliner\"\u003eCovalent organic frameworks (COFs) bipyridine ligands\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003efor synthesizing COFs and their metal complexes for host-guest interactions\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003e[3,3-Bipyridine]-6,6-dicarboxaldehyde (CAS number 1264748-06-2), also known under IUPAC name of 3,3'-bipyridine-6,6'-dicarbaldehyde, is a derivative of 3,3’-bipyridine functionalized with two aldehyde groups. [3,3-Bipyridine]-6,6-dicarboxaldehyde undergoes reactions with amines to synthesize Schiff bases. The formation of the imine on the \u003cem\u003emeso\u003c\/em\u003e-carbon and the imine in the pyridine ring can coordinate to metal center constructing a stable 5-membered ring. A metal-organic polyhedra composed of Fe\u003csup\u003eII\u003c\/sup\u003e and the Schiff base ligand prepared from [3,3-bipyridine]-6,6-dicarboxaldehyde and aniline, exhibits selective anion binding to PF\u003csub\u003e6\u003c\/sub\u003e\u003csup\u003e-\u003c\/sup\u003e over CF\u003csub\u003e3\u003c\/sub\u003eSO\u003csub\u003e3\u003c\/sub\u003e\u003csup\u003e-\u003c\/sup\u003e and BF\u003csub\u003e4\u003c\/sub\u003e\u003csup\u003e-\u003c\/sup\u003e.\u003c\/p\u003e\n\u003cp\u003eThe metal-organic complexes from [3,3-bipyridine]-6,6-dicarboxaldehyde based COFs display a reversible binding affinity towards fluorescent dyes. This property enables the design of indicator-displacement assays.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Facile reactions\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Lab_Proof.svg?v=1697623210\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eFacile reactions\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eAldehyde possesses excellent reactivity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High Purity 1264748-06-2\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh Purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;98% Purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Worldwide shipping for 1264748-06-2\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"MOF and COF ligands\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg?v=1698833718\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eMOF and COF ligands\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eAldehyde ligand for cross-linked COF networks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1264748-06-2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e12\u003c\/sub\u003eH\u003csub\u003e8\u003c\/sub\u003eN\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e2\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e3,3'-Bipyridine-6,6'-dicarbaldehyde\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e212.20 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e5-(6-formyl-3-pyridyl)pyridine-2-carbaldehyde\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBipyridine ligands, Aldehydes, COFs, MOFs, Host-guest interactions\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/3-3-bipyridine-6-6-dicarboxaldehyde-chemical-structure-title.png?v=1718706710\" target=\"_blank\" title=\"[3,3-Bipyridine]-6,6-dicarboxaldehyde chemical structure, CAS 1264748-06-2.\"\u003e\u003cimg alt=\"[3,3-Bipyridine]-6,6-dicarboxaldehyde chemical structure, CAS 1264748-06-2.\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/3-3-bipyridine-6-6-dicarboxaldehyde-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003e[3,3-Bipyridine]-6,6-dicarboxaldehyde chemical structure, CAS 1264748-06-2\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eN\/A\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBrown powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/3-3-bipyridine-6-6-dicarboxaldehyde.pdf\" target=\"_blank\" title=\"[3,3-Bipyridine]-6,6-dicarboxaldehyde MSDS Sheet\"\u003e\u003cimg alt=\"[3,3-Bipyridine]-6,6-dicarboxaldehyde\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003e[3,3-Bipyridine]-6,6-dicarboxaldehyde MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eAqueous anion receptors through reduction of subcomponent self-assembled structures\u003c\/em\u003e, J. Mosquera et al., Angew. Chem. Int. Ed., 53, 1556–1559 (2014); DOI: 10.1002\/anie.201308117.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSelective anion binding by a \"Chameleon\" capsule with a dynamically reconfigurable exterior\u003c\/em\u003e, Y. Hristova et al., Chem. Sci., 2, 638 (2011); DOI: 10.1039\/c0sc00495b.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDynamic imine chemistry in metal-organic polyhedra\u003c\/em\u003e, H. Vardhan et al., RSC Adv., 5, 67011–67030 (2015); DOI: 10.1039\/C5RA10801B.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003eA dynamic-covalent, luminescent metallopolymer that undergoes sol-to-gel transition on temperature rise\u003c\/em\u003e, X. Hatten et al., J. Am. Chem. Soc., 133(9), 3158–3164 (2011); DOI: 10.1021\/ja110575s.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSynthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties\u003c\/em\u003e, L. Wu et al., Nat. Synth., 2, 17–25 (2023); DOI: 10.1038\/s44160-022-00173-7.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44047879897304,"sku":"B3541-1g","price":237.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44047879864536,"sku":"B3541-500mg","price":148.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44047879930072,"sku":"B3541-5g","price":800.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/3-3-bipyridine-6-6-dicarboxaldehyde-chemical-structure-title.png?v=1718706710"},{"product_id":"benzene-1-3-5-triyltriboronic-acid","title":"Benzene-1,3,5-triyltriboronic acid","description":"\u003ch2 id=\"product-oneliner\"\u003eCovalent organic frameworks (COFs) benzenetriboronic acid ligand\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eused to synthesize COFs and MOFs for applications in sensors and battery cathodes\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#specifications\"\u003eSpecifications\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature and Reviews\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp\u003eBenzene-1,3,5-triyltriboronic acid (CAS number 89641-21-4) is a benzene derivative substituted with three boronic acid groups at the \u003cem\u003emeta\u003c\/em\u003e-position. Benzene-1,3,5-triyltriboronic acid reacts with various ligands to synthesize COFs. These reactions include dehydration reaction with boronic acids to form boroxine linkers, boronate esterification with diols to produce boronate ester linkers and Suzuki cross-coupling reaction with aryl halides. A conjugated COF, synthesized from benzene-1,3,5-triyltriboronic acid and dibromoanthraquinone, is used for sodium-ion battery cathodes. The resulting material delivers a high capacity of 200 mAh\/g and rate performance of 105 mAh\/g at 200 °C.\u003c\/p\u003e\n\u003cp\u003eBenzene-1,3,5-triyltriboronic acid also reacts with copper sulfate for a 2D MOF material with well-defined supramolecular structures. The 2D MOF exhibits a conductivity of 0.087 S\/cm.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Facile reactions\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Lab_Proof.svg?v=1697623210\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eFacile reactions\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eReadily for boronic acid condensation and Suzuki reaction\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High Purity 89641-21-4\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Purity.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh Purity\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003e\u0026gt;98% Purity\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"Worldwide shipping for 89641-21-4\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg?v=1698159365\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWorldwide shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eQuick and reliable shipping\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"MOF and COF ligands\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/All_Icons_CRYSTALS.svg?v=1698833718\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eMOF and COF ligands\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eBoronic acid ligand for cross-linked COF networks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"specifications\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eCAS Number\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e89641-21-4\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eChemical Formula\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eC\u003csub\u003e6\u003c\/sub\u003eH\u003csub\u003e9\u003c\/sub\u003eB\u003csub\u003e3\u003c\/sub\u003eO\u003csub\u003e6\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eFull Name\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBenzene-1,3,5-triyltriboronic acid\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMolecular Weight\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e209.57 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eSynonyms\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e1,3,5-benzenetriboronic acid, B,B',B''-1,3,5-benzenetriyltris-boronic acid, BTBA, BTPA\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eClassification \/ Family\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eBoronic acids, COFs, MOFs, Conjugated, Sensors, Battery cathodes, Porous materials\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eChemical Structure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/benzene-1-3-5-triyltriboronic-acid-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" target=\"_blank\" title=\"Benzene-1,3,5-triyltriboronic acid chemical structure, CAS 89641-21-4.\"\u003e\u003cimg alt=\"Benzene-1,3,5-triyltriboronic acid chemical structure, CAS 89641-21-4.\" height=\"180\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/benzene-1-3-5-triyltriboronic-acid-chemical-structure-title.png?v=1718706710\u0026amp;width=240\" width=\"240\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eBenzene-1,3,5-triyltriboronic acid chemical structure, CAS 89641-21-4\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003ePurity\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003e98%\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eMelting Point\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eN\/A\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd width=\"38.2%\"\u003e\u003cstrong\u003eAppearance\u003c\/strong\u003e\u003c\/td\u003e\n\u003ctd\u003eWhite powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/downloads.ossila.com\/msds\/benzene-1-3-5-triyltriboronic-acid.pdf\" target=\"_blank\" title=\"Benzene-1,3,5-triyltriboronic acid MSDS Sheet\"\u003e\u003cimg alt=\"Benzene-1,3,5-triyltriboronic acid\" class=\"msds-icon\" height=\"39\" loading=\"lazy\" msds=\"\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" width=\"30\"\u003eBenzene-1,3,5-triyltriboronic acid MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eLiterature and Reviews\u003c\/h2\u003e\n\u003chr\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cem\u003eHighly sensitive and selective fluorescence chemosensors containing phenanthroline moieties for detection of Zn\u003csup\u003e2+\u003c\/sup\u003e and Cd\u003csup\u003e2+\u003c\/sup\u003e ions\u003c\/em\u003e, C. Quan et al., Chem. Pap., 74, 485–497 (2020); DOI: 10.1007\/s11696-019-00893-9.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eElectrochemical synthesis of large area two-dimensional metal-organic framework films on copper anodes\u003c\/em\u003e, Y. Liu et al., Angew. Chem. Int. Ed., 60 (6), 2887–2891 (2021); DOI: 10.1002\/anie.202012971.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eNanoscale covalent organic frameworks as theranostic platforms for oncotherapy: synthesis, functionalization, and applications\u003c\/em\u003e, Q. Guan et al., Nanoscale Adv., 2, 3656 (2020); DOI: 10.1039\/d0na00537a.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003cdiv class=\"expandable\" id=\"literature-and-reviews\"\u003e\n\u003col start=\"4\"\u003e\n\u003cli\u003e\n\u003cem\u003ePyrene-based fluorescent porous organic polymers for recognition and detection of pesticides\u003c\/em\u003e, Z. Yan et al., Molecules, 27, 126 (2022); DOI: 10.3390\/molecules27010126.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eSynthetic control of electronic property and porosity in anthraquinone-based conjugated polymer cathodes for high-rate and long cycle-life Na-organic batteries\u003c\/em\u003e, L.-W. Luo et al., ACS Nano, 16 (9), 14590–14599 (2022); DOI: 10.1021\/acsnano.2c05090.\u003c\/li\u003e\n\u003c\/ol\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton class=\"anchor expand-link\" data-expand-target=\"literature-and-reviews\" data-toggle-text=\"Hide Literature and Reviews\" type=\"button\"\u003eView Literature and Reviews\u003c\/button\u003e\u003c\/p\u003e\n","brand":"Ossila","offers":[{"title":"1 g","offer_id":44050118508760,"sku":"B3551-1g","price":241.0,"currency_code":"GBP","in_stock":true},{"title":"500 mg","offer_id":44050118475992,"sku":"B3551-500mg","price":150.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":44050118541528,"sku":"B3551-5g","price":650.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/benzene-1-3-5-triyltriboronic-acid-chemical-structure-title.png?v=1718706710"},{"product_id":"hkust-1","title":"HKUST-1 MOF","description":"\u003ch2 id=\"product-oneliner\"\u003eOne of the Most Studied Metal Organic Frameworks\u003c\/h2\u003e\n\u003cp class=\"text-center\"\u003eExhibits high surface area for CO\u003csub\u003e2\u003c\/sub\u003e capture, water purification, and drug delivery\u003c\/p\u003e\n\u003chr\u003e\n\u003cp class=\"text-center\"\u003e\u003ca href=\"#product-information\"\u003eProduct Information\u003c\/a\u003e | \u003ca href=\"#msds\"\u003eMSDS\u003c\/a\u003e | \u003ca href=\"#literature\"\u003eLiterature \u0026amp; Reviews\u003c\/a\u003e | \u003ca href=\"#related-products\"\u003eRelated Products\u003c\/a\u003e\u003c\/p\u003e\n\u003chr\u003e\n\u003cp id=\"overview\"\u003eHKUST-1 (CAS number: 222404-02-6) is a copper-based metal organic framework constructed from copper centers and benzene-1,3,5-tricarboxylate (BTC) linkers. The crystal structure of HKUST-1 is built up by secondary building units called paddlewheel units. The paddlewheel units, where two copper ions are bridged by four BTC linkers, not only contribute to the high surface area (1,350 m\u003csup\u003e2\u003c\/sup\u003e\/g) but also provide structural rigidity with thermal stability up to 240 °C.\u003c\/p\u003e\n\u003cp\u003eHKUST-1 has multiple applications, including CO\u003csub\u003e2\u003c\/sub\u003e capture, drug delivery and batteries. HKUST-1 can capture water pollutants (i.e. Cr\u003csup\u003e3+\u003c\/sup\u003e ion) with adsorption capacity of 84.3 mg\/g. The purification process occurs via adsorption active sites and ionic exchange between copper and chromium ions. HKUST-1 is also applied in the direct air capture of CO\u003csub\u003e2\u003c\/sub\u003e. When incorporated with graphene oxide, it demonstrates CO\u003csub\u003e2\u003c\/sub\u003e capture capacities of up to 6.92 mmol\/g.\u003c\/p\u003e\n\u003cdiv class=\"row display-flex\"\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Versitile.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eWide range of Applications\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eGas separation, batteries, and more\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Icon_Lab_Proof.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eRobust Metal Organic Framework\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eStructural rigidity and thermal stability up to 240 °C\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg alt=\"High purity\" height=\"50\" loading=\"lazy\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/Ossila_Writers_Icons_Netwroking.svg\" width=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eHigh Surface Area\u003cbr\u003eof 1,350 m\u003csup\u003e2\u003c\/sup\u003e\/g\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eWith good adsorption capacity of 84.3 mg\/g\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"col-xs-12 col-md-3 text-center margin-top\"\u003e\n\u003cimg width=\"50\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/2D-Materials-Icons_-Free_ish_Shipping.svg\" loading=\"lazy\" height=\"50\"\u003e\n\u003cp class=\"blue-heading no-margin text-center\"\u003eSimple Worldwide Shipping\u003c\/p\u003e\n\u003cp class=\"text-center\"\u003eReliable delivery via tracked courier as standard\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e\n\u003ch2 id=\"product-information\"\u003eGeneral Information\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eCAS Number\u003c\/th\u003e\n\u003ctd\u003e222404-02-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eChemical Formula\u003c\/th\u003e\n\u003ctd\u003eC\u003csub\u003e18\u003c\/sub\u003eH\u003csub\u003e6\u003c\/sub\u003eCu\u003csub\u003e3\u003c\/sub\u003eO\u003csub\u003e12\u003c\/sub\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eFull Name\u003c\/th\u003e\n\u003ctd\u003ePoly[μ\u003csub\u003e2\u003c\/sub\u003e-benzene-1,3,5-tricarboxylato-tricuprate(II)]\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eMolecular Weight\u003c\/th\u003e\n\u003ctd\u003e604.9 g\/mol\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eSynonyms\u003c\/th\u003e\n\u003ctd\u003eMOF-199, Cu-BTC, Copper benzene-1,3,5-tricarboxylate MOF, Cu\u003csub\u003e3\u003c\/sub\u003e(BTC)\u003csub\u003e2\u003c\/sub\u003e, HKUST1\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eClassification or Family\u003c\/th\u003e\n\u003ctd\u003eMetal organic frameworks, Porous organic frameworks, MOFs\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2\u003eStructure\u003c\/h2\u003e\n\u003chr\u003e\n\u003cfigure\u003e\u003ca title=\"HKUST-1 structure\" href=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/HKUST-1-core-structure.png\" target=\"_blank\"\u003e\u003cimg src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/HKUST-1-core-structure.svg\" height=\"450\" width=\"600\" loading=\"lazy\" alt=\"HKUST-1 structure\"\u003e\u003c\/a\u003e\n\u003cfigcaption\u003eHKUST-1 paddlewheel core structure, CAS No. 222404-02-6\u003c\/figcaption\u003e\n\u003c\/figure\u003e\n\u003ch2\u003eProduct Details\u003c\/h2\u003e\n\u003chr\u003e\n\u003ctable width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eParticle Size\u003c\/th\u003e\n\u003ctd\u003e1.8 μm (D50)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eSurface Area (BET)\u003c\/th\u003e\n\u003ctd\u003e1166 m\u003csup\u003e2\u003c\/sup\u003e\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003ePore Size\u003c\/th\u003e\n\u003ctd\u003e0.3 – 1 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003cth width=\"38.2%\"\u003eAppearance\u003c\/th\u003e\n\u003ctd\u003eBlue powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003ch2 id=\"msds\"\u003eMSDS Documentation\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003e\u003ca title=\"HKUST-1 MSDS Sheet\" href=\"https:\/\/downloads.ossila.com\/msds\/hkust-1.pdf\" target=\"_blank\"\u003e\u003cimg width=\"30\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/product-downloads-msds.svg\" loading=\"lazy\" height=\"38.672\" class=\"msds-icon\" alt=\"HKUST-1 MSDS Sheet\"\u003eHKUST-1 MSDS Sheet\u003c\/a\u003e\u003c\/p\u003e\n\u003ch2 id=\"literature\"\u003eReferences\u003c\/h2\u003e\n\u003chr\u003e\n\u003cul\u003e\n\u003cli\u003e\n\u003cem\u003eThe effect of copper(II) salt precursor on physicochemical properties of HKUST-1 MOFs and their application as adsorbents of Cr(III) ions from aqueous solutions\u003c\/em\u003e, J. Mokrzycki et al., JWPE, 64,105761 (2024); DOI: 10.1016\/j.jwpe.2024.105761 .\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eRevisiting the HKUST01\/S composites as an electrode for Li-S batteries: inherent problems that hinder its performance\u003c\/em\u003e, J. Haro et al., Eur. J. Inorg. Chem., 2021(2), 177–18510 (2021); DOI: 10.1002\/ejic.202000837.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eResearch progress on the application of MOF materials in lithium-ion batteries\u003c\/em\u003e, X. Zhang et al., Battery Energy, 4, 20240046 (2025); DOI: 10.1002\/bte2.20240046.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003cdiv class=\"expandable\" id=\"references\"\u003e\n\u003cul\u003e\n\u003cli\u003e\n\u003cem\u003eSelective electrochemical sensing of sunset yellow in beverages based on synergistic signal amplification of HKUST1 and MWCNTs\u003c\/em\u003e, K. Mthiyane et al., Electroanalysis, 37, e12020 (2025); DOI: 10.1002\/elan.12020.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eHKUST-1 metal-organic framework nanoparticle\/graphene oxide\u003c\/em\u003e, A. Rosado et al., ACS Appl. Nano Mater., 4 (11), 12712–12725 (2021); DOI: 10.1021\/acsanm.1c03301.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eDrug delivery of paracetamol by metal-organic frameworks (HKUST-1): improvised synthesis and investigations\u003c\/em\u003e, Mater. Today Chem., 23, 100647 (2022); DOI: 10.1016\/j.mtchem.2021.100647.\u003c\/li\u003e\n\u003cli\u003e\n\u003cem\u003eCO\u003csub\u003e2\u003c\/sub\u003e adsorption on a water-resist HKUST-1 by incorporation of graphene oxide\u003c\/em\u003e, S. Loera-Serna et al., Adsorption, 31, 5 (2025); DOI: 10.1007\/s10450-024-00553-9.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003c\/div\u003e\n\u003cp\u003e\u003cbutton data-toggle-text=\"Hide references\" data-expand-target=\"references\" class=\"anchor expand-link\" type=\"button\"\u003eView more references\u003c\/button\u003e\u003c\/p\u003e\n\u003ch2 id=\"related-products\"\u003eRelated Products\u003c\/h2\u003e\n\u003chr\u003e\n\u003cp\u003eWe stock a wide range of metal organic frameworks available to purchase online. Please \u003ca title=\"Contact Us\" href=\"https:\/\/www.ossila.com\/pages\/contact-us\"\u003econtact us\u003c\/a\u003e if you cannot find what you are looking for.\u003c\/p\u003e\n\u003cdiv class=\"collection-container\"\u003e\n\u003cdiv class=\"collection-tile\"\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/collections\/organic-frameworks\"\u003e\n\u003cdiv class=\"collection-button background-light-blue\"\u003e\n\u003cimg src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/collection-link-COF-ligands.png\" loading=\"lazy\" alt=\"Porous organic frameworks\" height=\"109.266\" width=\"150\"\u003e\n\u003cp\u003ePorous Organic Frameworks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/www.ossila.com\/collections\/organic-frameworks\"\u003ePorous Organic Frameworks\u003c\/a\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"collection-tile\"\u003e\n\u003ca href=\"https:\/\/www.ossila.com\/collections\/metal-organic-frameworks\"\u003e\n\u003cdiv class=\"collection-button background-ossila-blue\"\u003e\n\u003cimg src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/metal-organic-frameworks-collection-design.png\" loading=\"lazy\" alt=\"Metal organic frameworks\" height=\"109.266\" width=\"150\"\u003e\n\u003cp\u003eMetal Organic Frameworks\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\n\u003cp\u003e\u003ca href=\"https:\/\/www.ossila.com\/collections\/metal-organic-frameworks\"\u003eMetal Organic Frameworks\u003c\/a\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003cdiv class=\"collection-tile\"\u003e\n\u003ca href=\"\/collections\/mof-ligands\"\u003e\n\u003cdiv class=\"collection-button background-light-blue\"\u003e\n\u003cimg alt=\"MOF Ligands Collection\" src=\"https:\/\/www.ossila.com\/cdn\/shop\/files\/collection-link-MOF-Ligands.png\" width=\"150\"\u003e\n\u003cp\u003eMOF Ligands\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/a\u003e\n\u003cp\u003e\u003ca href=\"\/collections\/mof-ligands\"\u003eMOF Ligands\u003c\/a\u003e\u003c\/p\u003e\n\u003c\/div\u003e\n\u003c\/div\u003e","brand":"Ossila","offers":[{"title":"1 g","offer_id":50970043744472,"sku":"M2562A1-1g","price":70.0,"currency_code":"GBP","in_stock":true},{"title":"5 g","offer_id":50970043777240,"sku":"M2562A1-5g","price":210.0,"currency_code":"GBP","in_stock":true},{"title":"10 g","offer_id":50970043810008,"sku":"M2562A1-10g","price":350.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/files\/hkust-1-title-image.jpg?v=1761056272"}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0823\/0287\/collections\/materials-collection-featured-photo_feb59460-6da7-475c-aef2-1cd59f2c3b3a.jpg?v=1765465104","url":"https:\/\/www.ossila.com\/collections\/mof-ligands.oembed?constraint=3-coordination-sites","provider":"Ossila","version":"1.0","type":"link"}